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Hotter-than-usual days are becoming more common, such that heat waves are expected to increase in intensity, frequency, duration, and spatial extent in Spain. Within this framework, this paper looks at the combined effects of extreme temperatures and air pollution in two cities in Spain, Córdoba and Valladolid, over the period 2006-2022. Synoptic patterns and air mass movement were analysed during the eleven coincident heat waves at both locations in order to study what impact orography and local meteorology have on ozone concentrations. Weak flow conditions were the most frequent synoptic pattern in the Iberian Peninsula during heat waves. Moreover, west and local circulations characterised the main air trajectories at low levels (500 m agl), while southwest maritime advections and African air mass transport were more frequent at higher levels (1500 and 3000 m agl) in Córdoba and Valladolid, respectively. On average, maximum ozone values were higher in Córdoba (105.1 µg m -3 ) than in Valladolid (80 µg m -3 ) and were strongly correlated with extreme temperatures at both locations (r up to 0.8, p-value < 0.05). Mean temperature in Córdoba was 31.9 °C, with the maximum value reaching 43.7 °C, while temperatures in Valladolid were lower (28.3 °C and 37.3 °C, respectively). Calculation and assessment of some indices helped to understand the impact of extreme events. Caution actions based on the Heat Index characterised heat wave periods. Moderate risk was the general Air Quality Health Index feature recorded and reached a very high risk of unhealthy air quality in the June 2022 event in Córdoba., (© 2024. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)

Metal mining in the Extremadura region was very important in the 19 th and 20 th centuries. However, due to different reasons the great majority of mines ceased operations, leading to plenty of abandoned mining sites, most of them with on-site waste dumps. Although metal extraction is not radioactive per se, it is considered a NORM activity. In this study, three former mining sites, in which Pb-V-Zn-Ag, Pb-Ag, and Pb-Zn were extracted, were selected to assess the radiological impact on the population and the environment. The external γ exposure was estimated by determining the effective dose and elaborating isodose maps of the sites. The presence of the mining sites increased up to 0.41 mSv/y the effective dose over the surrounding background, which is below the reference value of 1 mSv/y. In only one mining site, the uranium and radium activity concentration of waste dumps were higher than the surrounding soil. The soil to plant (wild grass) transfer factors were similar to other reported values without the influence of NORM activities. So, no enhanced transfer of radionuclides was observed. The radiological impact on the environment was assessed by the risk to non-human biota using the tiered approach developed in ERICA Tool. The sum of the risk quotients of all considered radionuclides in the most conservative Tier 1 was below 1. Total dose rates for several terrestrial Reference Animal and Plants (RAPs) were estimated using Tier 3, obtaining values below 40 µGy/h. Therefore, the impact on non-human biota can be considered as negligible., Competing Interests: Declaration of competing interest The authors declare the following financial interests/personal relationships which may be considered as potential competing interests: The corresponding author (J. Guillen) serves as Assistant Editor to the Journal of Environmental Radioactivity If there are other authors, they declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 The Authors. Published by Elsevier Ltd.. All rights reserved.)

Aims: Interdisciplinary collaboration between health and education professionals is one of the principles of inclusive education. This study aimed to describe the practices and service delivery by pediatric occupational therapists (OTs) in schools in Spain., Methods: Data came from a convenience sample of pediatric OTs recruited through Spanish professional colleges and associations for a web-based survey, mixed-method research study. Thirty-five respondents were excluded because they didn't meet the eligibility criteria. Ninety-two responses were obtained for data analysis. Twenty-nine OTs (31.5%) work in schools (school-OTs), and sixty-three participants (68.5%) don't work there but collaborate with schools (non-school OTs)., Results: Participants support students with and without a medical diagnosis. Services provided by OTs external to the educational system are mainly funded by families or only partially covered. Findings show that most participants use standardized assessments and apply several intervention approaches. They believe there are barriers to the collaboration and implementation of occupational therapy services in schools., Conclusions: This preliminary study shows a need for changes in Spain's State and Regional Education legislation and provides recommendations to improve school service delivery. Pediatric OTs are encouraged to reflect on and identify opportunities for changes to enhance school-based occupational therapy practice in Spain.

This study aims to support the development of Spain's Ozone Mitigation Plan by evaluating the present-day spatial variation (2015-2019) and trends (2008-2019) for seven ground-level ozone (O 3 ) metrics relevant for human/ecosystems exposure and regulatory purposes. Results indicate that the spatial variation of O 3 depends on the part of the O 3 distribution being analyzed. Metrics associated with moderate O 3 concentrations depict an increasing O 3 gradient between the northern and Mediterranean coasts due to climatic factors, while for metrics considering the upper end of the O 3 distribution, this climatic gradient tends to attenuate in favor of hotspot regions pointing to relevant local/regional O 3 formation. A classification of atmospheric regions in Spain is proposed based on their O 3 pollution patterns, to identify priority areas (or O 3 hotspots) where local/regional precursor abatement might significantly reduce O 3 during pollution episodes. The trends assessment reveals a narrowing of the O 3 distribution at the national level, with metrics influenced by lower concentrations tending to increase over time, and those reflecting the higher end of the O 3 distribution tending to decrease. While most stations show no statistically significant variations, contrasting O 3 trends are evident among the O 3 hotspots. The Madrid area exhibits the majority of upward trends across all metrics, frequently with the highest increasing rates, implying increasing O 3 associated with both chronic and episodic exposure. The Valencian Community area exhibits a mixed variation pattern, with moderate to high O 3 metrics increasing and peak metrics decreasing, while O 3 in areas downwind of Barcelona, the Guadalquivir Valley and Puertollano shows no variations. Sevilla is the only large Spanish city with generalized O 3 decreasing trends. The different O 3 trends among hotspots highlight the need for mitigation measures to be designed at a local/regional scale to be effective. This approach may offer valuable insights for other countries developing O 3 mitigation plans., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 The Authors. Published by Elsevier Ltd.. All rights reserved.)

In intertidal areas, the zonation is determined by factors such as sea-level and topography. For this reason, a mixed methodology for the characterization (topography, extension, and zonation) of maximum intertidal areas is presented, based upon multispectral satellite imagery, hydrodynamic modeling, and in situ measurements. The methodology is applied and validated in the inner Cadiz Bay (SW Spain) as a case study. Satellite-derived waterlines were vertically referenced by tide-gauge measurements of sea-level; the resulting partial topography of intertidal areas was integrated into available hydrographic/topographic data to elaborate a high-resolution (10 m) model grid from which hydrodynamic simulations were conducted. Model results for lowest and highest tidal level situations were used to characterize the maximum intertidal areas within the inner Cadiz Bay, as well as the lowest astronomical tidal surface (LAT). The obtained LAT, referenced with respect the chosen geoid and/or ellipsoid, was identified with the vertical reference surface for Hydrography (VRSH) in this environment, complementing and improving the official VRSH presently being developed for Spanish waters. Obtained results show errors of the order of 1 cm for sea-level amplitudes and <1 min for the main tidal lags when comparing with tide-gauge data. Further applications of this exportable, relatively fast, low-cost, and accurate methodology are outlined., Competing Interests: Declaration of competing interest Carlos J. González, corresponding author of the paper entitled “High-resolution characterization of intertidal areas and lowest astronomical tidal surface by use of Sentinel-2 multispectral imagery and hydrodynamic modeling: Case-study in Cadiz Bay (Spain)”, on behalf of the rest of authors J. R. Torres, S. Haro, J. Gómez-Enri, and O. Álvarez, discloses any financial and personal relationships with other people or organizations that could inappropriately influence (bias) our work., (Copyright © 2022 Elsevier B.V. All rights reserved.)

This study focuses on the analysis of the distribution, both spatial and temporal, of the PM 10 (particulate matter with a diameter of 10 µm or less) concentrations recorded in nine EMEP (European Monitoring and Evaluation Programme) background stations distributed throughout mainland Spain between 2001 and 2019. A study of hierarchical clusters was used to classify the stations into three main groups with similarities in yearly concentrations: GC (coastal location), GNC (north-central location), and GSE (southeastern location). The highest PM 10 concentrations were registered in summer. Annual evolution showed statistically significant decreasing trends in PM 10 concentration in all the stations covering a range from -0.21 to -0.50 µg m -3 /year for Barcarrota and Víznar, respectively. Through the Lamb classification, the weather types were defined during the study period, and those associated with high levels of pollution were identified. Finally, the values exceeding the limits established by the legislation were analyzed for every station assessed in the study.

In this work we present the personal exposure levels to Radiofrequency Electromagnetic Fields (RF-EMF) from Wireless Fidelity (Wi-Fi) 2.4 GHz and 5.85 GHz bands in a Spanish university, specifically, at the Faculty of Computer Science Engineering at the University of Castilla-La Mancha (Albacete, Spain). We present results from three years, 2017, 2018 and 2019 in the same study place and points; and measurements carried out in 2022 inside a classroom and inside a professor's office, with the aim to compare the measurements and verify compliance with reference levels established by the International Commission on Non-Ionizing Radiation Protection (ICNIRP). The minimum average was 0.0900 μW/m 2 in the 2.4 GHz Wi-Fi, in 2019, and the maximum average was 211 μW/m 2 in the 5.85 GHz Wi-Fi in 2017, around the building. Comparing the measurements carried out inside the classroom with students and without students, we identified that the maximum value was 278 μW/m 2 (classroom with students, in the 5.85 GHz Wi-Fi band) and the minimum value was 37.9 μW/m 2 (classroom without students, in the 5.85 GHz Wi-Fi band). Finally, comparing the results of all the measurements (average values) inside the classroom and inside a professor's office, the maximum value was 205 μW/m 2 (in the 5.85 GHz Wi-Fi band) inside the classroom with students, and the minimum value was 0.217 μW/m 2 inside a professor's office (in the 2.4 GHz Wi-Fi band). These values in no case exceed the limits established by the International Commission on Non-Ionizing Radiation Protection, 10 W/m 2 for general public exposure., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this article., (Copyright © 2022 Elsevier B.V. All rights reserved.)

Intensive care units (ICUs) are busy and noisy areas where patients and professional staff can be exposed to acoustic noise for long periods of time. In many cases, noise levels significantly exceed the levels recommended by the official health organisations. This situation can affect not only patient recovery but also professional staff, making ICUs unhealthy work and treatment environments. To introduce the measures and reduce the acoustic noise in the ICU, acoustic noise levels should first be measured and then appropriately analysed. However, in most studies dealing with this problem, measurements have been performed manually over short periods, leading to limited data being collected. They are usually followed by insufficient analysis, which in turn results in inadequate measures and noise reduction. This paper reviews recent works dealing with the problem of excessively high noise levels in ICUs and proposes a more thorough analysis of measured data both in the time and frequency domains. Applied frequency domain analysis identifies the cyclic behaviour of the measured sound pressure levels (SPLs) and detects the dominant frequency components in the SPL time series. Moreover, statistical analyses are produced to depict the patterns and SPLs to which patients in ICUs are typically exposed during their stay in the ICU. It has been shown that the acoustic environment is very similar every night, while it can vary significantly during the day or evening periods. However, during most of the observed time, recorded SPLs were significantly above the prescribed values, indicating an urgent need for their control and reduction. To effectively tackle this problem, more detailed information about the nature of noise during each of the analysed periods of the day is needed. This issue will be addressed in the continuation of this project.

Post-epidemic protocols have been implemented in public buildings to keep indoor environments safe. However, indoor environmental conditions are affected by this decision, which also affect the occupants of buildings. This fact has major implications in educational buildings, where the satisfaction and learning performance of students may also be affected. This study investigates the impact of post-epidemic protocols on indoor environmental conditions in higher education buildings of one Portuguese and one Spanish university. A sensor monitoring campaign combined with a simultaneous questionnaire was conducted during the reopening of the educational buildings. Results showed that although renewal air protocols were effective and the mean CO 2 concentration levels remained low (742 ppm and 519 ppm in Portugal and Spain universities, respectively), students were dissatisfied with the current indoor environmental conditions. Significant differences were also found between the responses of Portuguese and Spanish students. Indeed, Spanish students showed warmer preferences (thermal neutrality = 23.3℃) than Portuguese students (thermal neutrality = 20.7℃). In terms of involved indoor factors, the obtained data showed significant correlations (p < 0.001) between acoustic factors and overall satisfaction in the Portuguese students (ρ = 0.540) and between thermal factors and overall satisfaction in the Spanish students (ρ = 0.522). Therefore, indoor environmental conditions should be improved by keeping spaces safe while minimizing the impact of post-epidemic protocols on student learning performance., (© 2022 The Authors. Indoor Air published by John Wiley & Sons Ltd.)

CO 2 and CH 4 outliers may have a noticeable impact on the trend of both gases. Nine years of measurements since 2010 recorded at a rural site in northern Spain were used to investigate these outliers. Their influence on the trend was presented and two limits were established. No more than 23.5% of outliers should be excluded from the measurement series in order to obtain representative trends, which were 2.349 ± 0.012 ppm year -1 for CO 2 and 0.00879 ± 0.00004 ppm year -1 for CH 4 . Two types of outliers were distinguished. Those above the trend line and the rest below the trend line. Outliers were described by skewed distributions where the Weibull distribution figures prominently in most cases. A qualitative procedure was presented to exclude the worst fits, although five statistics were considered to select the best fit. In this case, the modified Nash-Sutcliffe efficiency is prominent. Finally, three symmetrical distributions were added to fit the observations when outliers are excluded, with the Gaussian and beta distributions providing the best fits. As a result, certain skewed functions, such as the lognormal distribution, whose use is frequent for air pollutants, could be questioned in certain applications., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier B.V. All rights reserved.)

Taking into account that in the literature on pork-production Life Cycle Assessment (LCA) there are a few studies about the Iberian pig, the present article evaluates an extensive (growing-fattening) Iberian-pig system in Spain, producing meat for Iberian ham and other quality-labelled products. The study has been based on Cumulative Energy Demand (CED), Global Warming Potential (GWP), ReCiPe (midpoint; endpoint) and USEtox (human toxicity; ecotoxicity). The analysis involves feed (for pigs and piglets), transportation, drinking water, straw usage and building materials (concrete). The impacts have been evaluated per kg of live or carcass weight (two functional units). The results show that the total impacts (per kg of live or carcass weight) range from: 1) 22.05 to 28.19 MJ prim (CED), 2) 4.37 to 6.19 kg CO 2.eq (GWP 20a, 100a and 500a), 3) 0.86 to 1.08 Pts (ReCiPe endpoint single-score, involving Human health, Ecosystems and Resources), 4) 9.9 × 10 -6 to 1.2 × 10 -5 DALY (ReCiPe endpoint with characterisation), 5) 2.8 × 10 -7 to 3.5 × 10 -7 (species.yr) (ReCiPe endpoint with characterisation), 6) 10.12 to 12.66 CTU e (USEtox: ecotoxicity). Overall, the results show that the feed for the pigs is responsible for the major part of the environmental impacts. More analytically, maize and soya are the components with the highest environmental impacts due to factors such as transportation, use of fertilisers and diesel fuel. The discussion about pig-production environmental impacts and the role of extensive pig farming is enriched with comparisons with the literature on pig-production LCA. Critical parameters are identified and discussed, with the aim of proposing solutions to reduce pork-production environmental impacts. Finally, the usefulness of the present study and future prospects are presented., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2021 Elsevier B.V. All rights reserved.)

Adequate thermic conditions are required for the preventive conservation of artworks, but such optimum conditions cannot always be achieved in historical buildings such as ancient churches. In those cases, it is of interest to assess the potential risk of punctual changes in indoor environments that can be harmful to artworks. These conditions can be assessed by means of a microclimate monitoring system comprised of a set of energy-efficient wireless sensors connected to the cloud using IoT techniques. This approach was followed at the baroque church of Saint Thomas and Saint Philip Neri in Valencia (Spain). A set of 26 wireless nodes was installed, which recorded values of temperature and relative humidity every hour for a period of 7 months. Small differences of temperature were obtained among sensors, so that an efficient methodology based on principal component analysis (PCA) was applied for the characterization of similarities and dissimilarities between sensors. Daily ranges of temperatures were studied as well as mean trajectories, differences between days of the week, and changes in the correlation structure of daily median values over time. Results provide a framework for an efficient characterization of temperatures in heritage buildings based on a network of wireless sensors. Such a framework is useful to assess the potential risk of temperature fluctuations on the preventive conservation of historical buildings and artworks.

The monitoring and control of thermo-hygrometric indoor conditions is necessary for an adequate preservation of cultural heritage. The European standard EN 15757:2010 specifies a procedure for determining if seasonal patterns of relative humidity (RH) and temperature are adequate for the long-term preservation of hygroscopic materials on display at museums, archives, libraries or heritage buildings. This procedure is based on the characterization of the seasonal patterns and the calculation of certain control limits, so that it is possible to assess whether certain changes in the microclimate can be harmful for the preventive conservation of artworks, which would lead to the implementation of corrective actions. In order to discuss the application of this standard, 27 autonomous data-loggers were located in different points at the Archaeological Museum of l'Almoina (Valencia). The HVAC system (heating, ventilation and air conditioning) at the museum tries to reach certain homogeneous environment, which becomes a challenge because parts of the ruins are covered by a skylight that produces a greenhouse effect in summer, resulting in severe thermo-hygrometric gradients. Based on the analysis of temperatures recorded during 16 months, the air conditions in this museum are discussed according to the standard EN 15757:2010, and some corrective measures are proposed to improve the conservation conditions. Although this standard is basically intended for data recorded from a single sensor, an alternative approach proposed in this work is to find zones inside the museum with a homogeneous microclimate and to discuss next the average values collected in each area. A methodology is presented to optimize the application of this standard in places with a complex microclimate like this case, when multiple sensors are located at different positions.

In this work, time-series analyses of the chemical composition and source contributions of PM 2.5 from an urban background station in Barcelona (BCN) and a rural background station in Montseny (MSY) in northeastern Spain from 2009 to 2018 were investigated and compared. A multisite positive matrix factorization analysis was used to compare the source contributions between the two stations, while the trends for both the chemical species and source contributions were studied using the Theil-Sen trend estimator. Between 2009 and 2018, both stations showed a statistically significant decrease in PM 2.5 concentrations, which was driven by the downward trends of levels of chemical species and anthropogenic source contributions, mainly from heavy oil combustion, mixed combustion, industry, and secondary sulfate. These source contributions showed a continuous decrease over the study period, signifying the continuing success of mitigation strategies, although the trends of heavy oil combustion and secondary sulfate have flattened since 2016. Secondary nitrate also followed a significant decreasing trend in BCN, while secondary organic aerosols (SOA) very slightly decreased in MSY. The observed decreasing trends, in combination with the absence of a trend for the organic aerosols (OA) at both stations, resulted in an increase in the relative proportion of OA in PM 2.5 by 12% in BCN and 9% in MSY, mostly from SOA, which increased by 7% in BCN and 4% in MSY. Thus, at the end of the study period, OA accounted for 40% and 50% of the annual mean PM 2.5 at BCN and MSY, respectively. This might have relevant implications for air quality policies aiming at abating PM 2.5 in the study region and for possible changes in toxicity of PM 2.5 due to marked changes in composition and source apportionment., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2021 The Authors. Published by Elsevier B.V. All rights reserved.)

Since students and teachers spend much of their time in educational buildings, it is critical to provide good levels of indoor environmental quality (IEQ). The current COVID-19 pandemic has shown that maintaining a good indoor air quality level is an effective measure to control the transmission of the SARS-CoV-2 virus. This study used sensors to monitor key IEQ factors and assess several natural ventilation scenarios in a classroom of the University of Granada. Subsequently, the IEQ factors (temperature, relative humidity, CO 2 concentration, acoustic environment, and air velocity) were evaluated for the selected ventilation scenarios in the occupied classroom, and the field monitoring was carried out in two different assessment periods, winter and summer. The obtained results show that the CO 2 concentration levels were well below the recommended limits. However, the maintenance of the recommended thermal and acoustic IEQ factors was significantly affected by the natural ventilation strategies (temperature and relative humidity values were very close to the outside values, and the background sound pressure level was over 35 dBA during the entire assessment). The proper measurements and careful selection of the appropriate ventilation scenarios become of utmost importance to ensure that the ventilation rates required by the health authorities are achieved.

The baroque church of Saint Thomas and Saint Philip Neri (Valencia, Spain), which was built between 1727 and 1736, contains valuable paintings by renowned Spanish artists. Due to the considerable height of the central nave, the church can experience vertical temperature gradients. In order to investigate this issue, temperatures were recorded between August 2017 and February 2018 from a wireless monitoring system composed of 21 sensor nodes, which were located at different heights in the church from 2 to 13 m from the floor level. For characterizing the temperature at high, medium and low altitude heights, a novel methodology is proposed based on sparse Partial Least Squares regression (sPLS), Linear Discriminant Analysis (LDA), and the Holt-Winters method, among others, which were applied to a time series of temperature. This approach is helpful to discriminate temperature profiles according to sensor height. Once the vertical thermal gradients for each month were characterized, it was found that temperature reached the maximum correlation with sensor height in the period between August 10th and September 9th. Furthermore, the most important features from the time series that explain this correlation are the mean temperature and the mean of moving range. In the period mentioned, the vertical thermal gradient was estimated to be about 0.043 ∘C/m, which implies a difference of 0.47 ∘C on average between sensor nodes at 2 m from the floor with respect to the upper ones located at 13 m from the floor level. The gradient was estimated as the slope from a linear regression model using height and hourly mean temperature as the predictor and response, respectively. This gradient is consistent with similar reported studies. The fact that such gradient was only found in one month suggests that the mechanisms of dust deposition on walls involved in vertical thermal gradients are not important in this case regarding the preventive conservation of artworks. Furthermore, the methodology proposed here was useful to discriminate the time series at high, medium and low altitude levels. This approach can be useful when a set of sensors is installed for microclimate monitoring in churches, cathedrals, and other historical buildings, at different levels and positions.

The aim of the present study was to evaluate the relative attenuation of VIS, UV and NIR solar radiation through a large pond skylight into the interior of the l'Almoina Archaeological Museum (Valencia, Spain), and to determine how relative attenuation varied throughout the year and time of day. Measurements were taken at 9:00 a.m., 12:00 p.m. and 3:00 p.m. during July 2019 and January 2020. Relative attenuation values were obtained from the measurement of spectral irradiance in the exterior and at different points in the interior by means of two Ocean Optics spectrometers: HR4000CG-UV-NIR for VIS (400-700 nm) and NIR (700-1000 nm) bands, and FLAME-S-UV-VIS for UV-A (280-315 nm) and UV-A (315-400 nm) bands. The central points of the skylight had relative attenuation at 520 nm, reaching a value of 50% in summer at noon and 38% in the afternoon. At noon in winter, there were two relative attenuation peaks above 33% at 520 nm and at 900 nm. For mean relative attenuation, in the UVB range, the highest relative attenuation (20%) was inside the ruins in the morning in both summer and winter, and the UVA band relative attenuation was quite constant throughout the museum, but lower than that of the UVB band, in the range 0-3%.

Along the industrial process devoted to the production of titanium dioxide pigments by using ilmenite as main raw material, small residues amounts are generated, remaining clearly enriched in natural radionuclides and chemical pollutants. Between them, we can remark the scales enriched in both radium isotopes and lead, which are formed in the internal walls of pipes and some equipment. These scales are radiological anomalies that demand its mineralogical, elemental and radiometric characterization as a basis for a detailed radiological and toxicological assessment from the occupational and public point of view. In this work, several scales collected in a TiO 2 pigment production plant in South of Spain have been mineralogically characterized by XRD, while information about their elemental composition and morphology have been obtained by applying the XRF and SEM techniques. In addition, radiometric determinations have been performed by gamma-ray and alpha-particle spectrometry. The performed study indicates that the radiological doses received due to the scales by the workers performing its conventional activities are clearly lower than 1 mSv/y. Special dosimetric and chemical controls could be needed for the workers in charge of the maintenance labours (which include the removal of the scales) if these workers belong to an external company devoted to perform maintenance operations in several NORM industries., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2021 Elsevier Ltd. All rights reserved.)

An earlier study carried out in 2010 at the archaeological site of L'Almoina (Valencia, Spain) found marked daily fluctuations of temperature, especially in summer. Such pronounced gradient is due to the design of the museum, which includes a skylight as a ceiling, covering part of the remains in the museum. In this study, it was found that the thermal conditions are not homogeneous and vary at different points of the museum and along the year. According to the European Standard EN10829, it is necessary to define a plan for long-term monitoring, elaboration and study of the microclimatic data, in order to preserve the artifacts. With the aforementioned goal of extending the study and offering a tool to monitor the microclimate, a new statistical methodology is proposed. For this propose, during one year (October 2019-October 2020), a set of 27 data-loggers was installed, aimed at recording the temperature inside the museum. By applying principal component analysis and k-means, three different microclimates were established. In order to characterize the differences among the three zones, two statistical techniques were put forward. Firstly, Sparse Partial Least Squares Discriminant Analysis (sPLS-DA) was applied to a set of 671 variables extracted from the time series. The second approach consisted of using a random forest algorithm, based on the same functions and variables employed by the first methodology. Both approaches allowed the identification of the main variables that best explain the differences between zones. According to the results, it is possible to establish a representative subset of sensors recommended for the long-term monitoring of temperatures at the museum. The statistical approach proposed here is very effective for discriminant time series analysis and for explaining the differences in microclimate when a net of sensors is installed in historical buildings or museums.

The composition of PM 10 , including molecular markers of biomass burning (levoglucosan, mannosan and galactosan), was determined at a residential site in southeastern Spain during winter and early spring. The average PM 10 concentration was 25.0 μg m -3 , being organic carbon (OC, 6.77 μg m -3 ), NO 3 - (2.02 μg m -3 ), SO 4 2- (1.36 μg m -3 ) and Ca 2+ (1.01 μg m -3 ) the main components. Levoglucosan was the dominant anhydrosugar (143 ng m -3 ), accounting for 81% of the total concentration of monosaccharide anhydrides. The average contribution of biomass combustion to OC, estimated from the levoglucosan data, was 23%. This value agreed well with that calculated by Positive Matrix Factorization (PMF, 25%). The PMF model resolved six factors that were assigned to road traffic (28%), secondary aerosols (27%), soil dust (14%), fresh sea salt (13%), aged sea salt (10%) and biomass burning (8%). This model was used to estimate the OC/Levoglucosan and PM 10 /Levoglucosan emission ratios for the study area., (Copyright © 2020 Elsevier Inc. All rights reserved.)

Pollen grains emitted by urban vegetation are the main primary biological airborne particles (PBAPs) which alter the biological quality of urban air and have a significant impact on human health. This work analyses the interactions which exist between pollen-type PBAPs, meteorological variables, and air pollutants in the urban atmosphere so that the complex relationships and trends in future scenarios of changing environmental conditions can be assessed. For this study, the 1992-2018 pollen data series from the city of Granada (southeast Spain) was used, in which the dynamics of the total pollen as well as the 8 main pollen types (Cupressaceae, Olea, Pinus, Platanus, Poaceae, Populus, Quercus and Urticaceae) were analysed. The trend analysis showed that all except Urticaceae trended upward throughout the series. Spearman's correlations with meteorological variables showed that, in general, the most influential variables on the pollen concentrations were the daily maximum temperature, relative humidity, water vapor pressure, global radiation, and insolation, with different effects on different pollen types. Parallel analysis by neural networks (ANN) confirmed these variables as the predominant ones, especially global radiation. The correlation with atmospheric pollutants revealed that ozone was the pollutant with the highest influence, although some pollen types also showed correlation with NO 2 , SO 2 , CO and PM 10 . The Generalized Linear Models (GLM) between pollen and pollutants also indicated O 3 as the most prominent variable. These results highlight the active role that pollen-type PBAPs have on urban air quality by establishing their interactions with meteorological variables and pollutants, thereby providing information on the behaviour of pollen emissions under changing environmental conditions., (Copyright © 2021 Elsevier Ltd. All rights reserved.)

The main objective of this work was to quantify the impact of handling of bulk materials on PM 10 levels measured at the port-city border of Alicante (Spain), located on the western Mediterranean coast. To achieve that goal, 355 PM 10 samples were collected at the perimeter of the harbor of Alicante from March 2017 to February 2018. A 181 sample subgroup was chemically characterized in order to perform a source apportionment study with the EPA PMF 5.0 model. Eight factors were identified, two of them directly related to the handling of bulk materials (Limestone + gypsum and Clinker), accounting jointly for 35% of the average PM 10 concentration. A Road traffic factor was the second highest contributor to PM 10 levels (17%) while the Shipping emissions factor accounted for only 6% of the average PM 10 mass. Other factors such as Biomass burning+ secondary nitrate and Aged sea salt represented a joint contribution of 25% of the PM 10 mass. Results indicate that emission abatement strategies should primarily focus on the reduction of fugitive emissions caused by the handling of bulk materials at the docks. Moreover, scenarios including reductions of more than 50% in bulk handling sources and 10% in other anthropogenic sources would help to reduce anthropogenic exceedances of the daily PM 10 limit (50 μg·m -3 ) and to approach to WHO daily PM 10 standard (20 μg m -3 )., (Copyright © 2020 Elsevier Ltd. All rights reserved.)

Phosphogypsum (PG) is disposed worldwide in large stacks usually placed in coastal zones, as in the case of Huelva (SW of Spain), where around 100 Mt of PG are stored on the salt marshes of the Tinto River estuary covering a surface of about 1000 ha. This management generates the weathering of PG, and due to its high acidity (pH ≈ 2) and pollutant load can provoke significant emissions into their surroundings. In this work were evaluated by laboratory experiments the effects of pH increase in the behaviour of heavy metals and natural radionuclides during the mixing of phosphogypsum leachates with seawater. The acidic phosphogypsum leachates showed concentrations of heavy metals from two to three orders of magnitude higher than natural continental waters, and natural radionuclides (U-isotopes and 210 Po) from four to five orders of magnitude higher than unperturbed aquatic systems. Major elements and some heavy metals as Mn, Ni, Cd, As, Sb and Co showed a conservative behaviour during the neutralisation of the leachates with seawater, remaining in the liquid phase, while other ones as Al, Fe, Cr, Zn, Cu, Pb precipitated and/or were adsorbed onto the solid phase. The U-isotopes and 210 Po showed a clear non-conservative behaviour probably due to coprecipitation/adsorption processes onto the formed precipitates, but while 210 Po reached a total removal at pH ≈ 7, U- isotopes after a total removal at pH ≈ 5 returned into the liquid phase due to redissolution/desorption processes at near neutral pH. The formed precipitates, mainly composed by iron phosphates particles, showed heavy metal and natural radionuclide concentrations from one to three orders of magnitude higher than unperturbed soils. All these facts demonstrate the serious environmental impact produced by the PG stacks into their surroundings and the urgency of effective restoration measures., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2020 Elsevier Ltd. All rights reserved.)

Most of blood borne and airborne pathogens are highly contagious, harmful and have prevalence among healthcare workers. In this group, healthcare students, especially nursing undergraduates, have even higher risk to be exposed and suffered a contagious accident. One of the main pillars to prevent exposure to such pathogens and decrease accidents seems to be through education. A prospective observational educational research focused on quantifying the students' knowledge, and prevention culture was carried out. The educational approach based on the development of a technological tool, its integration in the students' education, and posterior assessment. The Chi-square, ANOVA, Kruskal-Wallis, Man-Whitney U, and Spearman correlations were used to determine the effect of such educational methodology. The results, previous to the integration of the educational approach, showed differences between the elementary and proficient knowledge and correct procedure in each academic year ( p < 0.05), being the best year the third academic year. The mean of elementary knowledge among second year students after the inclusion of the educational methodology improved for 2017/2018 with a mean of 7.5 (1.11) and in 2018/2019 with 7.87 (1.34). This study argued that the educational approach proposed could improve the prevention culture and knowledge among students and future healthcare professionals.

Adequate radiological protection requires the quantification of radionuclide transfer to the human food chain, which is essential for the estimation of ingestion doses. Transfer parameters are key inputs for the development of radioecological models and decision support systems. There are many literature compilations of these parameters, however, most of values were calculated in temperate climates, and data for Mediterranean ecosystems are scarce. In this study, transfer factors to foodstuffs collected in Mediterranean ecosystems, in Spain, were compared to reported values for temperate climate. Foodstuff included cereals, meat (beef, lamb and pork), dairy products (milk, cheese yogurt, and kefir), and also typical products of Mediterranean diet, such as olives, olive oil, grapes and wine. Radioactive ( 137 Cs, 226,228 Ra and 4 0  K) and stable elements (Cs, Sr, K, Na, Ca, Mg, P, Pb, U and Th) were measured to enable the calculation of transfer factors. As a consequence, data for transfer factors in Mediterranean systems were increased by about 120 and 200 values for plant and animal products, respectively. Due to the low level radiocaesium concentration in Spanish ecosystems, transfer factors for this radioisotope were largely 'less than' values. Therefore, stable Cs and Sr transfer factors were used as proxy for comparison with temperate values., (Crown Copyright © 2020. Published by Elsevier Ltd. All rights reserved.)

In the last two decades, due to the development of the information society, the massive increase in the use of information technologies, including the connection and communication of multiple electronic devices, highlighting Wi-Fi networks, as well as the emerging technological advances of 4G and 5G (new-generation mobile phones that will use 5G), have caused a significant increase in the personal exposure to Radiofrequency Electromagnetic Fields (RF-EMF), and as a consequence, increasing discussions about the possible adverse health effects. The main objective of this study was to measure the personal exposure to radiofrequency electromagnetic fields from the Wi-Fi in the university area of German Jordanian University (GJU) and prepare georeferenced maps of the registered intensity levels and to compare them with the basic international restrictions. Spot measurements were made outside the university area at German Jordanian University. Measurements were made in the whole university area and around two buildings. Two Satimo EME SPY 140 (Brest, France) personal exposimeters were used, and the measurements were performed in the morning and afternoon, and on weekends and weekdays. The total average personal exposure to RF-EMF from the Wi-Fi band registered in the three study areas and in the four days measured was 28.82 μW/m 2 . The average total exposure from the Wi-Fi band registered in the ten measured points of the university area of GJU was 22.97 μW/m 2 , the one registered in the eight measured points of building H was 34.48 μW/m 2 , and the one registered in the eight points of building C was 29.00 μW/m 2 . The maximum average values registered in the campus of GJU are below the guidelines allowed by International Commission on Non-ionizing Radiation Protection (ICNIRP). The measurement protocol used in this work has been applied in measurements already carried out in Spain and Mexico, and it is applicable in university areas of other countries.

Next to the city of Huelva (SW of Spain), around 100 Mt of phosphogypsum (PG) are stored in stacks on the salt-marshes of the Tinto River estuary covering a surface of about 1000 ha. Due to the high content of 238 U series natural radionuclides of the PG, its acidic nature (pH about 3), and the fact that PG stacks were disposed without any kind of isolation from the substrate, they could produce a potential radioactive impact into the underlying sediments. The aim of this work is to assess the pollution of the underlying sediments by natural radionuclides coming from the PG stacks. To this end, seven cores were taken, and PG and sediments samples collected at different depths were analysed. The activity concentrations of the main long half-live natural radionuclides of interest were determined by applying both gamma-ray and alpha-particle spectrometry radiometric techniques. The results of this study showed that the first decimeters of salt-marsh sediment act as a "barrier" for the radionuclides coming from the PG stacks decreasing rapidly its activity concentration in depth, affecting mainly sediments located in the first 20 cm below the contact due to mixing processes. While 230 Th, 226 Ra and 210 Pb pollution is mainly restricted to the first 20 cm of sediments, U-isotopes can reach higher depths (up to around 50 cm) by leaching processes due to their lower reactivity and higher concentration in the polluted leachates. The obtained results have high relevance for the design of the perimeter channel which is projected to build in the restoration project, suggesting that should has around 1 m deep under the base of the PG stacks, to ensure the full collection of polluting leachates, and to prevent their release into the estuary of the Tinto River., (Copyright © 2019 Elsevier Ltd. All rights reserved.)

Several studies have characterized personal exposure to RF-EMF, which allows possible effects on health to be studied. All equipment has a detection limit, below which we obtain nondetects or censored data. This problem is a challenge for researchers as it makes the analysis of such data complex. We suggest reconsidering the statistical protocols of the nondetects analysis by comparing four different methods. Three of them substitute censored data using different approaches: regression on order of statistics (ROS) to simulate data below the detection limit (Method 1), substituting nondetect values by the detection limit divided by 2 (Method 2), a naïve calculation (Method 3) using the detection limit as a valid measurement. The fourth method consists of considering censored data to be missing values (Method 4). This article examines how these methods affect the quantification of personal exposure. We considered data from 14 frequency bands from FM to WiMax measured in Albacete (Spain) for 76 days every 10 s by a personal exposimeter (PEM) Satimo EME Spy 140.Methods 3 and 2 gave similar mean and median values to Method 1, but both underestimated the mean values when high nondetects records occurred, which conditioned the physical description of the real situation. The mean values calculated by Method 4 differed from those obtained by Method 1 but were similar when the percentage of nondetects was below 20%.Our comparison suggests that nondetects can be neglected when the percentage of censored data is low to provide a more realistic physical situation.

Organic carbon (OC) and elemental carbon (EC) concentrations were measured in PM 1 and PM 10 daily samples collected at an urban station in Elche (southeastern Spain) from February 2015 to February 2018. The effect of seasonal weather conditions, traffic, and specific pollution events (Saharan dust outbreaks and local pollution episodes) on the variability of carbonaceous aerosol levels was studied in this work. The joint contribution of carbonaceous species to PM 1 and PM 10 mass concentrations was, respectively, 48% and 26%. Both OC and EC concentrations were higher in winter than in summer because of the poor dispersion conditions and lower temperatures leading to the condensation of semivolatile species. Secondary organic carbon (SOC), estimated using the EC tracer method, also exhibited higher concentrations during winter, indicating that the prevailing meteorological conditions during the cold season are more favorable for the formation of secondary organic aerosols. Our results suggest different formation pathways of secondary organic components during summer and winter. At the sampling site, EC was primarily derived from traffic emissions, independently of the season and the type of event, with a modest contribution from biomass burning (<20%). The estimated contribution from this source to OC levels was similar. Local pollution episodes lead to a significant increase in the concentrations of carbonaceous species, in particular of SOC, influencing its temporal variation. On average, African dust outbreaks showed a moderate impact on the levels of carbonaceous aerosols; however, the effect was significantly stronger during winter Saharan events., (Copyright © 2019 The Authors. Published by Elsevier Ltd.. All rights reserved.)

In the salth-marshes of the Tinto River (Huelva estuary, SW Spain), are stored in stacks around 100 Mt of PG, covering a surface of 1000 ha without any type of isolation, which produce an important impact in the surrounding environment. On the other hand, this ecosystem it is affected by acid mine drainage (AMD) from sulphide mines located upstream the Tinto River. The aim of this study is to evaluate the deep pollution of the underlain salt-marsh sediments due to leachates from the PG stacks. For that purpose, 7 cores were collected from zones 2 and 3 of the stacks, and PG and salt-marsh sediments samples from different depths were analyzed. The physicochemical parameters, mineralogy, granulometry and the concentration of the main elements of interest were determined in the samples. Most analysed salt-marsh sediments are not affected by PG stacks pollution, because sediments act as a "barrier" for the leachates from the PG, concentrating the contaminants in the first decimetres (0.5 m) under PG-sediments contact, and the deep infiltration is very limited. The obtained results suggest that the perimeter channel which is projected to build in the restauration project, should has a depth of 1 m below the level of the PG stacks for assuring the complete collection of leachates from the stacks, and avoid their liberation into the Tinto River estuary., (Copyright © 2019 Elsevier Ltd. All rights reserved.)

Techniques of remote sensing are being used to develop phenological studies. Our goal is to study the correlation among the Normalized Difference Vegetation Index (NDVI) related with oak trees included in three set data polygons (15, 25 and 50 km to aerobiological sampling point as NDVI-15, 25 and 50), and oak (Quercus) daily average pollen counts from 1994 to 2013. The study was developed in the SW Mediterranean region with continuous pollen recording within the mean pollen season of each studied year. These pollen concentrations were compared with NDVI values in the locations containing the vegetation under a study based on two cartographic sources: the Extremadura Forest Map (MFEx) of Spain and the Fifth National Forest Inventory (IFN5) from Portugal. The importance of this work is to propose the relationship among data related in space and time by Spearman and Granger causality tests. 9 out of 20 studied years have shown significant results with the Granger causality test between NDVI and pollen concentration, and in 12 years, significant values were obtained by Spearman test. The distances of influence on the contribution of Quercus pollen to the sampler showed statistically significant results depending on the year. Moreover, a predictive model by using Artificial Neural Network (ANN) was applied with better results in NDVI25 than for NDVI15 or NDVI50. The addition of NDVI25 with the lag of 5 days and some weather parameters in the model was applied with a RMSE of 4.26 (Spearman coefficient r = 0.77) between observed and predicted values. Based on these results, NDVI seems to be a useful parameter to predict airborne pollen., (Copyright © 2019. Published by Elsevier B.V.)

Background: In recent years, radiofrequency electromagnetic fields (RF-EMF) exposure has increased owing to new communication technologies. Simultaneously, increased exposure to RF-EMF has led to society's growing concern about the possible effects they may have on human health. Many studies have described personal RF-EMF exposure by using personal exposimeters to know a population's daily exposure to mobile phone base stations and to other sources whose installations tend to be permanent. Nonetheless during special events like concerts or fairs, where many people gather, permanent installations might not suffice to cover demand. So telephone companies install temporary stations for these events, and modify the exposure pattern of these areas or populations., Objective: To study if installing temporary antennae for large events, and high concentrations of mobile phones, modify the exposure pattern compared to usual situations., Methods: Personal RF-EMF exposure from mobile phones (uplink) and mobile phone base stations (downlink) installed at the 2017 Albacete Fair (Spain) was recorded. Between 7 and 17 September, more than 2,500,000 people visited this Fair. Measurements were taken by two Satimo EME SPY 140 personal exposimeters, placed one each side of a research team member's waist. These exposimeters were programmed to take measurements every 4 s at different time of day; morning, afternoon and night; and in several places, around the Fair Enclosure (zones Ejidos and Paseo) and inside the enclosure (Interior). These measurements were repeated on a weekday, at the weekend and the day after the Fair ended after temporary base stations had been removed. They were also taken for 1 h in all three zones, for each time of day; that is, 9 h were recorded for each study day., Results: The mean RF-EMF recorded exposure from base stations (downlink-DL) on the days the Fair opened (morning, afternoon and night) for the three studied zones was 791.8 μW/m 2 , while the exposure produced by mobile phones (uplink-UL) was 59.0 μW/m 2 . These values were 391.2 μW/m 2 (DL) and 10.3 μW/m 2 (UL) a few days after the event ended. In study zones Ejidos and Paseo, both outside, the highest mean exposure was recorded at the weekend as 1494.1 and 848.1 μW/m 2 respectively. For the Interior zone, the mean value recorded during the Fair was 354.8 μW/m 2 . These values contrast with those recorded in the three zones after the event ended: 556.37 (Ejidos), 144.1 (Paseo); 473.21 μW/m 2 (Interior). The fact that the mean exposure recorded at Interior was slightly higher after the Fair could be due to signal shielding by so many people. The reduction in exposure in Paseo after the Fair was outstanding, probably due to the antennae being placed on low towers. Major differences were also found in the RF-EMF exposure from UL. In this case, the weekend values taken during the Fair were between 28.2 μW/m 2 at Interior (weekday) and 98.1 μW/m 2 at Ejidos (weekend), which dropped to 5.5 at Paseo after the Fair, to 11.7 μW/m 2 at Interior and to 13.6 μW/m 2 at Ejidos., Conclusions: Installing mobile phone base stations, and a dense public using mobile phones, imply a significant increase in personal RF-EMF exposure compared to that recorded during normal periods in the same area. However, the recorded measurements were below legally established limits., (Copyright © 2019 Elsevier Inc. All rights reserved.)

In the last decades, exposure to radiofrequency electromagnetic fields (RF-EMF) has substantially increased as new wireless technologies have been introduced. Society has become more concerned about the possible effects of RF-EMF on human health in parallel to the increase in their exposure. The appearance of personal exposimeters opens up wide-ranging research possibilities. Despite studies having characterised personal exposure to RF-EMF, part of the population is still worried, to the extent that psychogenic diseases ("nocebo" effect) appear, and patients suffer. It could be interesting to share personal exposure results with the population to better understand and promote public health. The main objective was to characterise personal exposure to environmental RF-EMF in Albacete (166,000 inhabitants, SE Spain), and assess the effect of sharing the results of the study on participants' risk perception. Measurements were taken by a personal Satimo EME SPY 140 exposimeter, which was programmed every 10 s for 24 h. To measure personal exposure to RF-EMF, we worked with 75 volunteers. Their personal exposure, 14 microenvironments in the city, e.g., home, outdoors, work, etc., and possible time differences were analysed. After participating in the study, 35 participants completed a questionnaire about their RF-EMF risk perception, which was also answered by a control sample to compare the results (N = 36). The total average exposure of 14 bands was 37.7 μW/m 2 , and individual ranges fell between 0.2 μW/m 2 , recorded in TV4&5, and a maximum of 264.7 μW/m 2 in DECT. For Friday, we recorded a mean of 53.9 μW/m 2 as opposed to 23.4 μW/m 2 obtained on Saturday. The recorded night-time value was 27.5 μW/m 2 versus 43.8 μW/m 2 recorded in the daytime. The mean personal exposure value also showed differences between weekdays and weekend days, with 39.7 μW/m 2 and 26.9 μW/m 2 , respectively. The main source that contributed to the mean total personal exposure was enhanced cordless telecommunications (DECT) with 50.2%, followed by mobile phones with 18.4% and mobile stations with 11.0% (GSM, DCS and UMTS), while WiFi signals gave 12.5%. In the analysed microenvironments, the mean exposure of homes and workplaces was 34.3 μW/m 2 and 55.2 μW/m 2 , respectively. Outdoors, the mean value was 34.2 μW/m 2 and the main sources were DECT, WiFi and mobile phone stations, depending on the place. The risk perception analysis found that 54% of the participants perceived that RF-EMF were less dangerous than before participating in the study, while 43% reported no change in their perceptions. Only 9% of the volunteers who received information about their measurements after the study assessed the possible RF-EMF risk with a value over or equal to 4 (on a scale from 1 to 5) versus 39% of the non-participant controls. We conclude that personal exposure to RF-EMF fell well below the limits recommended by ICNIRP and showed wide temporal and spatial variability. The main exposure sources were DECT, followed by mobile phones and WiFi. Sharing exposure results with participants lowered their risk perception., (Copyright © 2019 Elsevier Inc. All rights reserved.)

7 Be, 210 Pb and PM 10 levels in surface air have been simultaneously measured at two sampling sites in the southern Iberian Peninsula for a period of two years. Each site covers one different meteorological area of the Guadalquivir valley, from the mouth (Huelva) to the middle point (Cordoba). The objective of the present study is to analyse the spatial variability of both natural radionuclides, and to identify and characterise the meteorological patterns associated with similar and different surface concentration levels in this complex region. Concentrations are similar in both sampling sites. 7 Be level is in the 0.6-15.5 mBq m -3 range in Huelva and 1.2-13.3 mBq m -3 in Córdoba, 210 Pb activity concentrations are between 0.04 and 2.30 mBq m -3 in Huelva, and between 0.03 and 1.2 mBq m -3 in Cordoba, and PM 10 concentrations are found to be in the 5.1-81.3 μg m -3 range in Huelva, and 8.2-76.3 μg m -3 in Cordoba, respectively. A linear regression analysis indicates more regional variability for 210 Pb than for 7 Be between simultaneous measurements. Principal components analysis (PCA) is applied to the datasets and the results reveal that aerosol behaviour is mainly represented by two components, which explain 82% of the total variance. The analysis of surface measurements and meteorological parameters revealed that component F1 groups sampling periods in which the influence of similar meteorological conditions over the region lead to similar 7 Be, 210 Pb and PM 10 concentration levels in both sampling sites. On the other hand, component F2 detaches the 7 Be, 210 Pb and PM 10 concentration levels between monitoring sites, and the meteorological analysis shows how surface concentrations within this component are associated with the development of different mesoscale circulations in each part of the valley. The identification of sampling periods characterised by differences in surface concentrations and wind patterns between stations suggests that the valley could not be considered as one single unit for certain meteorological scenarios. These results evidence how the understanding of wind characteristics within a complex terrain provide some essential knowledge in the regionalization and/or optimization of monitoring networks., (Copyright © 2018 Elsevier Ltd. All rights reserved.)

Exposure to moisture-damaged indoor environments is associated with adverse respiratory health effects, but responsible factors remain unidentified. In order to explore possible mechanisms behind these effects, the oxidative capacity and hemolytic activity of settled dust samples (n = 25) collected from moisture-damaged and non-damaged schools in Spain, the Netherlands, and Finland were evaluated and matched against the microbial content of the sample. Oxidative capacity was determined with plasmid scission assay and hemolytic activity by assessing the damage to isolated human red blood cells. The microbial content of the samples was measured with quantitative PCR assays for selected microbial groups and by analyzing the cell wall markers ergosterol, muramic acid, endotoxins, and glucans. The moisture observations in the schools were associated with some of the microbial components in the dust, and microbial determinants grouped together increased the oxidative capacity. Oxidative capacity was also affected by particle concentration and country of origin. Two out of 14 studied dust samples from moisture-damaged schools demonstrated some hemolytic activity. The results indicate that the microbial component connected with moisture damage is associated with increased oxidative stress and that hemolysis should be studied further as one possible mechanism contributing to the adverse health effects of moisture-damaged buildings., (© 2018 John Wiley & Sons A/S. Published by John Wiley & Sons Ltd.)

One of the diseases that could affect diabetic patients is the diabetic foot problem. Unnoticed minor injuries and subsequent infection can lead to ischemic ulceration, and may end in a foot amputation. Preliminary studies have shown that there is a positive relationship between increased skin temperature and the pre⁻ulceration phase. Hence, we have carried out a review on wearables, medical devices, and sensors used specifically for collecting vital data. In particular, we are interested in the measure of the foot⁻temperature. Since there is a large amount of this type of medical wearables, we will focus on those used to measure temperature and developed in Spain.

Cosmogenic radionuclides provide information about air masses exchanges between stratosphere and troposphere. The 7 Be concentration in aerosols usually shows a seasonal variability, depending also of the climatic conditions. There are, however, fewer data available of the behavior of other cosmogenic radionuclides, such as 10 Be and 22 Na. In this work about 7 years of aerosols collected in Cáceres (Spain) were analyzed. The 7 Be concentration was higher than 22 Na and 10 Be, being the 22 Na/ 7 Be and 10 Be/ 7 Be ratios (1.16 ± 0.02)·10 -4 and (1.5 ± 0.3)·10 -4 respectively. For the 22 Na/ 7 Be, a seasonal variation was observed, being higher in spring/summer. Seasonal variation of 7 Be and 22 Na were explained using a model taking into account local values of the solar radiation, rainfall and dry deposition. The effective residence time for 7 Be and 22 Na were (9.9 ± 1.0) and (11.3 ± 1.4) d respectively. Both 7 Be and 22 Na seemed to decrease with increasing number of sunspots, although it was not statistically significant probably due to the low solar activity reported in the analyzed period., (Copyright © 2018 Elsevier Ltd. All rights reserved.)

This work analyses levels of particles PM10 and PM2.5 recorded at four air-quality monitoring stations located in the urban area of Valladolid (Spain) during 2015-2016. To achieve this, the evolution of particle concentrations at different time scales was determined. Average concentrations ranged from 15.3 to 17.6 µg m -3 for PM10 and between 8.9 and 14.8 µg m -3 for PM2.5. The highest monthly means were recorded in autumn and winter. The difference between mean concentrations at weekends and on weekdays for PM10 was around 3 µg m -3 at most of the measuring stations and was 1 µg m -3 for PM2.5. Two concentration peaks were found during the day, one in the morning and the other in the evening, which evidenced the influence of traffic and other anthropogenic activities on PM concentrations. Their mean values were approximately 21 and 17-21 µg m -3 , respectively, for PM10. Mean maximum values for PM2.5 were 12 µg m -3 , except at one of the measuring sites, with 17 µg m -3 for the morning maximum and 1 µg m -3 more for the nocturnal peak. In addition, the impact of long-distance transport of air masses in the study area was analysed by applying a HYSPLIT trajectory model, taking into account backward trajectories of European, African, and Atlantic origins as well as local conditions. In particular, high concentration events due to Saharan dust intrusions are presented. Finally, background levels of particle concentrations estimated at most sampling areas were around 15 and 7.7 µg m -3 for the PM10 and PM2.5 particle fractions, respectively.

The evaluation of the radiological impact in soils due to the fly-ash ponds using both in situ techniques and laboratory based measurements is presented. In order to check the in situ techniques capabilities for monitoring this type of industries, a comparison between both techniques was performed. A characterization of external radiation exposure in the fly-ash pond and in its surrounding soils was made. The associated external radiological hazard due to the fly-ash pond has been evaluated. In situ techniques could be used to determine the radiological impact on soils due to fly-ash deposition, but its use could be limited due to the associated uncertainties.

Fungi belonging to the genus of Alternaria are recognised as being significant plant pathogens, and Alternaria allergens are one of the most important causes of respiratory allergic diseases in Europe. This study aims to provide a detailed and original analysis of Alternaria transport dynamics in Badajoz, SW Spain. This was achieved by examining daily mean and hourly observations of airborne Alternaria spores recorded during days with high airborne concentrations of Alternaria spores (>100 s m(-3)) from 2009 to 2011, as well as four inventory maps of major Alternaria habitats, the overall synoptic weather situation and analysis of air mass transport using Hybrid Single Particle Lagrangian Integrated Trajectory model and geographic information systems. Land use calculated within a radius of 100 km from Badajoz shows that crops and grasslands are potentially the most important local sources of airborne Alternaria spores recorded at the site. The results of back trajectory analysis show that, during the examined four episodes, the two main directions where Alternaria source areas were located were: (1) SW-W; and (2) NW-NE. Regional scale and long distance transport could therefore supplement the airborne catch recorded at Badajoz with Alternaria conidia originating from sources such as crops and orchards situated in other parts of the Iberian Peninsula., (Published by Elsevier B.V.)

The relationship between the particulate matter in the atmosphere of Malaga and the origin of air masses with special attention to African intrusions was analyzed. The concentrations of PM10 and the activities of some radionuclides ((7)Be and (210)Pb) as tracers of these intrusions are discussed. The origin of these radiotracers is completely different. (210)Pb is a good tracer of air masses traveling close to the ground and come from inland areas. On the other hand, the production of (7)Be is very low in the vicinity of the Earth's surface, and increases with altitude, making it a great tracer of stratospheric air masses in the troposphere. Studies of radionuclide activities in aerosol particles provide a means for evaluating the integrated effects of transport and meteorology on the atmospheric loadings of substances with different sources. Measurements of aerosol mass concentration and specific activities of (7)Be and (210)Pb in aerosols at Malaga (36° 43' 40″ N; 4° 28' 8″ W) for the period 2009-2011 were used to obtain the relationships between radionuclide activities and airflow patterns by comparing the data grouped by air mass trajectory. The average concentration values of (7)Be and (210)Pb over the 3-year period have been found to be 5.05 and 0.55 mBq m(-3), respectively, with mean aerosol mass concentration of 53.6 μg m(-3). Taking into account the outbreaks of the daily values limits of PM10 in the study period (2009-2011), the origin of air masses is studied to explain three different situations of both radionuclides (7)Be and (210)Pb: 1) high concentrations of (7)Be and low concentrations of (210)Pb; 2) high concentrations of (210)Pb and low concentrations of (7)Be and 3) high concentrations of (7)Be and (210)Pb., (Copyright © 2015 Elsevier Ltd. All rights reserved.)

Airborne pollen transport at micro-, meso-gamma and meso-beta scales must be studied by atmospheric models, having special relevance in complex terrain. In these cases, the accuracy of these models is mainly determined by the spatial resolution of the underlying meteorological dataset. This work examines how meteorological datasets determine the results obtained from atmospheric transport models used to describe pollen transport in the atmosphere. We investigate the effect of the spatial resolution when computing backward trajectories with the HYSPLIT model. We have used meteorological datasets from the WRF model with 27, 9 and 3 km resolutions and from the GDAS files with 1° resolution. This work allows characterizing atmospheric transport of Olea pollen in a region with complex flows. The results show that the complex terrain affects the trajectories and this effect varies with the different meteorological datasets. Overall, the change from GDAS to WRF-ARW inputs improves the analyses with the HYSPLIT model, thereby increasing the understanding the pollen episode. The results indicate that a spatial resolution of at least 9 km is needed to simulate atmospheric flows that are considerable affected by the relief of the landscape. The results suggest that the appropriate meteorological files should be considered when atmospheric models are used to characterize the atmospheric transport of pollen on micro-, meso-gamma and meso-beta scales. Furthermore, at these scales, the results are believed to be generally applicable for related areas such as the description of atmospheric transport of radionuclides or in the definition of nuclear-radioactivity emergency preparedness.

The Tinto River estuary is highly polluted with the acid lixiviates from old sulphide mines. In this work the behaviour of dissolved and particulate trace metals under strong chemical gradients during a tidal cycle is studied. The pH values range from 4.4 with low tide to 6.9 with high tide. Precipitation of Fe and Al is intense during rising tides and As and Pb are almost exclusively found in the particulate matter (PM). Sorption processes are very important in controlling the mobility (and hence bioavailability) of some metals and particularly affect Cu below pH 6. Above pH~6 Cu is desorbed, probably by the formation of Cu(I)-chloride complexes. Although less pronounced than Cu, also Zn desorption above pH 6.5 seems to occur. Mn and Co are affected by sorption processes at pH higher than ca. 6. Cd behaves conservatively and Ni is slightly affected by sorption processes., (Copyright © 2014 Elsevier B.V. All rights reserved.)

The possible connectivity between the spatial distribution of water bodies suitable for vectors of malaria and endemic malaria foci in Southern Europe is still not well known. Spain was one of the last countries in Western Europe to be declared free of malaria by the World Health Organization (WHO) in 1964. This study combines, by means of a spatial-temporal analysis, the historical data of patients and deceased with the distribution of water bodies where the disease-transmitting mosquitos proliferate. Therefore, data from historical archives with a Geographic Information System (GIS), using the Inverse Distance Weighted (IDW) interpolation method, was analyzed with the aim of identifying regional differences in the distribution of malaria in Spain. The reasons, why the risk of transmission is concentrated in specific regions, are related to worse socioeconomic conditions (Extremadura), the presence of another vector (Anopheles labranchiae) besides A. atroparvus (Levante) or large areas of water bodies in conditions to reproduce theses vectors (La Mancha and Western Andalusia). In the particular case of Western Andalusia, in 1913, the relatively high percentage of 4.73% of the surface, equal to 202362 ha, corresponds to wetlands and other unhealthy water bodies. These wetlands have been reduced as a result of desiccation policies and climate change such as the Little Ice Age and Global Climate Change. The comprehension of the main factors of these wetland changes in the past can help us interpret accurately the future risk of malaria re-emergence in temperate latitudes, since it reveals the crucial role of unhealthy water bodies on the distribution, endemicity and eradication of malaria in southern Europe.

The term "commercial granite" comprises different natural stones with different mineralogical components. In Extremadura, western Spain, "commercial granites" can be classified in three types: granite s.s. (sensus stricti), granodiorite, and diorite. The content of naturally occurring radionuclides depended of the mineralogy. Thus, the (40)K content increased as the relative content of alkaline feldspar increased but decreased as the plagioclase content increased. The radioactive content decreased in the following order: granite s.s. > granodiorite > diorite. In this work, the radiological hazard of these granites as building material was analyzed in terms of external irradiation and radon exposure. External irradiation was estimated based on the "I" index, ranged between 0.073 and 1.36. Therefore, these granites can be use as superficial building materials with no restriction. Radon exposure was estimated using the surface exhalation rates in polished granites. The exhalation rate in granites depends of their superficial finishes (different roughness). For distinct mechanical finishes of granite (polish, diamond sawed, bush-hammered and flamed), the surface exhalation rate increased with the roughness of the finishes. Thermal finish presented the highest exhalation rate, because the high temperatures applied to the granite may increase the number of fissures within it. The exhalation rates in polished granites varied from 0.013 to 10.4 Bq m(-2) h(-1)., (Copyright © 2014 Elsevier Ltd. All rights reserved.)

This paper describes a comprehensive study of the behaviour of U in the Ría of Huelva estuary, formed by the Tinto and Odiel rivers. This ecosystem is conditioned by two hydrochemical facts: one connected with the acid mining drainage (AMD) generated in the first section of the river basins, and another one related to the fertilizer industry located at the estuary. AMD gives a singular character to these rivers; low pH and high redox potential that keep high amounts of toxic elements and radionuclides in dissolution. Most of the data for dissolved U in estuaries indicate conservative mixing, but there are examples of non-conservative behaviour attributed to oxidation/reduction processes or solubility variations. In the Ría of Huelva estuary the U shows a non-conservative behaviour due to solubility changes produced by variations in the pH. A complete removal of riverine dissolved U is observed in a pH range of 4-6. At higher pH values, U release from suspended matter, and probably also from sediments into the dissolved phase is found., (Copyright © 2013 Elsevier Ltd. All rights reserved.)

CO₂ concentrations recorded for two years using a Picarro G1301 analyser at a rural site were studied applying two procedures. Firstly, the smoothing kernel method, which to date has been used with one linear and another circular variable, was used with pairs of circular variables: wind direction, time of day, and time of year, providing that the daily cycle was the prevailing cyclical evolution and that the highest concentrations were justified by the influence of one nearby city source, which was only revealed by directional analysis. Secondly, histograms were obtained, and these revealed most observations to be located between 380 and 410 ppm, and that there was a sharp contrast during the year. Finally, histograms were fitted to 14 distributions, the best known using analytical procedures, and the remainder using numerical procedures. RMSE was used as the goodness of fit indicator to compare and select distributions. Most functions provided similar RMSE values. However, the best fits were obtained using numerical procedures due to their greater flexibility, the triangular distribution being the simplest function of this kind. This distribution allowed us to identify directions and months of noticeable CO₂ input (SSE and April-May, respectively) as well as the daily cycle of the distribution symmetry. Among the functions whose parameters were calculated using an analytical expression, Erlang distributions provided satisfactory fits for monthly analysis, and gamma for the rest. By contrast, the Rayleigh and Weibull distributions gave the worst RMSE values., (Copyright © 2013 Elsevier B.V. All rights reserved.)

The aim of this work was to detect the presence of Basidiomycetes spores (basidiospores, teliospores, uredospores and aeciospores) in Mérida (SW Spain) and assess the influence of weather parameters. Air was sampled continuously with a volumetric seven-day Burkard spore trap for two years. Fungi spores were identified and counted at x1,000 microscope resolution. Daily and weekly meteorological data and airborne spore concentration were analysed. Twenty-three spores types were identified, including basidiospores (Amanita, Agrocybe, Cortinarius, Coprinus -2 types-, Boletus, Bovista, Calvatia, Entoloma, Ganoderma, Inocybe, Russula, Scleroderma, Telephora), teliospores (Phragmidium, Tilletia, Ustillago -4 types-), uredospores, and aeciospores (2 types), all of these types of spores included different taxa. Average concentration was of 616 spores/m(3), with maximum concentration in autumn (October), and a second concentration in spring (May-June); however, some spore types were more frequent in summer (Bovista, Ganoderma) or even in winter (Entoloma, Calvatia). The Amanita type was the most frequent (white-hyaline basidiospores); the second were teliospores of Ustilago, the third spore type was basidiospores of Coprinus (blackish basidiospores) and Agrocybe type (smoothed light to dark coloured basidiospores). Basidiospore concentration was positively correlated with temperature and negatively with relative humidity in most cases, and Ustilago teliospores concentration was positively correlated with wind speed. Differences in monthly rain were probably the origin between years. Airborne spores of Basidiomycetes may be separated into more than 20 types, and their seasonal concentration depended on meteorology as well as whether they were saprotrophic or parasitic.

CO(2) transport in the low atmosphere near the surface at night was analysed using spatial procedures applied to back trajectories. Concentration and meteorological data were obtained at a rural site during a seven and a half month campaign. Daily evolution of CO(2) skewness showed positive values during the night and negative values during the day. One concentration and one recirculation factor, an indicator of local recirculation, were associated with each back trajectory calculated during the night to study source and meteorological influences on concentrations recorded. Moreover, four procedures were used to analyse the trajectories, and their strengths and weaknesses were also investigated. (1) The nonparametric trajectory analysis applied with two weight functions successfully marked the most contributing region. (2) Hexagonal cells were used to account for radial distribution of trajectories. The potential source contribution function calculated in these cells highlighted the influence of the source against meteorology, this procedure therefore proving the best to mark the source direction. (3) Trajectory sector analysis revealed the most contributing wind sector and emphasised the role of recirculation in the E-S sectors. (4) Cluster analysis grouped neighbouring trajectories and was the most flexible procedure to classify them, providing a contrast of around 12 ppm between medians obtained in the SE cluster and the least contributing group., (Copyright © 2012 Elsevier Ltd. All rights reserved.)

This paper presents measurements of the effect of the atmospheric radioactive release from the Fukushima Dai-ichi nuclear power station at three sites belonging to the Spanish environmental monitoring system. Measured values varied depending on the locations of the sites in Spain and their respective climatic characteristics. (134)Cs, (136)Cs, (137)Cs, (131)I, and (132)Te activity concentrations in filter samples were studied and associated levels of (131)I fallout were estimated from wet and dry deposition. Particulate aerosol activity concentrations ranges, in μBq/m(3), were 1.63-3080 ((131)I), 2.8-690 ((137)Cs), 1.3-620 ((134)Cs) and 3.6-330 ((132)Te), while the associated (131)I fallout was roughly estimated to be less than 20 Bq/m(2), Gaseous (131)I was also detected and the (131)I-gaseous/(131)I-total ratio increased at the three stations from approximately 0.75 at the end of March to 0.85-0.9 during the first few days of April. Finally, the presence of (131)I in some crucial parts of the food chain was also studied. (131)I was detected in samples from goat's and cow's milk (maximum levels of 1.11 Bq/L) and in broadleaf plants (maximum level 1.42 Bq/kg)., (Copyright © 2012 Elsevier Ltd. All rights reserved.)