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The spatial distribution of per- and polyfluoroalkyl compounds (PFCs) were investigated in coastal waters collected onboard research vessel Snow Dragon from the East to South China Sea in 2010. All samples were prepared by solid-phase extraction and analyzed using high performance liquid chromatography/negative electrospray ionization-tandem mass spectrometry (HPLC/(−)ESI-MS/MS). Concentrations of 9 PFCs, including C4 and C8 (PFBS, PFOS) perfluoroalkyl sulfonate (PFSAs), C5–C9 and C13 (PFPA, PFHxA, PFHpA, PFOA, PFNA, PFTriDA) perfluoroalkyl carboxylates (PFCAs), and N-ethyl perfluorooctane sulfonamide (EtFOSA) were quantified. The ΣPFC concentrations ranged from 133 pg/L to 3320 pg/L, with PFOA (37.5–1541 pg/L), PFBS (23.0–941 pg/L) and PFHpA (0–422 pg/L) as dominant compounds. Concentrations of PFCs were greater in coastal waters along Shanghai, Ningbo, Taizhou, Xiamen and along coastal cities of the Guangdong province compared to less populated areas along the east Chinese coast. Additionally, the comparison with other seawater PFC measurements showed lower levels in this study. [Copyright &y& Elsevier]

Abstract: Here we present interannual rare earth element (REE) records spanning the last two decades of the 20th century in two living Porites corals, collected from Longwan Bay, close to the estuarine zones off Wanquan River of Hainan Island and Hong Kong off the Pearl River Delta of Guangdong Province in the northern South China Sea. The results show that both coral REE contents (0.5–40 ng g−1 in Longwan Bay and 2–250 ng g−1 in Hong Kong for La–Lu) are characterized with a declining trend, which are significantly negative correlated with regional sea-level rise (9.4 mm a−1 from 1981 to 1996 in Longwan Bay, 13.7 mm a−1 from 1991 to 2001 in Hong Kong). The REE features are proposed to be resulted from seawater intrusion into the estuaries in response to contemporary sea-level rise. However, the tendency for the coral Er/Nd time series at Hong Kong site is absent and there is no significant relation between Er/Nd and total REEs as found for the coral at Longwan Bay site. The observations are likely attributed to changes of the water discharge and sediment load of Pearl River, which have been significantly affected by intense human activities, such as the construction of dams/reservoirs and riverbed sediment mining, in past decades. The riverine sediment load/discharge ratio of the Pearl River decreased sharply with a rate of 0.02 kg m−3 a−1, which could make significant contribution to the declining trend of coral REE. We propose that coastal corals in Longwan Bay and similar unexplored sites with little influences of river discharge and anthropogenic disruption are ideal candidates to investigate the influence of sea-level change on seawater/coral REE. [ABSTRACT FROM AUTHOR]

Abstract: We used positive thermal ionization mass spectrometry (PTIMS) to generate high precision δ11B records in Porites corals of the mid-late Holocene from the South China Sea (SCS). The δ11B values of the Holocene corals vary significantly, ranging from 22.2‰ to 25.5‰. The paleo-pH records of the SCS, reconstructed from the δ11B data, were not stable as previously thought but show a gradual increase from the Holocene thermal optimal and a sharp decrease to modern values. The latter is likely caused by the large amount of anthropogenic CO2 emissions since the Industrial Revolution but variations of atmospheric pCO2 cannot explain the pH change of the SCS before the Industrial Revolution. We suggest that variations of monsoon intensity during the mid-late Holocene may have driven the sea surface pH increase from the mid to late Holocene. Results of this study indicate that the impact of anthropogenic atmospheric CO2 emissions may have reversed the natural pH trend in the SCS since the mid-Holocene. Such ocean pH records in the current interglacial period can help us better understand the physical and biological controls on ocean pH and possibly predict the long-term impact of climate change on future ocean acidification. [Copyright &y& Elsevier]

Abstract: A modern massive Porites coral was collected from the Longwan Bay (19°20′N, 110°39′E) on the east coast of the Hainan Island, China. The coral was sectioned vertical to the growth axis into discs of double density-bands representing annual growth. The samples were analyzed for the Sr/Ca ratio by inductively coupled plasma atomic emission spectrometry. The history of winter sea-surface temperature (SST) is reconstructed using the Sr/Ca ratio in winter bands of corals. The winter SST at Xisha in the middle of the South China Sea (SCS) is weakly correlated with the instrument-measured winter monsoon velocity (WMV) with a correlation coefficient of 0.19. The winter SST data from corals at Longwan Bay, Hainan, in the northern SCS are moderately correlated with the WMV (r =0.40). Interestingly we found that the difference of winter SSTs between the two sites (Xisha and Longwan Bay, Hainan) (the X–H index) is significantly negatively correlated with the WMV (r =−0.73). This negative correlation may be related to the intrusion of the warm Kuroshio Current into the SCS through the Luzon Strait promoted by the strong northeastern monsoon winds in the winter. Using the relationship between our coralline data and observed WMV, the calculated winter monsoon velocity (WMVc) was obtained for 87 years. This data set in combination with the instrument-measured data between 1993 and 1998 generate a record of WMVc for a period of 93 years from 1906 to 1998. The WMVc in the 20th century shows significant interannual and decadal variability with a trend of persistent decline in the whole 20th century at the rate of decrease of −0.02 (m/s)/a. The lowest wind velocity occurred during the last two decades of the 20th century. The WMVc has decreased significantly by about 30% from the early to the late of 20th century. The 20th century decline of winter monsoon velocity evidenced from the SCS coral records is consistent with the atmosphere–ocean general circulation models (AOGCMs) simulations for monsoon response to increasing temperatures. In addition, an obvious decline shift of WMV around 1976 can be seen in both instrumental and proxy records and it coincides with many other Pacific records. This shift is likely to correspond to a Pacific-wide change in the Pacific Decadal Oscillation occurring at the same time. [Copyright &y& Elsevier]