1. Oxy-schorl, Na(Fe22+Al)Al6Si6O18(BO3)3(OH)3O, a new mineral from Zlatá Idka, Slovak Republic and Přibyslavice, Czech Republic.
- Author
-
BAČÍK, PETER, CEMPÍREK, JAN, UHER, PAVEL, NOVÁK, MILAN, OZDÍN, DANIEL, FILIP, JAN, ŠKODA, RADEK, BREITER, KAREL, KLEMENTOVÁ, MARIANA, ĎUĎA, RUDOLF, and GROAT, LEE A.
- Subjects
TOURMALINE ,MINERALS ,ELECTRON probe microanalysis ,CRYSTAL structure - Abstract
Oxy-schorl (IMA 2011-011), ideally Na(Fe
2+ 2 Al)Al6 Si6 O18 (BO3 )3 (OH)3 O, a new mineral species of the tourmaline supergroup, is described. In Zlatá Idka, Slovak Republic (type locality), fan-shaped aggregates of greenish black acicular crystals ranging up to 2 cm in size, forming aggregates up to 3.5 cm thick were found in extensively metasomatically altered metarhyolite pyroclastics with Qtz+Ab+Ms. In Přibyslavice, Czech Republic (co-type locality), abundant brownish black subhedral, columnar crystals of oxy-schorl, up to 1 cm in size, arranged in thin layers, or irregular clusters up to 5 cm in diameter, occur in a foliated muscovite-tourmaline orthogneiss associated with Kfs+Ab+Qtz+Ms+Bt+Grt. Oxy-schorl from both localities has a Mohs hardness of 7 with no observable cleavage and parting. The measured and calculated densities are 3.17(2) and 3.208 g/cm3 (Zlatá Idka) and 3.19(1) and 3.198 g/cm3 (Přibyslavice), respectively. In plane-polarized light, oxy-schorl is pleochroic; O = green to bluish-green, E = pale yellowish to nearly colorless (Zlatá Idka) and O = dark grayish-green, E = pale brown (Přibyslavice), uniaxial negative, ω = 1.663(2), ε = 1.641(2) (Zlatá Idka) and ω = 1.662(2), ε = 1.637(2) (Přibyslavice). Oxy-schorl is trigonal, space group R3m, Z = 3, a = 15.916(3) Å, c = 7.107(1) Å, V = 1559.1(4) Å3 (Zlatá Idka) and a = 15.985(1) Å, c = 7.154(1) Å, V = 1583.1(2) Å3 (Přibyslavice). The composition (average of 5 electron microprobe analyses from Zlatá Idka and 5 from Přibyslavice) is (in wt%): SiO2 33.85 (34.57), TiO2 <0.05 (0.72), Al2 O3 39.08 (33.55), Fe2 O3 not determined (0.61), FeO 11.59 (13.07), MnO <0.06 (0.10), MgO 0.04 (0.74), CaO 0.30 (0.09), Na2 O 1.67 (1.76), K2 O <0.02 (0.03), F 0.26 (0.56), Cl 0.01 (<0.01), B2O3 (calc.) 10.39 (10.11), H2 O (from the crystal-structure refinement) 2.92 (2.72), sum 99.29 (98.41) for Zlatá Idka and Přibyslavice (in parentheses). A combination of EMPA, Mössbauer spectroscopy, and crystal-structure refinement yields empirical formulas (Na0.591 Ca0.103 ⇔0.306 )Σ1.000 (Al1.885 Fe2+ 1.108 Mn0.005 Ti0.002 )Σ3.000 (Al5.428 Mg0.572 )Σ6.000 (Si5.506A l0.494 )Σ6.000O18 (BO3 )3 (OH)3 (O0.625 OH0.236 F0.136 Cl0.003 )Σ1.000 for Zlatá Idka, and (Na0.586 Ca0.017 K0.006 ⇔0.391 )Σ1.000 (Fe2+1.879 Mn0.015 Al1.013 Ti0.093 )Σ3.00 (Al5.732 Mg0.190 Fe3+0.078 )Σ6.000 (Si5.944 Al0.056 )Σ6.000O18 (BO3 )3 (OH)3 (O0.579 F0.307 OH0.115 )Σ1.000 for Přibyslavice. Oxy-schorl is derived from schorl end-member by the AlOFe-1 (OH)-1 substitution. The studied crystals of oxy-schorl represent two distinct ordering mechanisms: disorder of R2+ and R3+ cations in octahedral sites and all O ordered in the W site (Zlatá Idka), and R2+ and R3+ cations ordered in the Y and Z sites and O disordered in the V and W sites (Přibyslavice). [ABSTRACT FROM AUTHOR]- Published
- 2013
- Full Text
- View/download PDF