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Despite being one of the most important factors in deep oil and gas exploration, the preservation mechanisms of ultradeep carbonate reservoirs remain poorly understood. This study performed thin-section, geochemistry, field emission scanning electron microscopy, fluid inclusion, and basin model analysis of samples from two boreholes over 8,000 m deep in the Sichuan Basin to determine the pore features and preservation mechanism of the Sinian (Ediacaran) Dengying Formation carbonate reservoirs. The reservoir of CS well #1 is characterised by pore diameters larger than a centimetre (average porosity 7.48%; permeability 0.8562 mD), and the pores are mainly filled with dolomite or bitumen. In contrast, the reservoir of MS well #1 is predominantly composed of micron-scale residual pores (average porosity 1.74%; permeability 0.0072 mD), and the pores are typically filled with dolomite, bitumen, and multistage quartz. The burial thermal histories suggest that both reservoirs were subjected to high pressure (i.e., pressure coefficient > 1.5) before the Late Cretaceous. However, the pressure coefficient of the reservoir of MS well #1 has decreased to less than 1.0 owing to strong structural adjustment this well since the Late Cretaceous, which allowed other ore-forming fluids to enter and fill the pores, resulting in further compaction of the pores. In contrast, the pressure coefficient of CS well #1 is 1.1–1.2, which effectively prevented other ore-forming fluids from entering and filling the pores. The findings show that the dynamic adjustment of the Dengying Formation palaeo-gas reservoir indirectly affects the preservation or failure of the reservoir. The occurrence and geometry of bitumen in the Dengying reservoir exhibit good consistency with the pressure changes in both boreholes. In particular, bitumen with an annular shape and contraction joints in reservoir pores is widespread in CS well #1, which is attributed to the continuous preservation of palaeo-gas fields. Conversely, bitumen with a broken particle shape is located among the epigenetic minerals widespread in MS well #1, which is attributed to failure and depletion of the palaeo-gas fields. [ABSTRACT FROM AUTHOR]

Based on low-temperature thermochronological data (i.e., apatite fission-track (AFT) and (U–Th)/He (AHe)), structural evolution, burial and thermal history, this paper examines the relationship of multi-stage evolution between the upper Ordovician Wufeng and lower Silurian Longmaxi formations (i.e., the WL formation) and rapid exhumation at the Changning shale gas field in the southern Sichuan basin. AFT ages are generally young from southeast to northwest, decreasing from ca. 40 to 15 Ma while AHe single-grain ages range from ~35 to ~5 Ma. Inverse thermal histories show that a multi-stage cooling history with initial cooling began in the Late Cretaceous to early Cenozoic (middle Eocene), followed by accelerated rapid cooling in the late Cenozoic, with cooling rates of 2–4 °C/Myr across the Changning shale gas field. In particular, thermal models of samples in the western Changning area show a substantial increase in the cooling rates, i.e., from less than 1 °C/Myr to 3–5 °C/Myr in the Miocene. Integrated with inverse T-t models of low-temperature thermochronological data, the burial history indicates a four-stage thermal evolution of the WL Formation in the Changning shale-gas field: Early Mature from the middle Silurian to middle Permian, Middle Mature from the late Permian to Late Triassic, Late Mature from the Early Jurassic to Early Cretaceous, and Over mature since the middle Cretaceous, reaching a maximum burial depth of ~6000 m and maximum temperature of 190–200 °C at ca. 70–80 Ma. This evolution further suggests that a normal hydrostatic pressure index dominated the WL Formations in the Paleozoic. The gas generation and pressure index, however, have substantially increased since the Late Jurassic, particularly from the Early to middle Cretaceous, with a maximum pressure index of 2.1, which is indicative of the main shale gas accumulation and enrichment period in the WL Formation. Post-gas-generation structural deformation, uplift, and exhumation had a significant impact on shale gas enrichment, mainly through their influence on shale gas preservation. This suggests some relationships among the higher pressure coefficient of the WL Formation, the higher productivity and total gas content of the WL Formation, a weaker post-gas-generation structural deformation, and a weaker uplift, as indicated by the erosion and burial depth across the Changning shale gas field. Due to a significantly stronger cooling and uplift that occurred the in Late Cenozoic across the western Changning area, the pressure index decreased rapidly from ~2.0 to 1.0 with a normal pressure condition, indicating the destruction of the reservation condition in the WL Formation. • New low-temperature thermochronological data was from the SE Sichuan basin. • An accelerated cooling in the late Cenozoic was found. • Post-gas-generation deformation and exhumation controlled the shale gas enrichment. [ABSTRACT FROM AUTHOR]