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In this paper, a CdTe photovoltaic double-skin ventilated window integrated with vacuum glazing (VPV-DSV) is proposed. The mathematical model of VPV-DSV was developed and validated through tests in Hefei, China. Annual energy performance and the economic analysis of the VPV-DSV was evaluated and compared with the other two PV-DSVs and an insulating glazed window (IG) under climate conditions of five selected cities, including Changchun, Hefei, Kunming, Shenzhen, and Shijiazhuang. Moreover, effects of window design factors, including the window-to-wall ratio, PV coverage, and pillar spacing of the VG, were explored. Results indicated that: (1) the VPV-DSV produced the best energy saving results and the least energy consumption. (2) NECs of the VPV-DSV in the five cities above was 955.05 kW•h, 464.31 kW•h, 110.66 kW•h, 53.71 kW•h, and 443.14 kW•h, respectively. (3) Due to high cost of the VG, the VPV-DSV only had the best economic performance in Shenzhen and the NPV was 3931.47 CNY. (4) The WWR and PV coverage had obvious impacts on the overall performance of the VPV-DSV, while the pillar spacing only had a more significant impact on the air conditioning energy consumption. [ABSTRACT FROM AUTHOR]