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New optically stimulated luminescence dating and Bayesian models integrating all legacy and BRITICE‐CHRONO geochronology facilitated exploration of the controls on the deglaciation of two former sectors of the British–Irish Ice Sheet, the Donegal Bay (DBIS) and Malin Sea ice‐streams (MSIS). Shelf‐edge glaciation occurred ~27 ka, before the global Last Glacial Maximum, and shelf‐wide retreat began 26–26.5 ka at a rate of ~18.7–20.7 m a–1. MSIS grounding zone wedges and DBIS recessional moraines show episodic retreat punctuated by prolonged still‐stands. By ~23–22 ka the outer shelf (~25 000 km2) was free of grounded ice. After this time, MSIS retreat was faster (~20 m a–1 vs. ~2–6 m a–1 of DBIS). Separation of Irish and Scottish ice sources occurred ~20–19.5 ka, leaving an autonomous Donegal ice dome. Inner Malin shelf deglaciation followed the submarine troughs reaching the Hebridean coast ~19 ka. DBIS retreat formed the extensive complex of moraines in outer Donegal Bay at 20.5–19 ka. DBIS retreated on land by ~17–16 ka. Isolated ice caps in Scotland and Ireland persisted until ~14.5 ka. Early retreat of this marine‐terminating margin is best explained by local ice loading increasing water depths and promoting calving ice losses rather than by changes in global temperatures. Topographical controls governed the differences between the ice‐stream retreat from mid‐shelf to the coast. [ABSTRACT FROM AUTHOR]

Predicting the future response of ice sheets to climate warming and rising global sea level is important but difficult. This is especially so when fast‐flowing glaciers or ice streams, buffered by ice shelves, are grounded on beds below sea level. What happens when these ice shelves are removed? And how do the ice stream and the surrounding ice sheet respond to the abruptly altered boundary conditions? To address these questions and others we present new geological, geomorphological, geophysical and geochronological data from the ice‐stream‐dominated NW sector of the last British–Irish Ice Sheet (BIIS). The study area covers around 45 000 km2 of NW Scotland and the surrounding continental shelf. Alongside seabed geomorphological mapping and Quaternary sediment analysis, we use a suite of over 100 new absolute ages (including cosmogenic‐nuclide exposure ages, optically stimulated luminescence ages and radiocarbon dates) collected from onshore and offshore, to build a sector‐wide ice‐sheet reconstruction combining all available evidence with Bayesian chronosequence modelling. Using this information we present a detailed assessment of ice‐sheet advance/retreat history, and the glaciological connections between different areas of the NW BIIS sector, at different times during the last glacial cycle. The results show a highly dynamic, partly marine, partly terrestrial, ice‐sheet sector undergoing large size variations in response to sub‐millennial‐scale climatic (Dansgaard–Oeschger) cycles over the last 45 000 years. Superimposed on these trends we identify internally driven instabilities, operating at higher frequency, conditioned by local topographic factors, tidewater dynamics and glaciological feedbacks during deglaciation. Specifically, our new evidence indicates extensive marine‐terminating ice‐sheet glaciation of the NW BIIS sector during Greenland Stadials 12 to 9 – prior to the main 'Late Weichselian' ice‐sheet glaciation. After a period of restricted glaciation, in Greenland Interstadials 8 to 6, we find good evidence for rapid renewed ice‐sheet build‐up in NW Scotland, with the Minch ice‐stream terminus reaching the continental shelf edge in Greenland Stadial 5, perhaps only briefly. Deglaciation of the NW sector took place in numerous stages. Several grounding‐zone wedges and moraines on the mid‐ and inner continental shelf attest to significant stabilizations of the ice‐sheet grounding line, or ice margin, during overall retreat in Greenland Stadials 3 and 2, and to the development of ice shelves. NW Lewis was the first substantial present‐day land area to deglaciate, in the first half of Greenland Stadial 3 at a time of globally reduced sea‐level c. 26 kabp, followed by Cape Wrath at c. 24 kabp. The topographic confinement of the Minch straits probably promoted ice‐shelf development in early Greenland Stadial 2, providing the ice stream with additional support and buffering it somewhat from external drivers. However, c. 20–19 kabp, as the grounding‐line migrated into shoreward deepening water, coinciding with a marked change in marine geology and bed strength, the ice stream became unstable. We find that, once underway, grounding‐line retreat proceeded in an uninterrupted fashion with the rapid loss of fronting ice shelves – first in the west, then the east troughs – before eventual glacier stabilization at fjord mouths in NW Scotland by ~17 kabp. Around the same time, ~19–17 kabp, ice‐sheet lobes readvanced into the East Minch – possibly a glaciological response to the marine‐instability‐triggered loss of adjacent ice stream (and/or ice shelf) support in the Minch trough. An independent ice cap on Lewis also experienced margin oscillations during mid‐Greenland Stadial 2, with an ice‐accumulation centre in West Lewis existing into the latter part of Heinrich Stadial 1. Final ice‐sheet deglaciation of NW mainland Scotland was punctuated by at least one other coherent readvance at c. 15.5 kabp, before significant ice‐mass losses thereafter. At the glacial termination, c. 14.5 kabp, glaciers fed outwash sediment to now‐abandoned coastal deltas in NW mainland Scotland around the time of global Meltwater Pulse 1A. Overall, this work on the BIIS NW sector reconstructs a highly dynamic ice‐sheet oscillating in extent and volume for much of the last 45 000 years. Periods of expansive ice‐sheet glaciation dominated by ice‐streaming were interspersed with periods of much more restricted ice‐cap or tidewater/fjordic glaciation. Finally, this work indicates that the role of ice streams in ice‐sheet evolution is complex but mechanistically important throughout the lifetime of an ice sheet – with ice streams contributing to the regulation of ice‐sheet health but also to the acceleration of ice‐sheet demise via marine ice‐sheet instabilities. [ABSTRACT FROM AUTHOR]

Here we develop a novel method for quantifying sediment components, e.g. biogenic silica, organic or mineral matter, from near infrared (NIR) spectra based on fitting by multiple regression of measured spectra for end-member materials. We show that with suitable end-members our new open-source multiple regression routine gives excellent simultaneous quantification of the major components of a sediment, the concentrations comparing well with independent methods of quantification. Widely used partial least squares regression approaches rely on large environmental training data sets; our method produces comparable results, but with the advantages of negating the need for a training dataset and with greater simplicity and theoretical robustness. We demonstrate that component NIR spectra are additive, a prerequisite for use of multiple regression to un-mix the compound spectra, and show that a number of environmental materials make suitable end-members for this analysis. We show that spectral mixing is not conservative with respect to mass proportion, but rather to the relative chromatic intensity of contributing sediment components. Concentrations can be calculated using the measured spectra by correction using a chromatic intensity factor, the value of which can be measured independently. We have applied our approach to a postglacial sediment sequence from Loch Grannoch (SW Scotland) and reveal a down-core pattern of varying dominance by biogenic silica, organic and mineral content from the late glacial to present. With isolation and measurement of appropriate end-members this multivariate regression approach to interrogating NIR spectra has utility across a wide range of sedimentary environments and potentially for other spectral analytical methods. [ABSTRACT FROM AUTHOR]

Abstract During the Last Glacial Maximum (LGM) the marine-terminating Barra Fan Ice Stream (BFIS), a major conduit of the British Irish Ice Sheet (BIIS), drained much of western Scotland and northwest Ireland with ice streaming onto the continental shelf of the Malin Sea. The extent and retreat history of this ice stream across the shelf, until now, is not well known. In particular, geochronological constraints on the history of this ice stream have thus far been restricted to deep-sea cores or terrestrial cosmogenic nuclide dating onshore, with ages across the shelf absent. To understand the possible external forcing factors acting on this marine terminating ice stream during retreat, improved geochronological constraint on its deglaciation is necessary. Here, we present new geophysical data, marine sediment cores and over forty radiocarbon dates to provide important constraints on maximum extent of the BFIS, as well as the timing and pattern of retreat back across the Malin Shelf. Dated moraines and grounding-zone wedges (GZW) seen in seafloor sub-bottom profiles provide evidence that the BFIS reached the Malin Shelf edge during the LGM and was at its maximum extent around 26.7 ka BP. The presence of two sets of GZWs suggests that the style of retreat was episodic. The new radiocarbon chronology shows that retreat from the shelf edge was underway by 25.9 ka BP, with the majority of the continental shelf ice free by 23.2 ka BP, and that glacimarine conditions were present in the Sea of Hebrides by 20.2 ka BP at the latest. Collectively, these results indicate that the majority of the Malin Shelf was free of grounded ice by ∼21.5–20 ka BP, which is up to 4000 years earlier than previously reconstructed. We attribute this early deglaciation to high relative sea level caused by glacial isostatic depression when the BIIS reached its maximum extent promoting ice shelf and grounding line instability. Two deep troughs, forming reverse bed slopes, aided the continued retreat of the BFIS. This suggests that local ice loading and bed morphology can be significant controls on the destabilisation of a marine-terminating ice stream and can override the influence of ocean and atmospheric temperatures. Highlights • Detailed reconstruction of MIS 2 deglaciation of the Malin Shelf using marine data. • Early retreat of the Barra Fan Ice Stream (BFIS) from the shelf edge by 25.9 ka. • Initial retreat likely caused by isostatic loading and relative sea-level rise. • The entire Malin Shelf was ice free by 20.2 ka. [ABSTRACT FROM AUTHOR]