1. Application of sequential alkaline amorphous silica extraction for Cenozoic and early Paleozoic rocks.
- Author
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Merenkova, Sofia I, Mikheev, Ivan V, Kalmykov, Georgii A, Gabdullin, Ruslan R, and Suslenkova, Maria M
- Subjects
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SILICA , *PALEOZOIC Era , *CENOZOIC Era , *GEOLOGICAL time scales , *CLAY minerals - Abstract
The study of amorphous biogenic silica content in marine sediments makes it possible to evaluate changes in the silicon cycle in the world ocean, while periods of intense silicon deposition record changes in the water chemistry and the atmosphere. The technique of sequential leaching of silica with subsequent calculation of the contribution of clay minerals is actively used by researchers for Quaternary deposits. This study used sediments that differ in age (Neogene, Cambrian), composition (clay minerals content from 0 to 27%, quartz content from 9 to 88%), and paleoenvironment (oxic and anoxic conditions, marine and coastal environments). Three rock types were taken for comparison: Miocene siltstones (N1s2, Sarmatian regional stage, Taman, Russia), bituminous limestone, flint, and rocks of the mixed siliceous–clay–carbonate composition of the Inikan Formation of the Lower-Middle Cambrian (Є1-2in), and Middle-Upper Cambrian siltstones of the Evenki Formation (Є2-3ev) (Eastern Siberia, Russia). The alkaline leaching method has been improved to prevent possible changes in the reaction kinetics and to account for the heterogeneity of the sample at low estimated amorphous silica content. As a result of these studies, it has been found that the Si/time and Si/Al are the most optimal among the considered methods for calculating the content of amorphous silica in Neogene and Cambrian rocks with low amorphous silica content. When there is little discrepancy between the average values of conditionally biogenic silica, the Si/Al method is preferable for terrigenous rocks. The amount of amorphous silica available for extraction in the rocks of the Inikan (Є1-2) and Evenki (Є2-3) formations was estimated at 0–2.0 wt% and 1.6–3.0 wt%, respectively. Research Highlights: Sedimentary rocks of different ages (Neogene, Cambrian), composition (clay minerals content from 0 to 27%, quartz content from 9% to 88%), and paleoenvironment (oxic and anoxic conditions, marine and coastal environments) were studied. The alkaline leaching method has been improved to prevent possible changes in the reaction kinetics and to account for the heterogeneity of the sample at low estimated amorphous silica content. As a result of these studies, it has been found that the Si/time and Si/Al are the most optimal among the considered methods for calculating the content of amorphous silica in Neogene and Cambrian rocks with low amorphous silica content. Methodological issues related to the calculation of the contribution of clay minerals were discussed, as well as the role of catagenetic transformation for Paleozoic rocks. [ABSTRACT FROM AUTHOR]
- Published
- 2023
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