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• High levels of nitro-aromatic compounds (NACs) were observed in coastal Qingdao in winter. • Anthropogenic emissions and high humidity increased the abundance of particulate NACs. • Coal combustion and biomass burning made large contributions to the elevated NACs. • An improved SCWT model was established by adding horizontal and vertical coefficients. • Emissions in local Qingdao and adjacent areas were responsible for the observed NACs. Nitro-aromatic compounds (NACs) are among the major components of brown carbon (BrC) in the atmosphere, causing negative impacts on regional climate, air quality, and ecological health. Due to the extensive origins, it is still a challenge to figure out the contributions and originating regions for different sources of atmospheric NACs. Here, field observations on fine particulate NACs were conducted at a coastal rural area in Qingdao, China in the winter of 2018 and 2019. The mean total concentrations of fine particulate nitro-aromatic compounds were 125.0 ± 89.5 and 27.7 ± 21.1 ng/m3 in the winter of 2018 and 2019, respectively. Among the measured eleven NACs, nitrophenols and nitrocatechols were the most abundant species. Variation characteristics and correlation analysis showed that humidity and anthropogenic primary emissions had significant influences on the NAC abundances. In this study, two tracing methods of the improved spatial concentration weighted trajectory (SCWT) model and the receptor model of positive matrix factorization (PMF) were combined to comprehensively understand the origins of NACs in fine particles at coastal Qingdao. Four major sources were identified, including coal combustion, biomass burning, vehicle exhaust, and secondary formation. Surprisingly, coal combustion was responsible for about half of the observed nitro-aromatic compounds, followed by biomass burning (∼30%). The results by SCWT demonstrated that the coal combustion dominated NACs mainly originated from the Shandong peninsula and the areas to the north and southwest, while those dominated by biomass burning primarily came from local Qingdao and the areas to the west. [Display omitted] [ABSTRACT FROM AUTHOR]

Nitrated phenols in particulate matters are among the major components of brown carbon, harm plant growth and human health. To understand the size distributions of nitrated phenols in the polluted coastal region and the factors influencing these distributions, size-resolved particulate matters were collected from a rural site in the coastal city of Qingdao, China, in January 2019, and analyzed for the presence of 11 nitrated phenols. The average concentrations of total nitrated phenols in fine- and coarse-mode particles were 123.6 and 37.2 ng m−3, respectively. 4-Nitrophenol was found to be the dominant nitrated phenol, followed by 3-methyl-6-nitrocatechol, 3-methyl-4-nitrophenol, and 4-nitrocatechol. On average, maximum concentrations of nitrated phenols were in condensation-mode particles, whereas a minor concentration peak of nitro-salicylic acids was present in droplet-mode particles. In addition, a minor concentration peak of 4-methyl-2,6-dinitrophenol was noticed in coarse-mode particles. Comparisons of the size distributions under different situations confirmed that both primary emissions and secondary formation had significant effects on the abundances and particle-sizes of nitrated phenols. Coal combustion in residential villages and firework burning during a festival led to a sharp increase of nitrated phenols in condensation-mode particles, whereas dust promoted their heterogeneous formation in coarse-mode particles, and high humidity in the coastal area facilitated their aqueous formation in droplet-mode particles. Image 1028 • Concentrations and size distributions of 11 nitrated phenols (NPs) were presented. • Primary sources and secondary formation had impacts on size distributions of NPs. • Coal combustion and fireworks promoted the increases of NPs in condensation mode. • Dust in the atmosphere caused the heterogeneous formation of NPs in coarse particles. • High humidity obviously facilitated the aqueous formation of NPs in droplet mode. [ABSTRACT FROM AUTHOR]