Search

The endless and dramatic increase of global energy demand makes it imperative to develop sustainable, affordable, and efficient materials to act as electrocatalysts in the clean energy technologies. Electrocatalysts based on coal chars are promising materials as they can be considered as value-added by-products from coal combustion contributing to industrial ecology and circular economy. Therefore, herein we report the application of three sets of coal char (char concentrates before and after carbonization and demineralized and graphitized char concentrates) obtained from four different countries (Portugal, Romania, Poland, and South Africa) as oxygen reduction reaction (ORR) electrocatalysts. All electrocatalysts presented moderate ORR activity with some showing selectivity for the indirect two-electron process while others for a mixed regime between the two- and four-electron process. Still, the positive results obtained are better or in some cases comparable to commercial graphene. Moreover, all electrocatalysts presented good tolerance to methanol poisoning. More importantly, the results of this study demonstrate that pristine coal chars are promising materials to prepare efficient ORR electrocatalysts which will be of great importance in the near future. • Sustainable carbon-based material obtained from coal char recovered from fly ash. • Pristine coal char as graphene substitute for electrocatalysts production. • Promotion of circular economy using coal char as ORR electrocatalysts. [ABSTRACT FROM AUTHOR]

Natural graphite is a critical raw material and its substitution in some applications will contribute to reduce its supply risk. Coal ash, which is still produced in high amounts, contains a carbonaceous solid residue (char) that may be a substitute of natural graphite. For this purpose, char may be graphitized and used in electrocatalysis reactions, however char properties depend on coal rank, composition and combustion conditions that affect the graphitization process. Research on industrial coal char graphitization is limited, resulting in restricted comprehension of the contributing factors. In order to provide novel insights, industrial residual chars (derived from Poland, Portugal, Romania and South Africa) subjected to high-temperature treatments (carbonization at 1000 °C followed by treatment at 2600 °C under environmental pressure) were examined regarding their microstructural and microtextural transformations. The samples were studied by focussing on its heterogeneity, namely its specific properties and interactions, including elemental composition, optical character, and structure. Furthermore, the evolution of structural order of selected char morphotypes in samples derived from coal of similar rank was assessed using Raman microspectroscopy. The results highlighted a set of aspects that could have influenced the transformations experienced by the different chars during high temperature treatments (graphitization). It was found that Hydrogen might play a role in the graphitization ability of isotropic chars derived from low rank coal. The prior preferential orientation of the Basic Structural Units (BSU) contributes to achieve a higher graphitization degree, but it can be enhanced or hindered by other factors, e.g., hydrogen content. Raman microspectroscopy showed that char morphotypes from the same group underwent different transformations during graphitization, indicating that morphotypes or sections with unfused optical character may be more prone to graphitization. However, the existence of disordered domains and specific microtextures, such as polyhedral pores identified under TEM, likely hindered further graphitization. Further research on this topic is needed. [ABSTRACT FROM AUTHOR]

• Use wood fly ash instead of cement leads to more environmentally friendly solution. • Study the effect of wood fly ash on the durability and quality of concrete. • Wood fly ash concrete had similar results than coal fly ash concrete. • Using of wood fly ash leads to a decrease on energy and raw materials consumption. • Concrete with wood fly ash is a more sustainable option on the ash management. Wood fly ash (WFA) is a waste material produced in power plants as result of forest residues combustion to produce power and heat. In countries like Portugal, this waste is disposed of in landfills. Since this material shows pozzolanic characteristics, several studies have been done to evaluate its use as a construction material. This work shows an overview of some published results about the effect of the utilisation of WFA, as a supplementary cementitious material, on the durability and quality of concrete. The results showed that the increase on the wood fly ash content leads to a negative effect on the concrete properties when compared with a conventional concrete. However, the results showed that the behaviour of wood fly ash concrete is very similar to the coal fly ash concrete, which is the most pozzolanic material used in the world. In terms of durability, it was verified that WFA improved the most of the durability characteristics with the exception of carbonation resistance. However, more experimental analysis needs to be developed in terms of wood fly ash concrete durability. Results suggested that using wood fly ash to replace cement is a valuable sustainable option for concrete production. This manuscript discusses the key factors and attempts to provide new information about the application of the wood fly ash on concrete. [ABSTRACT FROM AUTHOR]