1. The observation of nitric acid-containing particles in the tropical lower stratosphere.
- Author
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Popp, P. J., Marcy, T. P., Jensen, E. J., Kärcher, B., Fahey, D. W., Gao, R. S., Thompson, T. L., Rosenlof, K. H., Richard, E. C., Herman, R. L., Weinstock, E. M., Smith, J. B., May, R. D., Vömel, H., Wilson, J. C., Heymsfield, A. J., Mahoney, M. J., and Thompson, A. M.
- Subjects
NITRIC acid ,STRATOSPHERE ,SULFATES ,AEROSOLS ,TROPOPAUSE - Abstract
Airborne in situ measurements over the eastern Pacific Ocean in January 2004 have revealed a new category of nitric acid (HNO
3 )-containing particles in the tropical lower stratosphere. These particles are most likely composed of nitric acid trihydrate (NAT). They were intermittently observed in a narrow layer above the tropopause (18±0.1 km) and over a broad geographic extent (>1100 km). In contrast to the background liquid sulfate aerosol, these particles are solid, much larger (1.7-4.7µm vs. 0.1µm in diameter), and significantly less abundant (<10-4 cm-3 vs. 10 cm-3 ). Microphysical trajectory models suggest that the NAT particles grow over a 6-14 day period in supersaturated air that remains close to the tropical tropopause and might be a common feature in the tropics. The small number density of these particles implies a highly selective or slow nucleation process. Understanding the formation of solid NAT particles in the tropics could improve our understanding of stratospheric nucleation processes and, therefore, dehydration and denitrification. [ABSTRACT FROM AUTHOR]- Published
- 2006
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