1. Crustal and mantle influences and U–Th–Ra disequilibrium in andesitic lavas of Ngauruhoe volcano, New Zealand
- Author
-
Price, Richard C., Turner, Simon, Cook, Craig, Hobden, Barbara, Smith, Ian E.M., Gamble, John A., Handley, Heather, Maas, Roland, and Möbis, Anja
- Subjects
- *
LAVA , *URANIUM isotopes , *SUBDUCTION zones , *BASALT , *CHEMICAL processes , *ANALYTICAL geochemistry , *MATHEMATICAL models , *CRUST of the earth , *EARTH'S mantle , *EARTH (Planet) - Abstract
Abstract: The andesitic volcano Ngauruhoe, which is located within the Tongariro Volcanic Complex at the southern end of the Taupo Volcanic Zone in North Island, New Zealand, has been constructed over the past 5ka and last erupted in 1975. Nearby Ruapehu volcano has a much longer eruptive history extending back beyond 230kaB.P. The magmas erupted at both volcanoes have been predominantly medium-K basaltic andesites and andesites, which evolved through polybaric crystal fractionation and assimilation processes that took place within complex, dispersed magmatic storage systems. Despite their close spatial proximity, the two volcanoes show geochemical contrasts suggesting that in each case both the mantle-derived parental magmas and the crustal assimilants were different. Variations in major and trace element data for Ngauruhoe lavas indicate control by crystal fractionation and assimilation (AFC) but the data are difficult to reconcile with derivation from a single batch of compositionally unique, mantle-derived parental basalt. Geochemical variation can be approximated by generalised AFC models using average basement or crustal xenolith compositions but precise mathematical modelling is limited because of the sensitivity of models to the selection of a particular parental composition and the difficulty of determining the exact nature of the crustal assimilant compositions that might have been involved in each specific case. U–Th isotopic data for Ngauruhoe volcanic rocks show disequilibrium that defines a positively inclined array lying to the right of the equiline on a 230Th/232Th versus 238U/232Th diagram. U-series data for Ngauruhoe and post 1945AD Ruapehu eruptives show similar patterns of disequilibrium but the Ngauruhoe data define an array with a different slope and a different intercept on the equiline. 230Th/238U ratios in Ngauruhoe lavas range from close to secular equilibrium (0.979) to 0.864 with the youngest (post 1870AD) eruptives showing the least disequilibrium. 230Th/238U and 87Sr/86Sr ratios are correlated; the samples with the highest 87Sr/86Sr values show the least disequilibrium. There is also a correlation between eruption age and Nd and Pb isotopic composition; the oldest samples tend to show the least radiogenic isotopic ratios. These data, in combination with major and trace element abundance data indicate that Ngauruhoe U–Th disequilibrium is determined by variations in parental magmatic compositions and AFC. Unlike the mature, long-lived Ruapehu system, Ngauruhoe''s eruptive cycles can be directly connected to periodic magma recharge from the lower crust and mantle. For Ngauruhoe eruptives, 226Ra/230Th varies from 1.218 to 1.492. This compares with a range of 0.972 to 1.186 for Ruapehu lavas erupted between 1945 and 1996. Reconciling the 226Ra/230Th data with decay during fractional crystallisation requires relatively low rates of fractionation (1–5×10−5/year) and short (1000–2000years) fractionation times. [Copyright &y& Elsevier]
- Published
- 2010
- Full Text
- View/download PDF