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[Display omitted] • Transition from barren to fertile geochemical signatures of arc magmas in the Baguio-Mankayan Mineral District is intimately linked with arc development and subduction dynamics. • Late Eocene barren magmas were generated in a thin nascent Luzon arc. • Middle Pliocene fertile magmas were formed from mixing of mafic and silicic melts associated with ridge subduction. • More hydrous conditions of Early Pleistocene fertile magmas are attributed to progressive crustal thickening and compression induced by ride subduction. The Baguio-Mankayan Mineral District (BMMD) in Northern Luzon, Philippines, is renowned for its world-class auriferous porphyry-Cu and epithermal deposits, which are associated with arc magmatism during the Pliocene-Pleistocene. One of the less studied areas in this region is in southern Mankayan, where the Suyoc epithermal prospect is located. New U-Pb zircon ages, combined with whole-rock and in-situ geochemical analyses of igneous rocks in the Suyoc area, revealed a shift from barren to fertile magmatic episodes in the BMMD. 1) Late Eocene (36.93–37.20 Ma) barren magmas generated in a thin, nascent Luzon arc, 2) Fertile Middle Pliocene (2.87–3.4 Ma) magmatism attributed to the mixing of primitive mafic and silicic crustal melts due to ridge subduction, and 3) Early Pleistocene (1.73 Ma) fertile magmatism associated with more hydrous melts due to progressive crustal thickening. The Late Eocene barren magmatism enhanced both source and intra-crustal conditions for the onset of younger fertile magmatic events via sub-arc modification and crustal addition/thickening. Furthermore, we consider the fertile Pliocene and Pleistocene magmatism in the BMMD as two separate events with different petrogenesis. Mafic-silicic interaction in the Pliocene was documented through core-rim analysis of amphiboles from the Pliocene Suyoc Diorite. On the other hand, the Pleistocene fertile magmatism, represented by the Bato Dacite Porphyry, showed geochemical signatures consistent with a thickened crust and also reflected higher magmatic H 2 O contents ranging from 6.3 to 7.8 wt%. [ABSTRACT FROM AUTHOR]

• Early Miocene, Middle Miocene and Pliocene magmatic events were identified in Sangilo. • Middle Miocene fertile magmatism is attributed to MASH zone development. • Pliocene mineralization is from increased fertility due to rapid ascent of basaltic melt. In the Baguio Mineral District (BMD), porphyry Cu ± Au deposition and associated epithermal mineralization are attributed to the highly evolved magmatism during the Pliocene. It has been well-documented that the interaction between silicic crustal melts and primitive mantle melts formed water-rich, oxidized magmas that resulted to hydrothermal mineralization. However, there are very few studies on the Early to Middle Miocene calc-alkaline magmatism which is considered to be barren of mineralization. This magmatic event is represented by phases of the Central Cordillera Diorite Complex (CCDC), which also serve as host rocks to the Sangilo epithermal deposit. The Sangilo quartz-carbonate veins in the BMD are hosted by an Early Miocene hornblende diorite (22.33 ± 0.63 Ma) intruded by a Middle Miocene quartz diorite (15.91 ± 0.6 Ma) which are, in turn, penetrated by Pliocene basaltic andesite dikes. The Miocene magmatic units with hybrid crust-mantle source affinity were formed from varying degrees of interaction within the MASH (mixing, assimilation, storage, and homogenization) zone during the formation of the CCDC. The basaltic andesite dikes, part of the Pliocene Mafic Dike Complex, represent direct differentiates of basaltic melts that experienced ponding at the base of the lower crust before ascending to shallow crustal levels. Based on the assessment of the physico-chemical conditions, three distinct magmatic events were identified: a barren Early Miocene event, a fertile Middle Miocene event and a fertile Pliocene event. The Middle Miocene fertile magmatism is attributed to further development of the MASH zone under the Luzon arc from the Early to Middle Miocene. On the other hand, the enhanced fertility during the Pliocene is associated with the subduction of the Scarborough Ridge. [ABSTRACT FROM AUTHOR]