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Separating productive green water from non-productive green water could determine the potential for improving green water use through water-to-vapor conversion and the optimization of green water resource management. This study selected three typical planted forests of Robinia pseudoacacia, Platycladus orientalis, and Pinus tabulaeformis in the Nanxiaohegou sub-basin, a typical small sub-basin located in the gully region of the Loess Plateau. A combination of field monitoring, hydrological models, and statistical tests was used to obtain the crop coefficient and to differentiate productive green water from non-productive green water, based on the hydrological, climatic, and ecological processes in the basin. The results demonstrated that the complementary relationship areal evapotranspiration (CRAE) model was the most effective complementary relationship-based model for the simulation. Based on the calibrated parameters, it could be used for the simulation of green water flux of different vegetation types in the studied region. In the Nanxiaohegou sub-basin, the amounts of productive green water, non-productive green water, and total green water flux of R. pseudoacacia were the highest among all three types of vegetation, followed by those of P. orientalis and P. tabulaeformis forests during the growing seasons between 2015 and 2017. [ABSTRACT FROM AUTHOR]