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In recent years, our world has experienced significant disruptions due to the COVID-19 pandemic, and Russia's 2022 invasion of Ukraine, impacting human activities and the global environment. This paper explored air quality changes in Ukraine due to COVID-19, and Russia's invasion of Ukraine using on-demand with a what-you-see-is-what-you-get approach. During the COVID-19 pandemic, strict quarantine policies in Ukraine led to a 2% reduction in tropospheric NO2 concentration before the lockdown and 4% during the lockdown period. Cities like Kyiv, Donetsk, and Dnipro exhibited reductions of 5%, 11%, and 16%, respectively. Total SO2 column concentration decreased by 6% before the lockdown and 2.5% during the lockdown period, except in high population density areas. Kyiv showed the highest reduction of 17% in SO2 concentration, while Donetsk and Dnipro exhibited an 11% reduction. However, during the Russian invasion, there was a significant increase in tropospheric NO2 concentration in heavily destroyed Kharkiv while most eastern regions experienced a reduction. The total SO2 column was 48% higher before the war but reduced throughout the country after the war, except for in Kyiv and a few central regions. These findings can contribute to analyzing air pollution and building digital twin simulations for future reconstruction scenarios. [ABSTRACT FROM AUTHOR]