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Abstract: An atypical potassium feldspar deposit of real economic potential has been found at Arcu de su Bentu, Southern Sardinia, Italy. The massive mineralization occurs in the Middle Ordovician Porphyroids'' metavolcanic complex, which consists of dominant metarhyolite and minor metarhyodacite lavas and/or ignimbritic flows, erupted in a sub-aerial environment. During Variscan orogenesis, the mineralized area was affected by low-grade (anchizone to greenschist facies) metamorphism. The deposit generally shows uniform macroscopic textural features over the entire outcrop, the significant presence of K-feldspar (sanidine) and quartz megacrystals, the latter being generally smaller than the former. Mafic minerals do not occur in significant proportions although minor amounts of biotite and muscovite occur locally. Besides the uncommon lithological type, the typical feature of this deposit is the unusual coarseness (10 to 20cm in diameter) of the potassium feldspar crystals. The favourable geomorphological conditions of the area, high K2O contents (6 to 8wt.%), high proportion of K-feldspar in the mineralized rock (35 to 51vol.%), and large reserves (estimated at 4,368,000t in just one restricted part of the deposit), are all favourable conditions for future economic exploitation. In spite of this, mineralogical and chemical impurities may adversely affect the possible use of K-feldspar from Arcu de su Bentu in some conventional applications (e.g., manufacture of high-quality products such as ceramics). To assess the real future economic development of the deposit, market-specific beneficiation is required, although it is important to note that the bulk raw materials, even if they have a lower market value, could be still be targeted to specific industrial sectors (e.g., red grès). [Copyright &y& Elsevier]

Abstract: The fluorite-bearing hydrothermal mineralization in Sardinia mainly occurs within Paleozoic volcanic and metasedimentary rocks. Only 3 occurrences are located in volcanic and siliciclastic Cenozoic rocks. Most Sardinian fluorites exhibit relatively high rare earth and Y (REY) contents, strong positive Y anomalies, slightly negative Ce and generally positive Eu anomalies. These features indicate that the REY were mobilized mainly from non-carbonate rocks. Neither Sr nor Nd isotopes can be used to date radiometrically the Sardinian fluorites. However, the measured Sr-isotope ratios of the fluorites hosted by Paleozoic rocks fit mixing lines in the 1000/Sr versus 87Sr/86Sr plot once recalculated at 280Ma, suggesting that the age inferred for the correction probably represents that of the formation of the fluorite mineralization. Mixing likely occurred between diluted surficial waters and brines circulating mainly through the Lower Paleozoic metasedimentary basement. The Cenozoic fluorites exhibit chemical and isotopic features similar to those of the Paleozoic fluorites, except the Nuraghe Onigu fluorite displaying a possible contribution of Sr from Cenozoic magmatic rocks. The initial εNd values of the Paleozoic fluorites fit the age proposed for the formation of the deposits. Moreover, the values suggest that radiogenic Nd was provided to the fluids from the Ordovician siliciclastic basement, except for 3 deposits where the potential source rocks of Nd were mainly Ordovician acidic magmatic rocks. The initial εNd values of the Cenozoic fluorites suggest a provenance of Nd essentially from the leaching of Variscan granitoids. [Copyright &y& Elsevier]