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The YK 1 shipwreck, found at Yenikapı, Istanbul, is one of 37 shipwrecks dating to the medieval era. This paper describes the studies and the processes which were conducted to conserve the YK 1. Firstly, the level of physical and chemical degradation of the wood from the YK 1 was examined, which revealed that the wood was highly degraded. Therefore, PEG 2000 was chosen for the impregnation process before vacuum freeze-drying. In addition, the ASE values confirmed that the PEG 2000 impregnation and vacuum freeze-drying method together were successful in conserving the YK 1, with values higher than PEG 2000 impregnation and vacuum freeze-drying methods alone. The concentration of the PEG solution in the tank was monitored throughout the impregnation process. Following this, samples taken from the wood cores were analysed using FTIR to evaluate the effectiveness of the impregnation process. Finally, SEM was used to examine the effectiveness of the PEG 2000 impregnation and vacuum freeze-drying method. The SEM images showed that the PEG 2000 was uniformly distributed, and the wood had no deformation after freeze-drying. [ABSTRACT FROM AUTHOR]

The Yenikapı (YK) 12 shipwreck is 1 of 37 shipwrecks found at Yenikapı, Istanbul. This merchantman has been dated to AD 672–876 by radiocarbon analyses. The conservation of YK 12, which was assembled with iron nails, was completed with the pre-impregnation of polyethylene glycol (PEG) and using vacuum freeze-drying processes. However, after conservation, dust formation was observed on some wooden parts of the shipwreck during storage. In this study, iron–sulfur-related problems detected in the woods of YK 12 were evaluated. We analysed samples taken from YK 12 to study the sulfur and iron content in woods from oak (Quercus), walnut (Juglans), and hornbeam (Carpinus), representing taxa with different wood properties. Fourier-transform infrared spectroscopy (FTIR) analyses, X-ray diffraction (XRD), and pH measurements were conducted on five samples. The results of these studies showed that the dust consisted of wood particles, PEG, and hydrated iron sulfates, such as FeSO4·4H2O and FeSO4·7H2O. Additionally, one sample included SiO2, whilst another exhibited a low pH value. These findings highlight the importance of optimum ambient conditions for the storage and display of these shipwrecks in order to prevent the irreversible degradation of YK 12 and other recovered shipwrecks. [ABSTRACT FROM AUTHOR]