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The current work is documented as the first record of the characteristics, removal efficiency, partitioning behavior, fate, and eco-toxicological effects of paraben congeners in a municipal wastewater treatment plant (WWTP, stabilization ponds) and hospital WWTPs (septic tank and activated sludge), as well as seawater-sediments collected from runoff estuarine stations (RES) and coastal stations (CS) of the north of the Persian Gulf. The median values of Σparabens at the raw wastewater and effluent of the studied WWTPs were 1884 ng/L and 468 ng/L, respectively. The activated sludge system had a greater removal efficiency (56.10%) in removing ∑parabens than the septic tank (45.05%) and stabilization pond (35.54%). The discharge rates of methyl paraben (MeP) was computed to be 2.23, 21.18, and 9.12 g/d/1000 people for stabilization ponds, septic tank, and activated sludge, respectively. Median concentrations of Σparabens in seawater (103.42 ng/L) and sediments (322.05 ng/g dw) from RES stations were significantly larger than from CS stations (61.2 and 262.0 ng/g dw in seawater and sediments, respectively) (P < 0.05). The median of field-based k oc for Σparabens was 130.81 cm 3 /g in RES stations and 189.51 cm 3 /g in CS stations. It was observed that the concentration of parabens could have negative impacts on some living aquatic populations (invertebrates and bacteria), but the risk was not significant for fishes and algae., (© 2022. The Author(s), under exclusive licence to Springer Nature B.V.)

One of the environmental effects of COVID 19 is the contamination of ecosystems with antibiotics due to their high consumption to treat this disease. Many years ago, the distribution of antibiotics including azithromycin (Azi) in wastewater treatment plants in Bushehr city, seawater, and sediment of the Persian Gulf has been investigated. As Azi has been prescribed to COVID 19 patients, contamination of the environment with this drug can also be assumed. Thus, we decided to examine this hypothesis by repeating our previous study during COVID 19 period. We collected wastewater samples from influent, effluent, and different units of three wastewater treatment plants (WWTPs) including one municipal WWTP (Plant A) and two hospital-WWTPs (Plant B and C). Seawater and adjusted sediments were gathered from 8 stations located in the Persian Gulf in two seasons to evaluate the special and temporal variation. The results showed a huge growth of Azi pollution in all studied matrixes. The mean Azi values in the influent of Plant A, B, and C were 145 ng/L, 110 ng/L, and 896 ng/L, which represented an 9, 6, and 48-time increase compared with those obtained in 2017 (before COVID 19). The Azi removal efficiency had a different behavior compared to before COVID 19. The mean concentration of Azi in seawater and sediment samples was 9 ng/L and 6 ng/g, which was 3 and 4-fold higher than the previous study. Opposed to our former study, the Azi amount in the aqueous phase was less subjected to temporal seasonal variations. Our observations indicated the wide distribution of Azi in the environment and a future threat of intense growth of antibiotic resistance in ecosystems., Competing Interests: Declaration of competing interest The authors declare that they have no known conflict of interest that may obscure or affect their judgment to influence the work reported in this paper., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

Urban runoff seems an obvious pathway for the transfer of microplastics (MPs) and phthalate acid esters (PAEs) from land-based sources to the marine environment; an issue that still lacks attention. This study presents the first results on MP and PAE levels in the urban runoff into the northern part of the Persian Gulf during the dry season. Average concentrations of MPs and PAEs in the urban runoff of eight selected sampling sites (N = 72) along the Bushehr coast were 1.86 items/L and 53.57 μg/L, respectively. MPs with a size range of 500-1000 μm had the highest abundance, and the mean levels of PAEs in MPs were 99.77 μg/g. The results of this study show that urban runoff is a main source of MP and PAE contaminants that are discharged into the Persian Gulf. Therefore, to decrease these pollutants from entering the aquatic environment, decision-makers in the area should consider this problem and stop the direct discharging of urban runoff into water bodies., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2021 Elsevier B.V. All rights reserved.)

Bushehr, a port along the northern part of the Persian Gulf, has repeatedly encountered dust storms in recent years but there is not been a comprehensive study on the PM 2.5 contents in this region. The present study reports the characteristics and health risks of atmospheric PM 2.5 -bound heavy metals (HMs) in Bushehr from December 2016 to September 2017. A total of 46 samples were analyzed, and a high volume air sampler equipped with quartz fiber filters was used for sampling. Inductively coupled plasma optical emission spectroscopy (ICP-OES) was also used for HMs analyses. Risk assessment and hazard index (HI) of these metals were computed by using USEPA's exposure parameters. The results showed that the average 24-h mass concentration of PM 2.5 ranged from 22.09 to 292.45 μg/m 3 . The results also indicated that 95.65 and 82.61% of the samples were higher than WHO and EPA guidelines for 24-h PM 2.5 . Also there was no statistically significant relationship between wind direction and PM 2.5 .The average concentration levels of seven measured metals (Cd, Co, Cr, Fe, Ni, Pb, and V) in the PM 2.5 samples were in the range of 6.03 ng/m 3 to 1335.94 ng/m 3 , and the order of their concentration was Fe > Ni > Pb > Cr > Cd > V > Co. Principal component analysis (PCA) showed that PM 2.5 -bound heavy metals were categorized in three groups. The ecological risk level of calculated metals was very significant, and the major contribution of the ecological risk was related to Cd. The highest HQ in children and adults was related to Cr, and overall HI in children was higher than adults. Also the RI values of Cr in both groups of children and adults were indicated high risk of developing cancer in human.

Phthalate acid esters (PAEs) are widely used as plasticizers in various plastic products and have aroused considerable concern over their ubiquitous presence and potentially hazardous effects on the environment. This research provides the first data on PAEs distribution in the sediments of northern part of the Persian Gulf. To determine the concentration of 16 PAEs, 26 samples of sediments were collected from industrial stations (IS), urban stations (US), agricultural stations (AGS), and natural field stations (NS) from Asalouyeh Harbor coasts from Nov 2016 to Jan 2017. The mean values of Ʃ16PAEs in the samples taken from IS, AGS, US, and NS were 78.08, 11.69, 46.56, and 5.180 µg/g, respectively. The results indicated that the mean concentrations of Ʃ16PAEs in the samples taken from IS and AGS areas were significantly higher (p < 0.05) than the ones taken from US and NS areas. The order of PAEs concentrations in sediment samples were as di(2-ethylhexyl) phthalate (DEHP), di-n-butyl phthalate (DnBP), butylbenzyl phthalate (BBP), and di-n-octyl phthalate (DnOP), respectively. DEHP was detected in all collected samples and the mean ± SD of its concentration in the IS, US, AGS, and NS regions were as 28.15 ± 4.9, 4.040 ± 0.53, 11.58 ± 1.2, and 1.780 ± 0.78 µg/g, respectively. The major sources of PAEs in the sediments collected from the study region were associated with the industrial and agricultural activities. The findings of this study indicated that the sediments of the Asalouyeh coasts are heavily contaminated with PAEs. They have shown potential ecotoxicological effects on the aquatic organisms and benthic. Therefore, more attention should be paid to prediction of the marine ecosystem in this region by the authorities., (Copyright © 2018 Elsevier Inc. All rights reserved.)