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In this research, the (1-x)(BNKT-BST)-xBFTa ceramics were fabricated via a solid-state mixed oxide method and sintered at the temperature of 1125 °C for 2 h dwell time in order to obtain dense ceramics. The XRD and Raman data revealed the coexisting rhombohedral and tetragonal phases for all samples. The density increased with increasing the additive content, which resulted in the improvements of mechanical and dielectric properties. The maximum dielectric ("r = 1799) and mechanical properties (HV = 6.30 GPa, HK = 5.30 GPa, E = 97 GPa and KIC = 1.95 MPa.m1=2) were observed. The leakage current density (J) increased with increasing amount of the additive at high electric fields of 30 kV/cm while the resistivity (p) was also found to decrease with the additive. The magnetocapacitance (-MC%) value also increased with increasing of the additive. The obtained results suggested that the additive not only enhanced the mechanical but also improved electrical properties of the studied samples. [ABSTRACT FROM AUTHOR]

Piezoelectric ceramics of bismuth sodium potassium titanate doped with a modified barium titanate (BNKT-xBTNb, x = 0.00–0.06) were prepared via the solid-state reaction process. The effect of BTNb on the phase formation, mechanical, dielectric, ferroelectric, and piezoelectric properties was investigated and discussed. All ceramics have a single perovskite phase. The data also revealed that there was a transformation from rhombohedral (x = 0.00) to mixed tetragonal/rhombohedral phases (0.02 ≤ x ≤ 0.04.), then to tetragonal-rich phases at x = 0.06. Microstructure analysis also indicated that the BTNb affected the morphology of the microstructure, where the average grain size decreased with increasing BTNb content. The BTNb doping produced an enhancement of mechanical properties, HV and HK increased with increasing BTNb content and reached the maximum values of 6.28 GPa, 5.51 GPa for x = 0.04 sample, respectively. The improvement of the properties was related to the change in microstructure. Furthermore, dielectric enhanced with increasing BTNb content, which reached a maximum value of 5439 for the x = 0.06 sample. However, the BTNb doping produced slimmer P-E loops which decreasing of Pr and Ec values. Meanwhile, the undoped BNKT displayed a highest piezoelectric coefficient, d33 of 198 pC/N. [ABSTRACT FROM AUTHOR]