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Blueschist tectonic blocks occur in serpentinites at Mochimaru, Hiroshima Prefecture, Southwest Japan. They contain alkali amphibole coexisting with pumpellyite and chlorite, with or without calcic amphibole. Textural and chemical analyses reveal that the blueschists, together with other mafic schists, have similar metamorphic history. After their capture by serpentinites and before the emplacement of the serpentinites into the present geological position, the tectonic blocks were subjected to high P/T metamorphism around the boundary between the blueschist and pumpellyite–actinolite facies. The amphiboles formed by this metamorphism change from tremolite through glaucophane to ferroglaucophane with increasing FeO/MgO of whole rock compositions. The P–T conditions are estimated to be within 200–350°C and 5–7 kbar. These are higher P/T conditions than those of the regional metamorphism of Southwest Japan. The difference in the P–T conditions implies differences in tectonic situation and timing of metamorphism between the blocks and regional metamorphic rocks. In addition, the high P/T metamorphism of the tectonic blocks probably occurred in more reducing environments than the regional metamorphism. Because the ferric/ferrous iron ratios of the tectonic blocks are within a narrow range, it is stressed that oxygen fugacity was externally buffered during the high P/T metamorphism by the serpentinization process of the host ultramafic rocks. The reducing effect of serpentinization is common throughout the high P/T metamorphic terranes of Southwest Japan. [ABSTRACT FROM AUTHOR]