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This study aimed to investigate the distribution of microplastics (MPs) within the Shiwuli River in Hefei, a Chinese inland city. Water and sediment samples were collected during flood season (from May to September) and non-flood season (from October to April) at 10 representative points along the truck stream. The electron microscope, the laser direct infrared chemical imaging system (LDIR), and the scanning electron microscope (SEM) were used to observe and quantify the colour and shape of the MPs, to identify the number, size, and polymer composition of the MPs, and to observe the microstructures of typical MP particles, respectively. The polymer risk index (RI) model and the pollution load index (PLI) model were used to assess the polymer-related risks and the overall extent of MP pollution in the river, respectively. Analysis of MP abundance for different sampling points showed that the water of Shiwuli River had an average abundance of MPs of 8.4 ± 2.5 particles/L during the flood season and 5.8 ± 1.7 particles/L during the non-flood season; the sediment had an average abundance of MPs of 78.9 ± 8.3 particles/kg during the flood season and 63.9 ± 7.1 particles/kg during the non-flood season. The abundance of MPs of different points was investigated. Result show that the more abundances of MPs were found at confluences with tributaries (S4, S5, and S6), where they are also close to the residential and industrial development, while lower values were found in agricultural areas (S8) and wetland ecological regions (S9 and S10). In water, the maximum appeared at S5 with 21.7 ± 4.6 particles/L during the flood season and 15.9 ± 4.2 particles/L during the non-flood season, respectively; the minimum appeared at S9 with 1.8 ± 1.0 particles/L during the flood season and 2.2 ± 0.4 particles/L during the non-flood season, respectively. In sediment, the maximum appeared at S5 with 174.1 ± 10.1 particles/kg during the flood season and 143.6 ± 10.4 particles/kg during the non-flood season, respectively; the minimum appeared at S8 with 10.3 ± 2.8 particles/kg during the flood season and at S9 with 12.1 ± 3.2 particles/kg during the non-flood season, respectively. MP characteristics were also studied. Results show that the MPs mainly exhibited a fibroid morphology (27.90–34%), and red-coloured particles (19.10%) within the smaller size less than 500 μm (38.60%) were more prevalent. Additionally, the result of LDIR scanning shows that a total of eleven types of MP polymers were found in the river water and sediment, including acrylates (ACR), chlorinated polyethylene (CPE), ethylene vinyl acetate (EVA), polyethylene (PE), polyethylene terephthalate (PET), polypropylene (PP), polystyrene (PS), polyurethane (PU), polyvinylchloride (PVC), polyamide (PA), and silicon. The most common particle was PE (19.3–21.6%). Furthermore, the environmental risk assessment demonstrated that the PS polymer posed a Level-III risk in the water samples and a Level-II risk in the sediment samples from the Shiwuli River. The remaining polymer types exhibited Level-I risk. The PLIzone value for water was 2.24 during the flood season, indicating heavy pollution, and 1.66 during the non-flood season, indicating moderate pollution. Similarly, the PLIzone value for sediments was 2.34 during the flood season and 1.91 during the non-flood season, both suggesting a heavy pollution. These findings highlight the potential risk posed by MP pollution in the Shiwuli River to the quality of drinking water sources in Chaohu Lake in Hefei. They provide valuable insights into management, pollution control, and integrated management strategies pertaining to MPs in urban inland rivers in Hefei. [ABSTRACT FROM AUTHOR]

As one of the primary nodes in the flow of micro-plastics (MPs) in the environment, it is critical to examine and assess the Sewage Treatment, occurrence, and removal of MPs in waste treatment plant (WWTP). This research explored the shape, size, and composition of MPs at various stages of the WWTP process in the south of the city of Hefei, China, in dry and rainy weather conditions, as well as the removal effectiveness of MPs in a three-stage process. The collected MPs were quantitatively and qualitatively examined using an Osmosis electron microscope and micro-FTIR. The pollution risk of MPs in WWTP was assessed using the EU classification, labelling and packaging (CLP) standard and the pollution load index (PLI). The findings revealed that the average abundance of fibrous MPs was greatest in WWTP sewage and sludge, 49.3% and 39.7% in dry weather, and 50.1% and 43.2% in rainy weather, respectively. The average distribution of MPs in the 0–500 μm range was highest in WWTP wastewater and sludge, 64.9% and 60.4% in dry weather and 67.9% and 69.0% in rainy weather, respectively. Finally, the overall removal rate was 87.7% and 83.5%. At the same time, it has been demonstrated that MPs with varied compositions are strongly tied to human activities, and environmental conditions (such as rainy weather) also influence their source. In both dry and wet weather, the amount of polymers and the risk score were linked to the pollution risk of MPs in WWTP. In wet weather, the MPS pollution index was more variable. The pollution indices of MPs in row water and tail water were 2.40 and 2.46, respectively, which were heavily contaminated, and 1.0 and 1.2, which were moderately polluted. MPs in dewatered sludge had severely polluted indexes of 3.5 and 3.4, respectively. As a result, there is still MPs efflux or buildup in sludge during and after the WWTP process, which presents an ecological contamination concern. [ABSTRACT FROM AUTHOR]

Excess bisphenol A (BPA) is a pollutant of concern in different water sources. In this work, magnetic illite clay-composite material (Fe 3 O 4 @illite) was synthesized via the coprecipitation method by loading Fe 3 O 4 nanoparticles (nano-Fe 3 O 4) onto the surfaces of illite clay. Results from different characterizations showed that nano-Fe 3 O 4 was embedded into illite clay nanosheets and existed on the surfaces of illite clay, thereby reducing the degree of agglomeration and improving dispersibility. The catalytic BPA degradation of Fe 3 O 4 @illite and nano-Fe 3 O 4 confirmed the superior performance of Fe 3 O 4 @illite compared with that of nano-Fe 3 O 4. The optimum operating parameters for degradation were 0.3 mL of H 2 O 2 at pH of 3 in the presence of Fe 3 O 4 @illite, which provided a maximum degradation capacity up to 816, 364, 113, and 68 mg/g for epoxy BPA concentration of resin wastewater (266 mg/L), synthetic wastewater (80 mg/L), Hefei City swan lake (25 mg/L), and Hefei University lake wastewater (14.94 mg/L), respectively, in 180 min reaction time. The degradation data conformed to the pseudo-first-order kinetic model. The degradation pathways and mineralization study revealed that the adsorption-Fenton-like reaction was the principal mechanism that demonstrated 100% degradation efficiency of Fe 3 O 4 @illite even after nine successive runs. The regeneration and reusability tendency analysis ensured that Fe 3 O 4 @illite can be easily separated by using magnets. Therefore, Fe 3 O 4 @illite composite with H 2 O 2 Fenton-like technology was a promising method for BPA degradation. Image 1 • Fe 3 O 4 @illite was successfully synthesized via a simple co-precipitation. • The maximum degradation capacity of Fe 3 O 4 @illite reached up to 364 mg/g. • Adsorption and Fenton-like oxidation were dominant removal mechanism. • BPA removal remained 100% after nine successive runs. • Magnetic separation of Fe 3 O 4 @illite was possible as a regeneration mechanism. [ABSTRACT FROM AUTHOR]