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Abstract We analyze Pb content and Pb isotope ratios in 29 surface sediments and one sediment core from the eastern Beibu Gulf, Southern China. The results indicate that obvious Pb enrichment was limited to the oil and gas exploration area in the central gulf and the mud deposit in the northern gulf. The enrichment of Pb in sediment core A97 started in the 1860s, but a notable drop of Pb content occurred in the 1970s, suggesting variations in human activity. The Pb isotope ratios in sediments were very similar to those in natural sources, except for the sediments near the oil platform, which may be polluted by anthropogenic input. Sediments with relatively high radiogenic Pb isotope compositions may be mainly sourced from northern coast of Beibu Gulf, sediment flux through Qiongzhou Strait, or the Red River, while the coastal zone of western Hainan Island and nearby bottom erosion area produce as minor provenances. Highlights • Higher Pb contents appeared near Qiongzhou Bay in the northern Beibu Gulf. • The Pb is mainly natural rock weathering products, not anthropogenic inputs. • The Pb from human activities play important roles in oil-gas exploration areas. • Core A97 Pb showed an enrichment since 1860s, but a notable drop in 1970s. [ABSTRACT FROM AUTHOR]

The concentrations of six heavy metals (Cd, Cr, Cu, Pb, Zn, and As) in offshore surface sediments of western Pearl River Estuary were analyzed to investigate their sources and spatial variations using factorial kriging analysis. Three-scale spatial variations in heavy metal concentrations were identified and separated: nugget, local, and regional scale, which indicated sample errors, anthropogenic pollution and natural variation, respectively. Anthropogenic heavy metals varied sharply and heterogeneous at range of 60 km. Maoming Port, Hailing Bay and coastal area northeastern Hainan Island were potential polluted areas of Cd, Cr, Cu, Pb, Zn and As, also the Nandu River, Baoling River and Wanquan River estuaries were potential polluted areas of As. These polluted areas ranged up to 60 km in size and tended to extend with currents. The natural heavy metals varied continuously and relatively homogeneous at range of 180 km, which was dominated by riverine input and paleo-sea-level changes. [Display omitted] • Heavy metal concentrations exhibited three-scale spatial variations: nugget, local scale, and regional scale. • Anthropogenic variation of heavy metals at local scale occurred sharply and heterogeneous. • Areas polluted by the heavy metals ranged up to 60 km in size and tended to extend with currents. • Natural heavy metals at regional scale varied continuously and relatively homogeneous. • Natural variation of heavy metals was dominated by riverine input and paleo-sea-level changes. [ABSTRACT FROM AUTHOR]

There are very few studies on the granites formed in Late Permian in Hainan (海南) Island. Petrology, geochronology and geochemistry research on Late Permian granites in Chahe (叉河) area, Hainan Island will be reported in this article. The results show that, Chahe granites formed in 251 Ma, are riched in SiO, alkali, FeO while depleted in MgO and CaO, with low Sr and high Yb, and have all the features consistent with A-type granite. The forming of Chahe granites may suggest that Hainan Island was already in post-orogenic setting in Late Permian. [ABSTRACT FROM AUTHOR]

A total of 388 surface sediment samples taken from the northern South China Sea (SCS) continental shelf were analyzed to characterize the signature of their rare earth elements (REEs). The average REEs concentration was 192.94 μg/g, with a maximum of 349.07 μg/g, and a minimum of 32.97 μg/g. The chondrite-normalized REEs pattern exhibits a remarkably light REEs accumulation, a relatively flat heavy REEs pattern, and a negative Eu anomaly. We subdivided the study area into three zones using the characteristics of REEs and statistical characteristics. Zone I: continental shelf off western Guangdong Province. Here, the sediment provenance is mainly river-derived from the Pearl River, Taiwanese rivers, and those in the adjacent area. Zone II: Qiongzhou Strait and Leizhou Peninsula. Here, the sediment provenance consists of the Qiongzhou Strait and the Hainan Island. Zone III: Hainan Island and SCS slope sediments are dominated. The REEs compositions are mainly controlled by source rock properties, hydrodynamic conditions, and an intensity of chemical weathering. We reconstructed the sediment dispersal and transport route using the REEs compositions, grain size, and other geochemical characteristics throughout the study area. [ABSTRACT FROM AUTHOR]

The nature of upper mantle is important to understand the evolution of the South China Sea (SCS); thus, we need better constrains on its mantle heterogeneity. Magma water concentration is a good indicator, but few data have been reported. However, the rarity of glass and melt inclusions and the special genesis for phenocrysts in SCS basalts present challenges to analyzing magmatic water content. Therefore, it is possible to estimate the water variations through the characteristics of partial melting and magma crystallization. We evaluated variations in Fe depletion, degree of melt fractions, and mantle source composition along the fossil spreading ridge (FSR) using SCS basalt data from published papers. We found that lava from the FSR 116.2° E, FSR 117.7° E, and non-FSR regions can be considered normal lava with normal water content; in contrast, lava from the FSR 117° E-carbonatite and 114.9–115.0° E basalts have higher water content and show evidence of strong Fe depletion during the fractional crystallization after elimination of the effects of plagioclase oversaturation. The enriched water in the 117° E-carbonatite basalts is contained in carbonated silicate melts, and that in the 114.9–115.0° E basalts results from mantle contamination with the lower continental crust. The lava from the 117° E-normal basalt has much lower water content because of the lesser influence of the Hainan plume. Therefore, there must be a mantle source compositional transition area between the southwestern and eastern sub-basins of the SCS, which have different mantle evolution histories. The mantle in the west is more affected by contamination with continental materials, while that in the east is more affected by the Hainan mantle plume. [ABSTRACT FROM AUTHOR]