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Different coatings of the metal implants of STAR prostheses have been used since 1999. In Europe metal implants with a double calcium-phosphate coating (BONIT) on a titanium sprayed surface have been available since 1999. We present a 2–17 year follow-up of a consecutive series from a single center with 474 STAR ankle replacements where the BONIT type of coating has been used. 55 prostheses (12%) have been revised, the majority of them due to fracture of the mobile bearing. 22 prostheses (5%) have been converted to an arthrodesis. Analysis of survival of the specific components showed an estimated 10-year survival rate of the tibia component, talus component and polyethylene mobile bearing of 99%, 98% and 84%, respectively. The corresponding estimated 15-year survival was 98%, 98% and 74%, respectively. This study showed an extraordinary high survival rate of the metal implants. Level III, prospective cohort series. [ABSTRACT FROM AUTHOR]

Due to the ever-growing demand for bast fibres for technical and garment textiles, complementary sources to textile flax, whose cultivation in western Europe cannot really be extended, need to be proposed. In this study, the interest in harvesting and processing linseed flax straw is studied for geotextile applications. The main critical stages of fibre-to-yarn production for geotextiles were investigated. Different dew retting levels as well as different all-fibre extraction processes were investigated to achieve this objective. It was demonstrated that the fibres extracted from linseed flax stems subjected to 12 weeks of dew retting using breaking rollers, thresher and a breaking card exhibited the most suitable morphological and mechanical properties. The optimal fibres were converted into 100% linseed flax yarns using a flyer spinning machine, and the mechanical properties as well as the biodegradability of the linseed yarns were evaluated to understand their potential as geotextiles. These linseed flax yarns were further coated with linseed oil or chitosan to enhance their durability. It was observed that the linseed oil coating better preserved the yarn's integrity and mechanical properties over time, and it permitted doubling their service life potential. [ABSTRACT FROM AUTHOR]

Background: Infection is one of the main reasons for failure of orthopedic implants. Antibacterial coatings may prevent bacterial adhesion and biofilm formation, according to various preclinical studies. The aim of the present study is to report the first clinical trial on an antibiotic-loaded fast-resorbable hydrogel coating (Defensive Antibacterial Coating, DAC®) to prevent surgical site infection, in patients undergoing internal osteosynthesis for closed fractures.Materials and Methods: In this multicenter randomized controlled prospective study, a total of 256 patients in five European orthopedic centers who were scheduled to receive osteosynthesis for a closed fracture, were randomly assigned to receive antibiotic-loaded DAC or to a control group (without coating). Pre- and postoperative assessment of laboratory tests, wound healing, clinical scores and X-rays were performed at fixed time intervals.Results: Overall, 253 patients were available with a mean follow-up of 18.1 ± 4.5 months (range 12-30). On average, wound healing, clinical scores, laboratory tests and radiographic findings did not show any significant difference between the two groups. Six surgical site infections (4.6%) were observed in the control group compared to none in the treated group (P < 0.03). No local or systemic side-effects related to the DAC hydrogel product were observed and no detectable interference with bone healing was noted.Conclusions: The use of a fast-resorbable antibiotic-loaded hydrogel implant coating provides a reduced rate of post-surgical site infections after internal osteosynthesis for closed fractures, without any detectable adverse event or side-effects.Level Of Evidence: 2. [ABSTRACT FROM AUTHOR]

• Investigation of post-constructive use of different PCM coatings under diverse environmental conditions. • Use of a validated finite elements numerical model is utilized, as well as Life Cycle Assessment. • Holistic determination of the optimal application conditions of PCM coatings. • The overall environmental performance of the investigated structural elements is defined. • PCM results to energy savings from 0.24 up to 29,84 [kWh/m2a] and energy payback periods from 0.81 to 19.40 years. In recent years, the post-constructive application of phase changing materials (PCMs) as coating to improve the thermal behavior of buildings, is gaining more ground. The question that arises concerns the required properties that these materials should have under different environmental conditions, in order to achieve optimal energy savings. Another issue concerns the overall evaluation of PCMs, considering sustainability assessment practices, a fact which is often neglected in PCM studies. This work investigates the post-constructive use of different PCM coatings under diverse environmental conditions, as well as for different structural elements. In the context of this work, a validated finite elements numerical model is utilized, as well as Life Cycle Assessment practices, for the holistic determination of the optimal application conditions of PCM coatings. The work examines the application of PCM coatings in 8 different structural elements, for diverse meteorological conditions in Europe, for all major buildings' orientations. Life Cycle Assessment is also employed to determine the overall environmental performance of the investigated structural elements. In certain cases, the study revealed that PCM implementation can contribute to energy savings, varying from 0.24 up to 29,84 [kWh/m2a] and energy payback periods from 0.81 to 19.40 years. The purpose of this study is to provide informed answers with regard to the post-constructive application of PCM in existing structures for the energy upgrade of buildings. [ABSTRACT FROM AUTHOR]

• Experimental tests were carried out for the evaluation of water repellents for masonry. • Infrared thermography was used to monitor the wetting and drying of laboratory walls. • Wetting and drying test were also carried out on treated/untreated bricks samples. • Multitemporal IRT images were processed by Change Detection Analysis (CDA) • Interesting data were obtained on water repellents' effectiveness and compatibility. Moisture is one of the main problems that affect new and historic masonry buildings, which are the most common ones in Europe and worldwide. The application of surface treatments based on water-repellents is a very common solution to protect masonry from rain and hence from moisture-related problems. However, there are very few studies on the monitoring of water-repellents in real buildings and a deeper knowledge would be necessary on the long-term effectiveness and compatibility of water repellents, especially considering that defects and flaking issues are often reported in-the-field. In this paper, infrared thermography was proposed as a totally non-invasive technique to monitor the behaviour of brick masonry subjected to wetting, both from outside (rain) and inside (internal moisture). An active thermal approach was used to simulate internal and external wetting. The behaviour of the masonry during wetting and drying was investigated both in laboratory walls and in brick samples, to elucidate their water transport properties. All the materials were tested both in untreated conditions and after the application of two different hydrophobic coatings. The results show that the drying behaviour of treated masonry materials is a critical issue, as the coatings may strongly slow down the drying of internal moisture, even if the coefficient of resistance to water vapour diffusion of the products is very low. The results also suggest that the methodology used to process thermal images using multi-temporal analysis is a promising way to interpret the water transport in treated walls and to monitor real buildings where water-repellents were applied. [ABSTRACT FROM AUTHOR]

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Autoxidation processes to achieve curing of alkyd resins in paints, inks, and coatings are ubiquitous in many applications. Cobalt soaps have been employed for these applications for many decades and most of the paint and ink alkyd resin formulations have been optimized to achieve optimal benefits of the cobalt soaps. However, cobalt soaps are under increased scrutiny because of likely reclassification as carcinogenic under REACH (Registration, Evaluation, Authorisation, and Restrictions of Chemicals) legislation in Europe. This is critical, since such coatings are available for regular human contact. Alternative manganese- and iron-based siccatives have been developed to address this need for over a decade. They often show very high curing activity depending on the organic ligands bound to the metal centers. Recently, new classes of catalysts and modes of application have been published or patented to create safe paints, whilst delivering performance benefits via their unique reaction mechanisms. Besides the use of well-defined, preformed catalysts, paint formulations have also been developed with mixtures of metal soaps and ligands that form active species in-situ. The change from Co-soaps to Mn- and Fe-based siccatives meant that important coating issues related to radical-based curing, such as skinning, had to be rethought. In this paper we will review the new catalyst technologies and their performance and modes of action, as well as new compounds developed to provide anti-skinning benefits. [ABSTRACT FROM AUTHOR]