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[Display omitted] • Validation performed on concrete/mortar mockups representative of 7 case studies. • Mockups specimens were aged by carbonation, induced cracks and carbonation. • Elastic modulus increase is more marked of physically damaged mockups. • Carbonated mockups are mostly improved in terms of surface hardness after treatment. • Addition of alkylsiloxane/alkylalkoxysilane decreases water absorption by over 75%. Many of the concrete structures that conform our modern cultural heritage are in need of repair and protective interventions. Silane-based impregnation treatments can be used to repair onset cracks and reinforce the surface due to their ability to produce silica and C-S-H gels, and can be modified by incorporating hydrophobic precursors to create multifunctional treatments that also protect from water ingress. Since the effectiveness of impregnation treatments is dependent on substrate properties and chemical-physical changes it may have experienced over time, validation using standard materials may not always be representative of on-site application. In this work, the effectiveness of three innovative silane-based impregnation treatments developed by our group (two of them combining superhydrophobic properties) was evaluated on mockup specimens, which simulate the properties of the cementitious materials from six different heritage structures across Europe, artificially aged to simulate weathering by three methods: carbonation, chloride ingress and physical damages (freeze–thaw and thermal cycles). The characterization of the treatments showed they are compatible in terms of chemical interaction, applicability and minimal aesthetical alterations. Surface resistance and ultrasound pulse measurements have been used to assess the improvement in mechanical properties. The incorporation of hydrophobic components and fumed silica has a relatively low impact over the mechanical properties while it significantly reduces water absorption and grants water repellent properties to the surface, giving rise to a superhydrophobic performance. [ABSTRACT FROM AUTHOR]

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