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Abstract: The chemical speciation of zinc in soil solutions is critical to the understanding of its bioavailability and potential toxic effects. We studied the speciation of Zn in soil solution extracts from 66 contaminated soils representative of a wide range of field conditions in both North America and Europe. Within this dataset, we evaluated the links among the dissolved concentrations of zinc and the speciation of Zn2+, soil solution pH, total soil Zn, dissolved organic matter (DOM), soil organic matter (SOM) and the concentrations of different inorganic anions. The solid–liquid partitioning coefficient (K d) for Zn ranged from 17 to 13,100Lkg−1 soil. The fraction of dissolved Zn bound to DOM varied from 60% to 98% and the soil solution free Zn2+ varied from 40% to 60% of the labile Zn. Multiple regression equations to predict free Zn2+, dissolved Zn and the solid–liquid partitioning of Zn are given for potential use in environmental fate modeling and risk assessment. The multiple regressions also highlight some of the most important soil properties controlling the solubility and chemical speciation of zinc in contaminated soils. [Copyright &y& Elsevier]

The impact of soil properties on metal bioavailability to plants is well recognized. However, the effect of soil bioavailability parameters on toxicity threshold values for Cu in plants needs quantification. Eighteen European soils varying widely in soil properties were amended with CuCl2 to obtain a range of seven concentrations including an unamended control. Two plant toxicity assays, barley root elongation (4 d) and tomato shoot growth (21 d after emergence), were performed on each soil under controlled environment conditions. The effective concentration of added Cu causing 50% inhibition (EC50) ranged from 36 to 536 mg/kg soil and from 22 to 851 mg/kg soil for barley root elongation and tomato shoot growth, respectively, representing variation in EC50 among soils of 15- and 39-fold. Single regressions carried out between Cu toxicity threshold values and various soil properties showed that exchangeable calcium and soil cation exchange capacity (CEC; measured at soil pH) were the best single predictors for toxicity values from both plant tests. The inclusion of other soil properties, such as iron oxide concentration, soil pH, clay, or organic carbon content, further improved predictions. For risk assessment, we suggest that Cu toxicity threshold values (EC50) be normalized on the key soil property of CEC. If available, soil exchangeable calcium and iron oxide concentration would improve the normalization. [ABSTRACT FROM AUTHOR]

• Data of lab, greenhouse and 33 field trials allowed analyzing P dynamics in soil. • Only 27% of the P mass balance found in the extractable P pool of the topsoil. • More but not all P found by aqua regia extraction and including deeper soil layers. • Net P addition is required to maintain target soil P values. A sustainable supply of phosphorus (P) to agricultural soils should maintain soil fertility without jeopardizing the environment. This study analyzed the change in the soil P as a function of the net soil P mass balance, i.e. the input minus removal by the harvested crop. The P available for crops was estimated by the P extracted by ammonium lactate at pH 3.75 (P-AL). First, laboratory and pot-trial data showed that the net change in soil P-AL was only 68% of the change in total soil P, either when P had been added to soil or when P had been mined by plants for 1–2 years, indicating removal to or release from the non-extractable pool depending on the balance. Secondly, data were collated from 33 field trials in Europe with a wide range of cumulative soil P balances (−1200 to +2500 kg P ha−1) in time spans ranging from 3 to 51 years. The average change in P-AL across the negative and positive balance was only 27% (95% confidence interval 25–30%) of the net balance. The change in P-AL was larger as the net balance increased and as the initial P-AL decreased. The slope of the change versus the balance was smaller as time increased and initial P-AL decreased. The other soil characteristics did not affect these changes, and the model developed was not different for negative or positive P balances. Our results suggest that a steady state P-AL concentration at optimal P supply for crops is obtained at a net P balance of about 1–10 kg P ha−1. The P mass balance of a 51 year-old trial showed that the aqua regia soluble P of the 0–90 cm layer accounted for only 64% of the net P balances at the surface. This still incomplete P balance could be related to upward P transport by plant uptake from > 90 cm soil layers, lateral P movement in the field, and changes in the soil P fraction that could not be extracted with aqua regia. This study quantified the long-term dynamics of P-AL, which is useful for agronomic and environmental purposes and policy, and pointed out the importance of non-extractable P and vertical P movement. [ABSTRACT FROM AUTHOR]