Search

Lead chromate was commonly employed as a pigment in coloured road markings until restrictions led to the development of safer alternatives. In this study, the presence and concentrations of Pb and Cr have been determined in 236 road paints of various colours sampled from streets, highways, footways and carparks from eleven European countries. According to energy-dispersive X-ray fluorescence spectrometry, Pb was detected (>10 mg kg -1 ) in 148 samples at concentrations up to 17.2% by weight, and above 1000 mg kg -1 yellow was the dominant paint colour. Lead concentrations on an area basis varied from 0.02 to 8.46 mg cm -2 and the metal was located at different depths amongst the samples, suggesting that formulations had been painted both recently and historically (and overpainted). Chromium was detected (>5 to 50 mg kg -1 ) in 81 samples at concentrations between 20 and 20,000 mg kg -1 and most often in yellow paints, and concentrations co-varied with those of Pb. These observations, and results of scanning electron microscopy coupled with energy-dispersive X-ray spectrometry, suggested that heterogeneously dispersed PbCrO 4 was the dominant, but not the only, Pb-based pigment in the samples. Although there were significant international differences in frequency of Pb detection and median Pb concentrations, overall, and despite various, albeit complex, regulations, recent or extant road paint pigmented with Pb and Cr remains a pervasive environmental problem and a potential health risk in many European countries., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 The Authors. Published by Elsevier Ltd.. All rights reserved.)

Kohl is an eye cosmetic that was traditionally used in many Asian and African countries but that is now more widely available. Ingredients of kohl reported in previous studies seem to be rather variable but mention is frequently made of minerals based on Pb whose use in cosmetic products is prohibited in Europe. We purchased 23 products of kohl from retail outlets in five different European countries and over the internet and analysed their chemical composition by XRF and SEM-EDXS. The majority of the products (n = 17) did not conform with European legislation based on the presence of Pb (often as galena), whose concentrations ranged from a few mg kg -1 to over 400000 mg kg -1 . Cadmium, another element prohibited in cosmetic products in Europe, was also present as a contaminant in 13 products at concentrations up to a few hundred mg kg -1 . In addition to heavy metals, minerals of other metals (e.g. Fe and Zn) appeared to be present in the nano-size range and might represent an additional health hazard. Clearly, the lack of quality control in the manufacture of kohl results in the widespread occurrence of toxic and unwanted elements and the trade of illegal products in Europe. In principle, shop sales would be relatively straightforward to prevent, but products traded through internet are more difficult to regulate., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2020 The Authors. Published by Elsevier Inc. All rights reserved.)