Search

Nitrifying biologically active filters (BAFs) have been found to be high emitters of nitrous oxide (N 2 O), a powerful greenhouse gas contributing to ozone layer depletion. While recent models have greatly improved our understanding of the triggers of N 2 O emissions from suspended-growth processes, less is known about N 2 O emissions from full-scale biofilm processes. Tertiary nitrifying BAFs have been modeled at some occasions but considering strong simplifications on the description of gas-liquid exchanges which are not appropriate for N 2 O prediction. In this work, a tertiary nitrifying BAF model including the main N 2 O biological pathways was developed and confronted to full-scale data from Seine Aval, the largest wastewater resource recovery facility in Europe. A mass balance on the gaseous compounds was included in order to correctly describe the N 2 O gas-liquid partition, thus N 2 O emissions. Preliminary modifications of the model structure were made to include the gas phase as a compartment of the model, which significantly affected the prediction of nitrification. In particular, considering gas hold-up influenced the prediction of the hydraulic retention time, thus nitrification performances: a 3.5% gas fraction reduced ammonium removal by 13%, as the liquid volume, small in such systems, is highly sensitive to the gas presence. Finally, the value of the volumetric oxygen transfer coefficient was adjusted to successfully predict both nitrification and N 2 O emissions., (Copyright © 2019 Elsevier Ltd. All rights reserved.)