1. Simulating estuarine nitrous oxide production by means of a dynamic model
- Author
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Rodrigues, P.P.G.W., Barnes, J., and Upstill-Goddard, R.C.
- Subjects
ATMOSPHERIC nitrous oxide ,HYDROLOGIC models ,ESTUARINE ecology ,NITRIFICATION ,NITROGEN in water ,NITRIFYING bacteria ,GROWTH rate - Abstract
Abstract: We describe a dynamic model developed from a commercially available modeling package (ECoS-III) to simulate estuarine dissolved inorganic nitrogen (DIN) dynamics, and consequent N
2 O production and atmospheric flux on the timescale of tidal cycles. Simulated model state variables were , and N2 O concentrations, and salinity. Model outputs were evaluated through comparison with summer field data for the Tyne estuary, UK. The model adequately reproduced the observed axial profiles of , and N2 O concentrations. Nitrification was shown to be the dominant N2 O source and estimates of the ratios nitrification to DIN load and N2 O emission to DIN load are considerably lower than the corresponding values adopted in global scale models of estuarine N2 O emissions based on DIN transformations. Hence our results are consistent with the requirement imposed by atmospheric N2 O growth rate constraints that the amount of atmospheric N2 O arising from agriculturally related sources, including estuarine transformations of N, be revised downward. [Copyright &y& Elsevier]- Published
- 2007
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