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Summary: Hydrochemical and stable isotopic (2H, 18O) data were used to characterize the groundwater flow and major chemical features within a complex fractured volcanic aquifer system, the Argnat basin, which is located in the Chaîne des Puys (French Massif Central). From 10 sampling points, the study of the transfer into the saturated zone from upstream to downstream, given the geological context and topography, allows to estimate the role of supply from high and low altitudes to the recharge processes. This work shows the existence of different types of supply between pahoehoe and a’a flows. Therefore, the morphology of volcanic flows impacts the chemical and isotopic signatures of groundwater, enhancing or reducing the influence of the unsaturated zone on the pathways of infiltrated water. Pahoehoe flows imply horizontal water flows of low discharge at the top of the lava whereas a’a flows seems to be much more heterogeneous and locally able to promote the existence of perched water bodies and further vertical circulations. Taking into account these two types of behaviour, a conceptual scheme of the functioning of this heterogeneous environment is proposed, which will help towards a sustainable management of volcanic aquifers in relation with the . [ABSTRACT FROM AUTHOR]