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In recent years, winter PM 2.5 and summer O 3 pollution which often occurred with air stagnation condition has become a major concern in China. Thus, it is imperative to understand the air stagnation distribution in China and elucidate its impact on air pollution. In this study, three air stagnation indices were calculated according to atmospheric thermal and dynamics parameters using ERA5 data. Two improved indices were more suitable in China, and they displayed similar characteristics: most of the air stagnant days were found in winter, and seasonal distributions showed substantial regional heterogeneity. During stagnation events, flat west or northwest winds at 500 hPa and high pressure at surface dominated, with high relative humidity (RH) and temperature (T), weak winds in most regions. The pollutants concentrations on stagnant days were higher than those on non-stagnant days in most studied areas, with the largest difference of the 90th percentiles of maximum daily 8-h average (MDA8) O 3 up to 62.2 μg m -3 in Pearl River Delta (PRD) and PM 2.5 up to 95.8 μg m -3 in North China Plain (NCP). During the evolution of stagnation events, the MDA8 O 3 concentrations showed a significant increase (6.0 μg m -3 day -1 ) in PRD and a slight rise in other regions; the PM 2.5 concentrations and the frequency of extreme PM 2.5 days increased, especially in NCP. Furthermore, O 3 was simultaneously controlled by temperature and stagnation except for Xinjiang (XJ), with the average growth rate of 19.5 μg m -3 every 3 °C at 19 °C-31 °C. PM 2.5 was dominated by RH and stagnation in northern China while mainly controlled by stagnation in southern China. Notably, the extremes of summer O 3 (winter PM 2.5 ) pollution was most associated with air stagnation and T at 25 °C-31 °C (air stagnation and RH >50%). The results are expected to provide important reference information for air pollution control in China., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2021. Published by Elsevier B.V.)

Absorbing carbonaceous aerosols, i.e. black and brown carbon (BC and BrC), affected heavily on climate change, regional air quality and human health. The nationwide lockdown measures in 2020 were performed to against the COVID-19 outbreak, which could provide an important opportunity to understand their variations on light absorption, concentrations, sources and formation mechanism of carbonaceous aerosols. The BC concentration in Wuhan megacity (WH) was 1.9 μg m -3 during lockdown, which was 24% lower than those in the medium-sized cities and 26% higher than those in small city; in addition, 39% and 16-23% reductions occurred compared with the same periods in 2019 in WH and other cities, respectively. Fossil fuels from vehicles and industries were the major contributors to BC; and compared with other periods, minimum contribution (64-86%) mainly from fossil fuel to BC occurred during the lockdown in all cities. Secondary BrC (BrCsec) played a major role in the BrC light absorption, accounting for 65-77% in WH during different periods. BrCsec was promoted under high humidity, and decreased through the photobleaching of chromophores under higher Ox. Generally, the lockdown measures reduced the BC concentrations significantly; however, the variation of BrCsec was slight., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2021 Elsevier B.V. All rights reserved.)

Carbonaceous aerosols in high emission areas attract worldwide attention of the scientific community and the public due to their adverse impacts on the environment, human health and climate. However, long-term continuous hourly measurements are scarce on the regional scale. In this study, a one-year hourly measurement (from December 1, 2016 to November 30, 2017) of organic carbon (OC) and elemental carbon (EC) in airborne fine particles was performed using semi-continuous OC/EC analyzers in Beijing, Tianjin, Shijiazhuang and Tangshan in the Beijing-Tianjin-Hebei (BTH) region in China, which is one of high emission areas in China, even in the world. Marked spatiotemporal variations were observed. The highest concentrations of OC (22.8 ± 30.6 μg/m 3 ) and EC (5.4 ± 6.5 μg/m 3 ) occurred in Shijiangzhuang while the lowest concentrations of OC (11.0 ± 10.7 μg/m 3 ) and EC (3.1 ± 3.6 μg/m 3 ) were obtained in Beijing and Tianjin, respectively. Pronounced monthly, seasonal and diurnal variations of OC and EC were recorded. Compared to published data from the past two decades for the BTH region, our OC and EC levels were lower, implying some effect of recent measures for improving the air quality. Significant correlations of OC versus EC (p < 0.001) were found throughout the study period with high slopes and correlation coefficients in winter, but low slopes and correlation coefficients in summer. The estimated secondary OC (SOC), based on the minimum R squared (MRS) method, represented 29%, 47%, 38% and 48% of the OC for Beijing, Tianjin, Shijiazhuang and Tangshan, respectively. These percentages are larger than previous ones obtained for the BTH region in the past decade. There were obvious differences in the potential source regions of OC and EC among the four cities. Obvious prominent potential source areas of OC and EC were observed for Beijing, which were mainly located in the central and western areas of Inner Mongolia and even extended to the Mongolian regions, which is different from the findings in previous studies. For all sites, adjacent areas of the main provinces in northern China were found to be important potential source areas., (Copyright © 2019 The Authors. Published by Elsevier Ltd.. All rights reserved.)