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This study aimed to assess the pollution levels, sources, and human health risks of heavy metals in street dust from a typical industrial district in Wuhan City, Central China. In total, 47 street dust samples were collected from the major traffic arteries and streets around Wuhan Iron and Steel (Group) Company (WISC) in Qingshan District, Wuhan. The concentrations of heavy metals (Cr, Mn, Ni, Zn, Fe, Cu, and Cd) in street dust were determined by atomic absorption spectroscopy. Results indicated that the mean concentrations of Zn (249.71 mg/kg), Cu (51.15 mg/kg), and Cd (0.86 mg/kg) in street dust were higher than their corresponding soil background values in Hubei Province. Heavy metal enrichment is closely related to urban transportation and industrial production. The pollution level of heavy metals in street dust was assessed using the geo-accumulation method ( I geo ) and potential ecological risk assessment (PERI). Based on the I geo value, Cr, Mn, Fe, and Ni showed no pollution, Zn and Cu showed light to moderate contamination, and Cd showed moderate contamination. The PERI values of heavy metals in street dust ranged between 76.70 and 7027.28, which represents a medium to high potential ecological risk. Principal component analysis showed that the sources of heavy metals in street dust were mainly influenced by anthropogenic activities. Among the studied metals, Cu, Cr, Zn, Fe, and Mn mainly come from industrial processes, while Ni and Cd come from traffic exhaust. The non-carcinogenic risk indexes of heavy metals for children and adults are ranked as Cr > Cu > Ni > Cd > Zn. The health risks to children through the different exposure pathways are higher than those for adults. Hand-to-mouth intake is the riskiest exposure pathway for non-carcinogenic risk. In addition, Cr, Ni, and Cd do not pose a carcinogenic risk for the residents.

Twenty dust samples collected from Wuchang and Wuhan Railway Stations, the biggest transport stations in the mega traffic hub city in Central China, were analyzed for polycyclic aromatic hydrocarbons (PAHs) to investigate the concentration, sources apportionment, and relationship with black carbon (BC) and assess the health risk. The results suggested that the concentrations of PAHs, BC and TOC in Wuhan Railway Station (WHRS) (PAHs = 5940 ± 1920 ng g -1 , BC = 53.2 ± 23.1 mg g -1 and TOC = 80.7 ± 44.4) were twice higher than those in Wuchang Railway Station (WCRS) (PAHs = 2580 ± 1630 ng g -1 , BC = 20.4 ± 14.3 mg g -1 and TOC = 33.9 ± 20.1 mg g -1 ). Moreover, the 3 - and 4 - rings PAHs were major PAHs in railway station dust. The composition pattern of PAHs in these railway station dusts had a common characteristic with HMW-PAHs contribution. The results of source identification revealed that different local development features and energy consumption of trains would influence the sources of PAHs and BC. PAHs and BC were most likely related to industrial activities in WHRS. Coal and biomass combustion may influence the PAHs components and BC distribution in WCRS. Moreover, BC had played an important role in retaining PAHs in urban railway stations. Especially in WHRS, BC would more likely to absorb the high molecular weight PAHs, such as 4 -ring (p<0.05), 5 -ring (p<0.05) and 6 -ring (p<0.05) PAHs; while BC just played limited roles in the binding of volatile and semi-volatile organic pollutants, such as 2 -ring and 3 -ring PAHs. With the coexistence of BC and PAHs, passengers would face significant potential health risks by exposure to toxic dust in railway stations, especially for children. The cancer risk in WHRS was almost twice higher than that in WCRS, and it would tend to be stable by a semi-confined structure in the platform area., (Copyright © 2020 Elsevier Inc. All rights reserved.)

Aerosol samples of PM 2.5 and PM 10 were collected every 6 days from March 2012 to February 2013 in Huangshi, a typical industrial city in central China, to investigate the characteristics, relationships, and sources of carbonaceous species. The PM 2.5 and PM 10 samples were analyzed for organic carbon (OC), elemental carbon (EC), char, and soot using the thermal/optical reflectance (TOR) method following the IMPROVE&#95;A protocol. PM 2.5 and PM 10 concentrations ranged from 29.37 to 501.43 μg m -3 and from 50.42 to 330.07 μg m -3 , with average levels of 104.90 and 151.23 μg m -3 , respectively. The 24-h average level of PM 2.5 was about three times the US EPA standard of 35 μg m -3 , and significantly exceeds the Class II National Air Quality Standard of China of 75 μg m -3 . The seasonal cycles of PM mass and OC concentrations were higher during winter than in summer. EC and char concentrations were generally highest during winter but lowest in spring, while higher soot concentrations occurred in summer. This seasonal variation could be attributed to different seasonal meteorological conditions and changes in source contributions. Strong correlations between OC and EC were found for both PM 2.5 and PM 10 in winter and fall, while char and soot showed a moderate correlation in summer and winter. The average OC/EC ratios were 5.11 and 4.46 for PM 2.5 and PM 10 , respectively, with individual OC/EC ratios nearly always exceeding 2.0. Higher char/soot ratios during the four seasons indicated that coal combustion and biomass burning were the major sources for carbonaceous aerosol in Huangshi. Contrary to expectations, secondary organic carbon (SOC) which is estimated using the EC tracer method exhibited spring maximum and summer minimum, suggesting that photochemical activity is not a leading factor in the formation of secondary organic aerosols in the study area. The contribution of SOC to OC concentration for PM 2.5 and PM 10 were 47.33 and 45.38%, respectively, implying that SOC was an important component of OC mass. The serious air pollution in haze-fog episode was strongly correlated with the emissions of pollutants from biomass burning and the meteorological conditions.