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Ammonia, as the only high-concentration alkaline gas in the atmosphere, plays an extremely important role in the initial nucleation process of aerosols. A rise in the concentration of NH3 after sunrise has been observed in many areas, known as the "morning peak phenomenon", which is likely related to the dew evaporation process because of the considerable amount of NH4+ present in dew. To investigate and compare the flux and rate of NH3 release from dew evaporation in downtown (WH) and suburban areas (SL), the dew amount and chemical makeup were measured and analyzed in Changchun, in northeastern China, from April to October 2021. The differences in the fraction of NH4+ released as NH3 gas and the NH3 emission flux and rate during the process of dew evaporation between SL and WH were identified. The results showed that the daily dew amount in WH (0.038 ± 0.017 mm) was lower than that in SL (0.065 ± 0.032 mm) (P < 0.01), and the pH in SL (6.58 ± 0.18) was approximately 1 pH unit higher than that in WH (5.60 ± 0.25). SO42−, NO3−, Ca2+ and NH4+ were the main ions in WH and SL. The ion concentration in WH was significantly higher than that in SL (P < 0.05), which was influenced by human activities and pollution sources. A total of 24%-48% NH4+ was released as NH3 gas during dew evaporation in WH, which was lower than the conversion fraction of SL dew (44%-57%). The evaporation rate of NH3 was 3.9–20.6 ng/m2·s (9.9 ± 5.7 ng/m2·s) in WH and 3.3–15.9 ng/m2·s (8.6 ± 4.2 ng/m2·s) in SL. The dew evaporation process makes an important contribution to the NH3 morning peak phenomenon, but it is not the only contributor. [ABSTRACT FROM AUTHOR]

Dew is a part of the water cycle of ecosystems and is a source of water and humidity. The climate characteristics of the frost-free period in Northeast China are suitable for dew condensation, and dew is an important factor of water balance in this area. Northeast China is among the most significant warming areas in China, with an obvious "warm and dry" climate trend, which may affect dew condensation. To determine the dew amounts in different ecosystems in Northeast China and the influence of climate change on these amounts, dew condensation in farmland (corn), wetland (Carex lasiocarpa) and urban ecosystems (Syringa oblata Lindl.) was monitored during the growing period (May to October) from 2005 to 2021. The results showed that the annual average number of dew days was 132.8 in a wetland in Fujin, 122.9 in a farmland in Lishu and 118.1 in an urban area in Changchun. The daily dew intensity in the three ecosystems was lowest in May and highest in July and August. The average daily dew intensity was higher in the wetland (0.125 ± 0.069 mm) than the farmland (0.061 ± 0.026 mm) and urban area (0.028 ± 0.009 mm). The annual dew amount was also highest in the wetland (44.09 ± 7.51 mm) compared to the farmland (34.46 ± 3.54 mm) and much higher than that in the urban ecosystem (25.32 ± 3.29 mm). The annual dew in the farmland, wetland and urban ecosystems accounted for 7.92 ± 2.76%, 14.98 ± 5.93% and 6.71 ± 2.66% of the rainfall in the same period, respectively. The results indicated that dew was an important source of water and that wetlands had greater dew deposition than farmlands and urban areas. Considering the climate data during the dew condensation period from 1957 to 2021, the annual dew amount showed a decreasing trend of −0.40 mm/10a (p < 0.05) in Changchun. However, under the joint influence of relative humidity (RH) and wind speed (V), the impact of climate change on dew condensation was not obvious. This study further clarified the impact of climate change on the near-surface water cycle. [ABSTRACT FROM AUTHOR]

The dew condensation frequency is high, and the dew amount is heavy in urban ecosystems. During the condensation process, particulate matter acts as a condensation core, playing an important role in purifying the air. At night, dew mainly condenses on plant leaf surfaces, the plant leaves settle the particles in the dew, and some of the particles are resuspended into the atmosphere in the process of dew evaporation after sunrise. This paper monitored the condensation and evaporation processes of dew on four common plants in Changchun city from June to September 2020. By analyzing the mass and size of particles on different leaves after dew condensation and evaporation, the ability of different plants to retain particles in dew was analyzed. The results showed that there was no significant difference in the TSP capture ability during dew condensation between Buxus sinica (Rehd. et Wils.) Cheng subsp. sinica var. parvifolia M. Cheng, Syringa oblata Lindl., Hemiptelea davidii (Hance) Planch., and Pinus tabuliformis Carrière, with a TSP content of 0.21 ± 0.06 μg/cm2. Coarse particulate matter is the main type of deposit in the dew condensation stage. Particulate deposition varied according to species, leaf shape, and microstructure. The proportion of TSP remaining on leaves after dew evaporation from Pinus tabuliformis Carrière, Hemiptelea davidii (Hance) Planch., Buxus sinica (Rehd. et Wils.) Cheng subsp. sinica var. parvifolia M. Cheng, and Syringa oblata Lindl. tree was 89.7 ± 3.9%, 80.6 ± 3.6%, 75.9 ± 4.5%, and 71.4 ± 3.7%, respectively. The ability of the leaves to trap fine particles was significantly higher than that for coarse particles (P < 0.05) after dew evaporation. The highest amount of particle captured by Syringa oblata Lindl. individual was 15.17 g/y during dew condensation, and the amount of remaining particles after dew evaporation was 10.83 g/y. This paper provides a theoretical basis for the selection of tree species for urban greening. [ABSTRACT FROM AUTHOR]

Dew and rain water were collected during 2013 and 2014 in Changchun, China. The dew was analyzed and the following parameters were measured: pH, EC, TDS, major anions (F−, Cl−, SO42-, and NO3-), and major cations (NH4+, Na+, K+, Ca2+, and Mg2+). The mean pH, EC, and TDS values of dew were comparable with the values for rainwater. The pH values of dew and rain were 6.72 and 6.16, respectively. Both EC (308 μS/cm) and TDS (154 mg/L) of dew were higher than those in rain samples. The concentration of main ions in dew was 1.5–5.7 times higher than levels in rainwater. The near-neutral pH values in dew were caused by the neutralization of acidity and buffering by the alkaline elements of soil origin (Ca2+). This neutralization was confirmed by a strong correlation between the acidic ions (SO42- and NO3-) and the major cations (Ca2+ and Mg2+). Natural dust made an important contribution to the ions present in dews, but the presence of sulfate concentrations that are notably higher than rain water (up to 1584.5 μeq/L) indicated a significant contribution of anthropogenic sources. Dew has the ability to capture particulates, and the purifying effect on the underlying surface was obvious. [ABSTRACT FROM AUTHOR]

Plant leaf surface moisture is a frequent meteorological phenomenon that has complicated sources. As such, the determination of whether surface moisture is the input water or only the redistribution of water in the soil–plant–atmosphere ecosystem is of great importance. In this study, δ18O and δD characteristic values of dew, guttation, and soil waters in Buxus sinica var. parvifolia M. Cheng were monitored during the frost-free period (June–September 2017) in Changchun, China, to differentiate the hydraulic relationship among atmospheric vapor, rainwater, soil, dew, and guttation waters and quantitatively distinguish the leaf surface moisture on the canopy and bottom of plants. The water vapor sources of the leaf surface moisture on plants' canopy and bottom were quantitatively verified in accordance with isotope fractionation and mass conservation principles. Results demonstrated that leaf surface moisture, atmospheric vapor, soil water, and dew were closely related. Leaf surface moisture was mainly the condensation of dew. The sources of canopy and bottom leaf surface moisture were basically the same. The proportions of canopy moisture from plant guttation, atmospheric vapor, and soil water were 2.4%–2.5%, 79.8%–92.4%, and 5.1%–17.8%, respectively. By comparison, the proportions of bottom leaf surface moisture were 0.6%–1.4%, 80.0%–93.0%, and 6.4%–18.6%, respectively. Leaf surface moisture is an important water input in urban systems. Moreover, the characteristic values of stable hydrogen and oxygen isotopes of urban dew are supplemented, and the transformation of atmospheric vapor, rainwater, and soil and dew waters is revealed. [ABSTRACT FROM AUTHOR]