1. Temporal trends in “legacy” organochlorine contaminants in blubber of ringed seals (Phoca hispida) from Ulukhaktok, NT, Canada between 1972 and 2010.
- Author
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Addison, R.F., Muir, D.C., Ikonomou, M.G., Harwood, L., Smith, T.G., and Alikamik, J.
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ORGANOCHLORINE pesticides , *MOLECULAR structure , *POLYCHLORINATED biphenyls , *CLIMATE change , *CHLORDAN , *BLUBBER , *RINGED seal - Abstract
Abstract: In blubber of ringed seals (Phoca hispida) from Ulukhaktok, NT, residues of DDT, other organochlorine pesticides, and PCBs declined between 1972 and 2010. The rate of decline varied: concentrations of the DDT-group began to fall after 1981, whereas those of PCBs fell rapidly between 1972 and 1981, and then slowed. Concentrations of cis- and trans-chlordane and of HCB in both sexes, and of cis-nonachlor in males, declined slowly between 1978 and 2010; those of other organochlorine pesticides remained steady. Exponential half-lives of p,p′-DDT and p,p′-DDE in female seals are about 9 and 36y (corresponding to initial declines of 7.8% and 1.9% per year, respectively) and those of PCB congeners from about 20 to 60y (declines of 3.2% to <1.5% per year); the more refractory residues may be detectable for centuries to come. Exploratory PCA of PCB congener distribution identified temporal changes apparently not related to molecular structure. [Copyright &y& Elsevier]
- Published
- 2014
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