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The development of methods for determining volatile and semi-volatile organic compounds in public spaces has become necessary to identify potential health and environmental risks. This study presents a practical methodology for sampling, extracting, detecting, and identifying these compounds in a vehicular traffic region in Belo Horizonte, Brazil. The methodology uses direct-immersion solid phase microextraction (DI-SPME) and static headspace (SHS) to extract SVOCs/VOCs. Comprehensive time-of-flight gas chromatography mass spectrometry (GC×GC/Q-TOFMS) and gas chromatography coupled to mass spectrometry (GC/MS) were used to detect and identify compounds. The analysed samples, collected with a high-volume sampler (Hi-Vol) with quartz filters and in which particulate matter (PM 2.5 ) was retained, showed the presence of more than 200 compounds, both biogenic (natural origin) and anthropogenic (human origin). Regarding the distribution of chemical classes, aromatic compounds were predominantly found at 29.2%, followed by esters at 20.8%, non-aromatic hydrocarbons at 5.6%, and carboxylic acids at 9.4%. Static headspace gas chromatography (HS-GC) enabled the identification and quantification of 21 volatile compounds, including BETX, dichloromethane, chloroform, and naphthalene, which are currently regulated by the US Environmental Protection Agency (EPA)., Competing Interests: Declarations. Ethical approval: Not applicable. Consent to participate: All authors consented to participate in the draughting of this research article. Consent for publication: All authors consented to publish this research article. Competing interests: The authors declare no competing interests., (© 2024. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)

Passive sampling is a sensitive and efficient method for analyzing pesticides in water. This article describes a hollow fiber liquid-phase microextraction (HF-LPME) device that was improved using polypropylene membranes grafted with nanocellulose for the passive sampling of pesticides in water. A comprehensive gas chromatography time-of-flight mass spectrometry (GCxGC/Q-TOFMS) system was used to separate, identify, and quantify pesticides. The sampling rates of 38 moderately hydrophobic to hydrophobic agricultural pesticides (2.18 < log K ow  < 6.89) from different chemical classes, including the main triazine, organochlorine and organophosphate compounds, were calculated. A calibration process was applied to evaluate the role of flow velocity and select potential candidates for a possible performance reference compound (PRC). Sampling rates varied between 0.17 mL d -1 and 23.15 mL d -1 . The accumulation curves identified linear periods ranging from 3 to 18 days. The new passive sampler device was applied for 8 days in rivers and marginal lagoons of natural parks of the São Francisco basin in Minas Gerais, Brazil and identified 10 target pesticides. Furthermore, 10 non-targeted pesticides were detected by the GCxGC/Q-TOFMS method., Competing Interests: Declaration of competing interest The authors have no relevant financial or non-financial interests to disclose., (Copyright © 2023. Published by Elsevier B.V.)

Several endophytic fungi have been reported to have produced bioactive metabolites. Some of them, including the Induratia species, have the capacity to emit volatile compounds with antimicrobial properties with broad spectrum against human and plant pathogens. The present study aimed to prospect the Induratia species producing volatile organic compounds (VOCs), in carqueja plants used in alternative medicine and coffee plants in Brazil. A total of 11 fungal isolates producing volatile metabolites were obtained by a parallel growth technique, using I. alba 620 as a reference strain. Phylogenetic relationships revealed the presence of at least three distinct species, I. coffeana, I. yucatanensis, and Induratia sp. SPME/GC/MS analyses of the VOCs in the headspace above the mycelium from Induratia species cultured for 10 days on PDA revealed the volatile profile emitted by I. coffeana CCF 572, I. coffeana COAD 2055, I. yucatanensis COAD 2062, and Induratia sp. COAD 2059. Volatile organic compounds produced by I. coffeana isolates presented antimicrobial activity against Aspergillus ochraceus, A. sclerotiorum, A. elegans, A. foetidus, A. flavus, A. tamari, A. tubingensis, A. sydowii, A. niger, A. caespitosus, A. versicolor, and A. expansum, sometimes by decreasing the growth rate or, mainly, by fully inhibiting colony growth. Fifty-eight percent of the target species died after 6 days of exposure to VOCs emitted by I. coffeana CCF 572. In addition, VOCs emitted by the same fungus inhibited the growth in A. ochraceus inoculated into coffee beans, which indicates that plants which have I. coffeana as an endophyte may be protected from attacks by this plant pathogen., (© 2023. The Author(s) under exclusive licence to Sociedade Brasileira de Microbiologia.)

A risk assessment and a source apportionment of the particulate- and gas-phase PAHs were conducted in a high vehicular traffic and industrialized region in southeastern Brazil. Higher concentrations of PAHs were found during summer, being likely driven by the contributions of PAHs in the vapor phase caused by fire outbreaks during this period. Isomer ratio diagnostic and Principal Component Analysis (PCA) identified four potential sources in the region, in which the Positive Matrix Factorization (PMF) model confirmed and apportioned as gasoline-related (31.8%), diesel-related (25.1%), biomass burning (23.4%), and mixed sources (19.6%). The overall cancer risk had a tolerable value, with ∑CR = 4.6 × 10 -5 , being ingestion the major via of exposure (64% of the ∑CR), followed by dermal contact (33% of the ∑CR) and inhalation (3%). Mixed sources contributed up to 45% of the overall cancer risk (∑CR), followed by gasoline-related (up to 35%), diesel-related (up to 15%), and biomass burning (up to 10%). The risk assessment for individual PAH species allowed identifying higher CR associated with BaP, DBA, BbF, BaA, and BkF, species associated with gasoline-related and industrial sources. Higher risks were associated with PM 2.5 -bound PAHs exposure, mainly via ingestion and dermal contact, highlighting the need for measures of mitigation and control of PM 2.5 in the region., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

Air quality in large cities has worsened in recent years as a consequence people's health is directly affected. Among the toxic compounds released to environmental air are polycyclic aromatic hydrocarbons (PAHs), nitrated PAHs (nitro-PAHs), and oxygenated PAHs (oxy-PAHs). Performant methods to analyze these compounds is necessary to enable adequate monitoring of air quality. Thus, this manuscript presents the development of a highly sensitive method to analyze PAHs, nitro-PAHs, and oxy-PAHs collected from ambient air (PM 2.5 ) and the gas phase for a period of one year in the urban area of Belo Horizonte, Brazil. PAHs and their derivatives were extracted by cold fiber solid phase microextraction (CF-SPME) and analyzed by gas chromatography coupled to mass spectrometry (GC/MS). The proposed method allows simultaneous analysis of 16 PAHs, nitro-PAHs and oxy-PAHs, presenting very good limits of detection and quantification, as well as appropriate precision and recovery. The results obtained for the period of one year allowed different studies. The compounds collected simultaneously from gas and particulate phase showed that total concentration of 16 PAHs were higher in the gas phase than in the particulate. On the other hand, nitro-PAHs and oxy-PAHs presented similar concentration in gas and particulate phases. The potential carcinogenicity of PAHs relative to benzo[a]pyrene showed benzo[a]pyrene equivalents of 0.49 ng m -3 . The estimated risk of lifetime lung cancer was 5 × 10 -5 . Principal component analysis and diagnostic ratio was applied for source distribution indicating that burning of gasoline, diesel and biomass accounted for the PAHs profile in ambient air samples., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2020 Elsevier Ltd. All rights reserved.)

This paper describes a new, efficient and versatile method for the sampling and preconcentration of PAH in environmental water matrices using special hybrid magnetic carbon nanotubes. These N-doped amphiphilic CNT can be easily dispersed in any aqueous matrix due to the N containing hydrophilic part and at the same time show high efficiency for the adsorption of different PAH contaminants due to the very hydrophobic surface. After adsorption, the CNT can be easily removed from the medium by a simple magnetic separation. GC/MS analyses showed that the CNT method is more efficient than the use of polydimethylsiloxane (PDMS) with much lower solvent consumption, technical simplicity and time, showing good linearity (range 0.18-80.00 μg L(-1)) and determination coefficient (R(2) > 0.9810). The limit of detection ranged from 0.05 to 0.42 μg L(-1) with limit of quantification from 0.18 to 1.40 μg L(-1). Recovery (n=9) ranged from 80.50 ± 10 to 105.40 ± 12%. Intraday precision (RSD, n=9) ranged from 1.91 to 9.01%, whereas inter day precision (RSD, n=9) ranged from 7.02 to 17.94%. The method was applied to the analyses of PAH in four lake water samples collected in Belo Horizonte City, Brazil., (Copyright © 2015 Elsevier B.V. All rights reserved.)

A total of 117 dried fruit samples (black sultanas, white sultanas, dates, dried plums, dried figs and apricots) from different origins were analysed both for toxigenic fungi and for the presence of ochratoxin A. Amongst the fungi found, Aspergillus niger was predominant, with 406 isolates, of which 15% were ochratoxin A producers. They were followed by A. ochraceus, with 15 isolates and 87% ochratoxigenics, and A. carbonarius, with only five isolates of which 60% were ochratoxin A producers. The average infection rates for A. niger in black sultanas, plums, figs, dates and white sultanas were 22.0, 8.0, 4.0, 1.5 and 0.5%, respectively. The apricot samples were not contaminated by any fungi or ochratoxin A. Black sultana and dried figs contained the highest contamination with ochratoxin A, with 33 and 26.3% of the samples containing more than 5 microg kg(-1) respectively, while all the white sultanas, dates and plums had no sample that exceeded this limit.