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Shipyard activities have contributed to the release of anthropogenic metals in sediment in the Amazon delta estuary, but no studies of the issue have been carried out in northern Brazil. This study evaluated the sediment that is under the influence of shipyard activities in the Guajará Bay and in the channel of the Maguari River, in Belém, Pará (PA) state, northern Brazil. Sediment samples were collected in the vicinity of the shipyards, while samples of paint and metal fragments were collected from hulls of abandoned vessels. Metals under analysis were Cu, Zn, Pb, Ni, Cr, Ba, V, Li, Fe and Al. Mean Cu concentrations found in the sediment in two shipyards — 28.3 mg kg−1 and 41.0 mg kg−1 — were above the threshold effect level (TEL) for the amphipod Hyalella azteca. The highest concentrations of metals found in paint fragments from abandoned vessels were 29,588 mg kg−1 Ba, 9,350 mg kg−1 Zn, 1,097 mg kg−1 Pb and 548 mg kg−1 Cr. This fact suggests that vessel abandonment is a major source of contamination in shipyard areas. The principal component analysis (PCA) showed that most metals under study are closely related to sediment contamination in the shipyards. Geoaccumulation index and screening concentrations of inorganic contaminants for metals in freshwater ecosystems confirmed that a shipyard was contaminated by copper. Results may support further studies of contamination and application of waste management to shipyards and vessel graveyards around the world. [ABSTRACT FROM AUTHOR]

Marinas are central hubs of global maritime leisure and transport, yet their operations can deteriorate the environmental quality of sediments. In response, this study investigated the metal contamination history associated with antifouling paint uses in a sediment core collected from Bracuhy marina (Southeast Brazil). Analysis target major and trace elements (Cu, Zn, Pb, Cd and Sn), rare earth elements (REEs), and Pb isotopes. The modification in Pb isotopic ratios and REEs pattern unequivocally revealed sediment provenance disruption following the marina construction. Metal distribution in the sediment core demonstrates that concentrations of Cu and Zn increased by up to 15 and 5 times, respectively, compared to the local background. This severe Cu and Zn contamination coincides with the onset of marina operations and can be attributed to the use of antifouling paints., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024. Published by Elsevier Ltd.)

This review summarized booster biocides studies from Latin America and the Caribbean during the last two decades. Studies were focused on six countries, with most of them in Brazil. In water and sediment, diuron and Irgarol were the most abundant and frequent biocides, probably due to their former intense use. Antifouling paint particles were also reported and had mainly DCOIT, which is currently the most used booster biocide. Toxicity of individual booster biocides was tested in laboratory, and most effects were related to chlorothalonil, DCOIT, dichlofluanid, and Irgarol, including, but not limited to DNA damage, fertility decrease, and mortality at different trophic levels. This review highlighted the need for further studies on environmental occurrence of booster biocides in Latin America and Caribbean associated to ecotoxicological studies. Such information is essential to determine the potential ecological risks and to create directives regarding safe limits of booster biocides in aquatic systems. [Display omitted] • Irgarol and diuron were the most detected biocides in water and sediments. • DCOIT is the most frequent and most abundant biocide in APP samples. • Further environmental and ecotoxicological studies should be performed. • Toxicity was assessed for different organisms under laboratory conditions. • An improvement for booster biocides analysis in biological matrices is urgent. [ABSTRACT FROM AUTHOR]