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Pharmaceuticals and personal care products (PPCPs) in reclaimed water can enter into soil, groundwater, and air during the irrigation of urban green spaces, leading to potential risks due to their negative effects of feminization, on root elongation, and as carcinogens. In this study, a validated HYDRUS-1D model by field experiments and an exposure model were used to simulate the distributions of 67 PPCPs detected in the effluent from municipal wastewater treatment plants of Beijing under two scenarios (1, uniform irrigation concentrations; 2, detected irrigation concentrations) in soil, groundwater, and air. To determine the priority ranks of the 67 PPCPs, the effect values of the PPCPs in soil, groundwater, and air were calculated on the basis of distributions and toxicity data, and then weighted and scored. Under scenario 1, roxithromycin, medroxyprogesterone acetate, and megestrol acetate, characterized by high adsorption and low volatilization and degradation, had the highest accumulations in soil, and ofloxacin, characterized by the lowest degradation and adsorption, had the highest leaching to groundwater. The highest volatilization was observed for galaxolide abbalide, tonalid, and dioctyl phthalate. Under scenario 2, based on their overall scores and priority ranks, the 67 PPCPs were divided into three groups: I, high priority; II, moderate priority; III, low priority. Of the 67 PPCPs, 17 were classified in group I, with the highest priority rankings for ofloxacin, 17α-ethynylestradiol, dibutyl phthalate, dioctyl phthalate, and sulfamethoxazole. In group III (total 33 PPCPs), 28 of the PPCPs were not of urgent concern under reclaimed water irrigation in Beijing., (Copyright © 2019. Published by Elsevier B.V.)