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Verification of beef production systems and authentication of origin is becoming increasingly important as consumers base purchase decisions on a greater number of perceived values including the healthiness and environmental impact of products. Previously Raman spectroscopy has been explored as a tool to classify carcases from grass and grain fed cattle. Thus, the aim of the current study was to validate Partial Least Squares Discriminant Analysis (PLS-DA) models created using independent samples from carcases sampled from northern and southern Australian production systems in 2019, 2020 and 2021. Validation of the robustness of discrimination models was undertaken using spectral measures of fat from 585 carcases which were measured in 2022 using a Raman handheld device with a sample excised for fatty acid analysis. PLS-DA models were constructed and then employed to classify samples as either grass or grain fed in a two-class model. Overall, predictions were high with accuracies of up to 95.7% however, variation in the predictive ability was noted with models created for southern cattle yielding an accuracy of 73.2%. While some variation in fatty acids and therefore models can be attributed to differences in genetics, management and diet, the impact of duration of feeding is currently unknown and thus further work is warranted., Competing Interests: Declaration of competing interest Funding was achieved by Stephanie Fowler with the assistance of David Hopkins. Stephanie Fowler designed the experiment, complied the first draft, was responsible for project administrated and collected the data along with Matthew Kerr. Data was analysed by Leigh Schmidtke. Edits were made by all authors and the final manuscript was prepared by Stephanie Fowler. The authors declare no conflict of interest., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

The use of spectral data is seen as a fast and non-destructive method capable of monitoring pasture biomass. Although there is great potential in this technique, both end users and sensor manufacturers are uncertain about the necessary sensor specifications and achievable accuracies in an operational scenario. This study presents a straightforward parametric method able to accurately retrieve the hyperspectral signature of perennial ryegrass ( Lolium perenne ) canopies from multispectral data collected within a two-year period in Australia and the Netherlands. The retrieved hyperspectral data were employed to generate optimal indices and continuum-removed spectral features available in the scientific literature. For performance comparison, both these simulated features and a set of currently employed vegetation indices, derived from the original band values, were used as inputs in a random forest algorithm and accuracies of both methods were compared. Our results have shown that both sets of features present similar accuracies (root mean square error (RMSE) ≈490 and 620 kg DM/ha) when assessed in cross-validation and spatial cross-validation, respectively. These results suggest that for pasture biomass retrieval solely from top-of-canopy reflectance (ranging from 550 to 790 nm), better performing methods do not rely on the use of hyperspectral or, yet, in a larger number of bands than those already available in current sensors.

Cheese is a nutritious dairy product and a valuable commodity. Internationally, cheddar cheese is produced and consumed in large quantities, and it is the main cheese variety that is exported from Australia. Despite its importance, the analytical methods to that are used to determine cheese quality rely on traditional approaches that require time, are invasive, and which involve potentially hazardous chemicals. In contrast, spectroscopic techniques can rapidly provide molecular information and are non-destructive, fast, and chemical-free methods. Combined with partner recognition methods (chemometrics), they can identify small changes in the composition or condition of cheeses. In this work, we combined FTIR and Raman spectroscopies with principal component analysis (PCA) to investigate the effects of aging in commercial cheddar cheeses. Changes in the amide I and II bands were the main spectral characteristics responsible for classifying commercial cheddar cheeses based on the ripening time and manufacturer using FTIR, and bands from lipids, including β'-polymorph of fat crystals, were more clearly determined through changes in the Raman spectra.

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A comparison of the analysis of respirable crystalline silica direct-on-filter methods using X-ray diffraction (XRD) and Fourier transform infrared (FT-IR) spectroscopy was undertaken using 253 real workplace air samples from road construction and tunnelling, coal mining, and kitchen benchtop manufacturing in Australia. Using pure α-quartz standards, XRD and FT-IR direct-on-filter analyses produced identical test results, however, the real workplace samples showed a clear discrepancy between FT-IR and XRD results with on average a 9% positive bias of the FT-IR results. The cause of the positive bias was due to matrix interferences which was confirmed by using synthetic mixture air samples. Approximately a third of the data by direct-on-filter method using FT-IR was assessed to be invalid based on the peak height ratio criterion due to excessive interferences and weight overload limitations. The XRD method showed better results due to less interference from the common matrices. XRD could handle up to twice the sample loading and at higher loadings up to 7 mg when a correction was applied. It was also able to achieve a lower limit of detection of 2 µg filter−1 when a slower scan condition was utilized. [ABSTRACT FROM AUTHOR]

The Zyvox® Annual Appraisal of Potency and Spectrum (ZAAPS) Program monitors the in vitro activities of linezolid and comparator agents for Gram-positive organisms in Latin America, Europe, Canada, and the Asia-Pacific. For the 2010 Program a total of 6305 Gram-positive strains were collected from 75 medical centres on five continents (24 countries). Reference broth microdilution susceptibility tests were performed on organisms from the following groups: Staphylococcus aureus (2875), coagulase negative staphylococci (CoNS) (855), enterococci (787), Streptococcus pneumoniae (926), viridans group and other streptococci (325), and beta-haemolytic streptococci (507). Linezolid demonstrated a 99.81% susceptibility rate among 6305 strains tested from 24 nations. Of the resistant isolates, four linezolid-resistant strains of enterococci (two each for Enterococcus faecalis and Enterococcus faecium) were found in four nations (China, Thailand, Germany, and Brazil). Eight CoNS (Staphylococcus epidermidis, Staphylococcus hominis) isolates were observed to be resistant to linezolid (MIC, ≥8 μg/ml). Two strains from Mexico were determined to be from an ongoing epidemic, and investigations showed that isolates from Italy and Brazil were also from circulating resistant clones discovered in earlier years. MRSA rates varied by region and between nations, as did resistances to other potential therapeutic agent options frequently listed for MRSA therapy such as clindamycin, fluoroquinolones and trimethoprim/sulfamethoxazole. In summary, the 2010 ZAAPS Program demonstrated that linezolid activity remains stable around the world with >99% susceptibility.

A total of 960 beef carcases from northern and southern Australian production regions were assessed by examining the subcutaneous fat. Carcases from four different production systems within each region were assessed, by Raman spectroscopy and the fatty acid composition determined to develop models that best classified the various production systems. As a result, 12 Partial Least Square Discriminant Analysis models were developed. A two-class model based on fatty acid composition was able to correctly classify 99% of grass and grain fed animals. The best Raman spectroscopic model correctly classified 94% of grass vs grain carcases produced in the northern region. For the southern production region, the models had the following classification accuracies; southern long-term grain fed (98%), southern short-term grain fed (95%), southern grass (96%), southern grass supplemented (97%), and the southern model classified grass vs grain (97%). Raman spectroscopy is considered a useful rapid method for classification of beef carcases based upon production system., (Copyright © 2022. Published by Elsevier Ltd.)

In order to mimic the chemical reactions in cave systems, the analogue of the mineral stercorite H(NH(4))Na(PO(4))·4H(2)O has been synthesised. X-ray diffraction of the stercorite analogue matches the stercorite reference pattern. A comparison is made with the vibrational spectra of synthetic stercorite analogue and the natural Cave mineral. The mineral in nature is formed by the reaction of bat guano chemicals on calcite substrates. A single Raman band at 920 cm(-1) (Cave) and 922 cm(-1) (synthesised) defines the presence of hydrogen phosphate in the mineral. In the synthetic stercorite analogue, additional bands are observed and are attributed to the dihydrogen and phosphate anions. The vibrational spectra of synthetic stercorite only partly match that of the natural stercorite. It is suggested that natural stercorite is more pure than that of synthesised stercorite. Antisymmetric stretching bands are observed in the infrared spectrum at 1052, 1097, 1135 and 1173 cm(-1). Raman spectroscopy shows the stercorite mineral is based upon the hydrogen phosphate anion and not the phosphate anion. Raman and infrared bands are found and assigned to PO(4)(3-), H(2)O, OH and NH stretching vibrations. Raman spectroscopy shows the synthetic analogue is similar to the natural mineral. A mechanism for the formation of stercorite is provided., (Copyright © 2011 Elsevier B.V. All rights reserved.)

This article deals with the potential of Fourier transform (FT) Raman spectroscopy in discrimination of botanical species of green and roasted coffees. There are two species of commercial importance: Coffea arabica (arabica) and Coffea canephora (robusta). It is recognized that they differ in their lipid fraction, especially in the content of the diterpene kahweol, which is present at 0.1-0.3% dry matter basis in arabica beans and only in traces (<0.01%) in robusta. The visual examination of the Raman spectra of the lipid fraction extracted from arabica, robusta and liberica samples shows differences in the mid-wavenumbers region: arabica spectra have two characteristic scattering bands at 1567 and 1478 cm(-1). The spectrum of the pure kahweol shows the same bands. Principal component analysis is applied to the spectra and reveals clustering according to the coffee species. The first principal component (PC1) explains 93% of the spectral variation and corresponds to the kahweol concentration. Using the PC1 score plot, two groups of arabica can be distinguished as follows: one group with high kahweol content and another group with low kahweol content. The first group includes samples coming from Kenya and Jamaica; the second group includes samples from Australia. The main difference between these coffees is that those from Kenya and Jamaica are well-known for growing at a high altitude whereas those ones from Australia are grown at a low altitude. To our knowledge, the application of Raman spectroscopy has never been used in coffee analysis.

Calcium (Ca) and magnesium (Mg) are essential for growth of sugarcane leaves and roots, as well as respiration and nitrogen metabolism, respectively. To assist farmers decide suitable application rates of lime and Mg fertiliser, respectively, the Australian sugarcane industry established the Six-Easy-Steps nutrient management guidelines based on topsoil (0-0.3 m) Ca (cmol(+) kg -1 ) and Mg (cmol(+) kg -1 ). Given the heterogeneous nature of soil, digital soil mapping (DSM) methods can be employed to allow for the precise application rate to be determined. In this study, we examine statistical models (i.e., ordinary kriging [OK], linear mixed model [LMM], quantile regression forests [QRF], support vector machine [SVM], and Cubist regression kriging [CubistRK]) to predict topsoil and subsoil (0.6-0.9) Ca and Mg, employing digital data in combination (i.e., proximal sensing electromagnetic induction (EMI) [e.g., 1mPcon, 1mHcon, etc.], gamma-ray [γ-ray] spectrometry [i.e., TC, K, U and Th] and digital elevation model [DEM] derivatives). We also investigate various sampling designs (i.e., spatial coverage [SCS], feature space coverage [FSCS], conditioned Latin hypercube [cLHS] and simple random sampling [SRS]) and calibration sample size (i.e., n = 180, 150, 120, 90, 60 and 30). The predictions are assessed using Lin's concordance correlation coefficient (LCCC) and ratio of performance to interquartile distance (RPIQ) with an independent validation dataset (i.e., n = 40). The best results were for prediction of subsoil Mg, utilising CubistRK (LCCC = 0.82) with the largest calibration sample size (n = 180), followed by LMM (0.79), SVM (0.76), QRF (0.70) and OK (0.65). This was generally the case for topsoil and subsoil Ca. We also conclude that no single sampling design was universally better, and 180 samples were necessary for predicting topsoil Ca and Mg with moderate agreement (0.65 < LCCC < 0.80). However, with FSCS, a minimum of 120 samples were enough to calibrate a CubistRK model and achieve substantial (LCCC > 0.80) agreement for predicting subsoil Ca and Mg. With respect to soil use and management according to the Six-Easy-Steps, the sandy soil in the north and south require large application rate of lime (3.5 t/ha) and Mg (125 kg/ha), respectively. Conversely, varying amounts of fertiliser rates of lime (2.0, 1.5 and 1 t/ha) and Mg (50 kg/ha) were recommended where Vertosols were previously mapped., (Copyright © 2021 Elsevier Ltd. All rights reserved.)

The levels of trace elements in whole blood and plasma have been widely used for assessing nutritional status and monitoring exposure and can vary widely in populations from different geographical regions. In this study, whole blood samples ( n = 120) and plasma samples ( n = 120) were obtained from healthy donors attending the Red Cross Blood Bank (Queensland Red Cross Blood Service), which provided information for age and sex. There were 71 males (age range: 19-73 years) and 49 females (age range: 18-72 years) for whole blood samples, and 59 males (age range: 19-81 years) and 61 females (age range: 19-73 years) for plasma samples. The main aim of the study was to provide information on blood reference levels of 21 trace elements (Ag, Al, As, Bi, Br, Cd, Co, Cr, Cu, Hg, I, Mn, Mo, Ni, Pb, Sb, Se, Tl, U, V, Zn) in Queensland. The study also aimed to assess differences in trace element blood levels between males and females and the effect of age. The trace element levels in blood samples were analysed using inductively coupled plasma mass spectrometry (ICP-MS) and the standard reference materials of Seronorm (Trace Elements Whole Blood) and UTAK (Trace Elements Serum) were used for quality control and assurance. The study found wide variations of trace element levels in whole blood and plasma, and generally the levels were comparable to other countries. No detectable levels were found for Bi, Cr, U and V in whole blood, but V levels were found in plasma samples. There were significant differences between males and females for whole blood Cu ( p < 0.001), I ( p = 0.009), Tl ( p = 0.016) and Zn ( p = 0.016). Significant differences were also found for plasma Cu ( p < 0.001) and Se ( p = 0.003) between males and females. There were trends of increased levels of blood Pb, Se and Zn with age. The study has provided further information on a wide range of trace elements in blood as reference levels for Queensland and Australia which are currently lacking.

An extract from the bryozoan Amathia lamourouxi with antiplasmodial activity was identified through high-throughput screening of an Australian marine invertebrate extract library against Plasmodium falciparum . Chemical investigation of A. lamourouxi resulted in the isolation of six new brominated alkaloids, convolutamines K and L ( 1 and 2 ), volutamides F-H ( 3 - 5 ), and 2,5-dibromo-1-methyl-1 H -indole-3-carbaldehyde ( 6 ). Three of the compounds ( 2 - 4 ) displayed moderate to potent antiplasmodial activity against both the chloroquine-sensitive (3D7) and chloroquine-resistant (Dd2) parasite strains of Plasmodium falciparum with an IC 50 range of 0.57-1.7 μM and a high selectivity index against a human cell line (HEK293).

Australian grass and grain-fed beef products attract premium prices at sale and several beef processors market beef underwritten by production system claims. This preliminary investigation assessed the feasibility of using Raman spectroscopy to detect differences in the chemical composition of subcutaneous fat from cattle raised in extensive and intensive production systems. Raman spectra, fatty acid composition, β-carotene composition and objective colour measurements were measured on 150 grass and 150 grain-fed cattle. Spectral differences at peaks including 1069 cm -1 , 1127 cm -1 , 1301 cm -1 and 1445 cm -1 suggest that Raman spectra is able to detect differences in saturated fatty acids, which were significantly higher in carcases from grain-fed cattle. Differences in spectra at 1658 cm -1 were observed, however further research is required to investigate the cause of this spectral feature. Overall, this study indicated that Raman spectroscopy is a potential tool for the authentication of beef carcases from grass and grain-fed production systems., (Copyright © 2019 Elsevier Ltd. All rights reserved.)

Baeckea frutescens is a medicinal plant distributing from Southeast Asia to Australia. A pair of novel diastereomeric C -methylated triflavonoids named baeckeins L ( 1 ) and M ( 2 ) were isolated from the roots of B. frutescens . The structures of these isolates were elucidated by analysis of the 1D ( 1 H/ 13 C) and 2D NMR (HSQC/HMBC/NOESY) and HR-ESI-MS spectroscopic data, and the absolute configurations of chiral carbons (C-2/C-3/C-2°/C-3°) were established by CD spectrometry combined with quantum chemical calculations.

Purpose of the Study: The aim of the work is a spectroscopic investigation and comparison of the molecular composition of dentine and gingival fluids as well as of their diagnostic potential for the preventive screening of dentin caries., Material and Methods: Applying infrared spectroscopy including synchrotron radiation the samples of biological fluids taken from the oral cavity (dentine fluid, fluid from the gingival sulcus and blood) were studied for the patients with the progressive dentine caries. The part of this research was undertaken with the infrared microspectroscopy beamline at the Australian Synchrotron., Results: Dentine and gingival fluids were shown to have no less complicated composition than the blood serum. Having all this in mind, in spite that these two fluids are derivatives of the blood serum, and a majority of the molecular groups observed in all of the three fluids can be detected in their IR-spectra, it follows that there is a number of signature modes that are in fact present in the IR spectra of only dentine and gingival fluids. This fact indicates at the molecular exchange between them under certain conditions. It means the high diagnostic potential in the study of the pathologic processes occurring in the oral fluid of a human. We have observed and fixed an increase of thiocyanates and esters in the samples of both dentine and gingival fluids under the development of dentin caries., Conclusion: Utilization of the gingival fluid for screening taking into account that its sampling is not such a complicated challenge as dentine fluid sampling will promote a transition to the personalized medicine, the development of high-technology healthcare and technology of the health preservation as a whole.

We investigated the prevalence of extended-spectrum β-lactamase (ESBL)-producing Escherichia coli in untreated hospital wastewaters and 2 sewage treatment plants (STPs). A collection of 252 ESBL-producing E. coli isolates from hospital wastewater and STPs were typed and tested for resistance to 17 antimicrobial agents and for the presence of integron-associated integrases ( intI gene) and ESBL genes. Eighty-nine percent ( n = 176) of the ESBL-producing E. coli strains from hospital wastewater were found in more than 1 sample (common types), with 1 common type accounting for 35% of isolates, found in all samples. These strains were also resistant to up to 9 non-β-lactam antibiotics and showed the same pattern of resistance in all samples. More than 73% of the hospital wastewater isolates possessed SHV-type ESBL as opposed to isolates from STPs that carried only CTX-M-type ESBL genes. The prevalence of the intI gene did not differ between the sources of the isolates. Certain ESBL-producing E. coli were dominant in hospital wastewaters. These strains possessed β-lactamase genes that were different from isolates found in STPs. From a public health point of view, the presence of such a high level of ESBL-producing E. coli strains in hospital wastewaters is of great importance. [ABSTRACT FROM AUTHOR]

Aims: To determine the antibacterial spectrum and cytotoxic activities of serrulatane compounds from the Australian plant Eremophila neglecta. Methods and Results: Antimicrobial activities of serrulatane compounds 8,19-dihydroxyserrulat-14-ene ( 1) and 8-hydroxyserrulat-14-en-19-oic acid ( 2) were tested against Gram-negative and Gram-positive bacteria including human and veterinary pathogens and some multidrug-resistant isolates. Minimum inhibitory concentrations (MICs) and minimum bactericidal concentrations (MBCs) of the compounds were determined by broth microdilution assay. Both compounds exhibited antibacterial activity against all Gram-positive test strains. They showed antimycobacterial activity against isolates of Mycobacterium fortuitum and Mycobacterium chelonae. Of the five Gram-negative bacteria tested, only Moraxella catarrhalis showed susceptibility to the compounds. Cytotoxic activities were tested in the Vero cell line. Compound 1 showed more activity than 2 in both antibacterial and cytotoxicity assays with cytotoxicity at concentrations similar to the MBC. Conclusions: Serrulatane compounds showed significant activity against medically important bacteria, with 1 exhibiting stronger antibacterial activity. However, they also displayed toxicity to mammalian cells. Significance and Impact of the Study: Serrulatanes are of interest as novel antibacterial compounds for use in biomedical applications; this study reports data obtained with a range of bacterial strains and mammalian cells, essential for assessing the capabilities and limitations of potential applicability of these compounds. [ABSTRACT FROM AUTHOR]

Abstract: The Clustering LARge Applications (CLARA) statistical sampling and clustering algorithm is used to classify sea wave spectra into groups with different spectral properties. The actual spectrum is used in the classification, not proxy sets of spectral parameters. The clustering needs no a priori information on spectral properties, statistical distributions, or number of modes in the spectra. Cluster membership can be viewed as being essentially determined by the geometrical or shape properties of spectra, and is uninfluenced by the numerical dominance of particular shapes if a sufficient number of clusters is requested. The CLARA algorithm also enables outlier detection. CLARA provides a spectrum from each grouping or cluster as a central tendency measure or medoid. This allows a collection of spectra to be reduced to a set of basis or representative spectra according to the different spectral shapes present. However, other statistical measures constructed from the clusters form more suitable basis spectra than medoids. The methods are illustrated with a one-year long waverider data set from a shallow water coastal site off northwest Australia. The site experiences spectral peaks in three frequency bands, seasonally changing conditions, and daily sea breezes. [ABSTRACT FROM AUTHOR]

Gigahertz-peaked spectrum (GPS) radio sources are thought to be young objects which later evolve into Fanaro–Riley type I (FR I) and FR II radio galaxies. We have used the Australia Telescope 20 GHz (AT20G) survey catalogue to select a uniform sample of GPS sources with spectral peaks above 5 GHz, which should represent the youngest members of this class. In this paper, we present e-VLBI observations of 10 such objects which are associated with nearby galaxies and so represent a new population of local, low-power GPS sources. Our e-VLBI observations were carried out at 4.8 GHz with the Australia Telescope Long Baseline Array (LBA) using a real-time software correlator. All 10 sources were detected, and were unresolved on scales of ∼100 mas, implying that they are typically less than 100 pc in linear size. [ABSTRACT FROM AUTHOR]

We present 11 spectra from 12 candidate radio sources co-identified with known planetary nebulae (PNe) in the Large Magellanic Cloud (LMC). Originally found in Australia Telescope Compact Array (ATCA) LMC surveys at 1.4, 4.8 and 8.64 GHz and confirmed by new high resolution ATCA images at 6 and 3 cm (400/200), these complement data recently presented for candidate radio PNe in the Small Magellanic Cloud (SMC). Their spectra were obtained using the Radclifie 1.9-meter telescope in Sutherland (South Africa). All of the optical PNe and radio candidates are within 200 and may represent a population of selected radio bright sample only. Nebular ionized masses of these objects are estimated to be as high as 1.8 Mʘ, supporting the idea that massive PNe progenitor central stars lose much of their mass in the asymptotic giant branch (AGB) phase or prior. We also identify a sub-political. [ABSTRACT FROM AUTHOR]

Abstract: This paper compares predictions of soil organic carbon (SOC) using visible and near infrared reflectance (vis–NIR) hyperspectral proximal and remote sensing data. Soil samples were collected in the Narrabri region, dominated by Vertisols, in north western New South Wales (NSW), Australia. Vis–NIR spectra were collected over this region proximally with an AgriSpec portable spectrometer (350–2500 nm) and remotely from the Hyperion hyperspectral sensor onboard satellite (400–2500 nm). SOC contents were predicted by partial least-squares regression (PLSR) using both the proximal and remote sensing spectra. The spectral resolution of the proximal and remote sensing data did not affect prediction accuracy. However, predictions of SOC using the Hyperion spectra were less accurate than those of the Agrispec data resampled to similar resolution as the Hyperion spectra. Finally, the SOC map predicted using Hyperion data shows similarity with field observations. There is potential for the use of hyperspectral remote sensing for predictions of soil organic carbon. The use of these techniques will facilitate the implementation of digital soil mapping. [Copyright &y& Elsevier]

We have used the Australia Telescope Compact Array (ATCA) at 95 GHz to carry out continuum observations of 130 extragalactic radio sources selected from the Australia Telescope 20 GHz (AT20G) survey. We use a triple-correlation method to measure simultaneous 20- and 95-GHz flux densities for these objects, and over 90 per cent of our target sources are detected at 95 GHz. We demonstrate that the ATCA can robustly measure 95-GHz flux densities with an accuracy of ∼10 per cent in a few minutes for sources stronger than about 50 mJy. We measure the distribution of radio spectral indices in a flux-limited sample of extragalactic sources, and show that the median 20–95 GHz spectral index does not vary significantly with flux density for . This finding allows us to estimate the extragalactic radio source counts at 95 GHz by combining our observed 20–95 GHz spectral-index distribution with the accurate 20-GHz source counts measured in the AT20G survey. Our derived 95-GHz source counts at flux densities above 80 mJy are significantly lower than those found by several previous studies. The main reason is that most radio sources with flat or rising spectra in the frequency range 5–20 GHz show a spectral turnover between 20 and 95 GHz. As a result, there are fewer 95-GHz sources (by almost a factor of 2 at 0.1 Jy) than would be predicted on the basis of extrapolation from the source populations seen in lower-frequency surveys. We also derive the predicted confusion noise in cosmic microwave background surveys at 95 GHz and find a value 20–30 per cent lower than previous estimates. The 95-GHz source population at the flux levels probed by this study is dominated by quasi-stellar objects with a median redshift . We find a correlation between optical magnitude and 95-GHz flux density which suggests that many of the brightest 95-GHz sources may be relativistically beamed, with both the optical and millimetre continuum significantly brightened by Doppler boosting. [ABSTRACT FROM AUTHOR]

The Australia Telescope 20-GHz (AT20G) Survey is a blind survey of the whole southern sky at 20 GHz (with follow-up observations at 4.8 and 8.6 GHz) carried out with the Australia Telescope Compact Array from 2004 to 2007. The Bright Source Sample (BSS) is a complete flux-limited subsample of the AT20G Survey catalogue comprising 320 extragalactic ) radio sources south of with Jy. Of these, 218 have near simultaneous observations at 8 and 5 GHz. In this paper we present an analysis of radio spectral properties in total intensity and polarization, size, optical identifications and redshift distribution of the BSS sources. The analysis of the spectral behaviour shows spectral curvature in most sources with spectral steepening that increases at higher frequencies (the median spectral index α, assuming , decreases from between 4.8 and 8.6 GHz to between 8.6 and 20 GHz), even if the sample is dominated by flat spectra sources (85 per cent of the sample has . The almost simultaneous spectra in total intensity and polarization allowed us a comparison of the polarized and total intensity spectra: polarized fraction slightly increases with frequency, but the shapes of the spectra have little correlation. Optical identifications provided an estimation of redshift for 186 sources with a median value of 1.20 and 0.13, respectively, for QSO and galaxies. [ABSTRACT FROM AUTHOR]

We present results of polarization observations at 1.4 GHz of the two fields imaged by the DASI experiment ( and , respectively). Data were taken with the Australia Telescope Compact Array with 3.4-arcmin resolution and ∼0.18-mJy beam−1 sensitivity. The emission is dominated by point sources, and we do not find evidence for diffuse synchrotron radiation even after source subtraction. This allows to estimate an upper limit of the diffuse polarized emission. The extrapolation to 30 GHz suggests that the synchrotron radiation is lower than the polarized signal measured by the DASI experiment by at least two orders of magnitude. This further supports the conclusions drawn by the DASI team itself about the negligible Galactic foreground contamination in their data set, improving by a factor of ∼5 the upper limit estimated by Leitch et al. The dominant point-source emission allows us to estimate the contamination of the cosmic microwave background (CMB) by extragalactic foregrounds. We computed the power spectrum of their contribution, and its extrapolation to 30 GHz provides a framework where the CMB signal should dominate. However, our results do not match the conclusions of the DASI team about the negligibility of point-source contamination, suggesting taking into account a source subtraction from the DASI data. [ABSTRACT FROM AUTHOR]

Previous studies have found that rates of suicide have a distinct annual rhythm with a peak in spring. Two recent European studies, however, have found that the amplitude of this rhythm has decreased over time. The purpose of this study was to examine whether such effects are found in Australia. Australian Bureau of Statistics data on all suicides in Australia 1970–1999 were analysed by spectral analysis. We found that suicide, violent suicide and suicide by males are seasonal and that the seasonal amplitude has increased over time. Males who use violent methods determine the seasonal effect. These results support previous findings that suicide and particularly violent suicide have a characteristic seasonal rhythm. However, the progressive increase in the amplitude of this rhythm over time in Australia is in direct contrast to other European findings. We suggest that this may be related to differences in patterns of anti-depressant use and also the effect of migration on the number of seasonally vulnerable individuals in Australia. [Copyright &y& Elsevier]

Variations of water properties in surface and intermediate layers along 32°S in the southern Indian Ocean were examined using a 50-year (1960-2010) time series reproduced from historical hydrographic and Argo data by using optimum interpolation. Salinity in the 26.7-27.3σ density layer decreased significantly over the whole section, at a maximum rate of 0.02 decade at 26.8-26.9σ, for the 50-year average. Three deoxygenating cores were identified east of 75°E, and the increasing rate of apparent oxygen utilization in the most prominent core (26.9-27.0σ) exceeded 0.05 ml l decade. The pycnostad core of Subantarctic Mode Water (SAMW) and the salinity minimum of Antarctic Intermediate Water shifted slightly toward the lighter layers. Comparisons with trans-Indian Ocean survey data from 1936 suggest that the tendencies found in the time series began before 1960. Interestingly, cores of many prominent trends were located just offshore of Australia at 26.7-27.0σ, which is in the SAMW density range. Spectrum analysis revealed that two oscillation components with time scales of about 40 and 10 years were dominant in the subsurface layers. Our results are fairly consistent with, and thus support, the oceanic responses in the southern Indian Ocean to anthropogenic climate change predicted by model studies. [ABSTRACT FROM AUTHOR]

Time variations of lightning activity in the three main tropical thunderstorm centers located in the Maritime Continent (Pakistan, India, Southeast Asia, Indonesia, and Australia), Africa, and the Americas are analyzed using a lightning activity index IRS, which is calculated from the resonances of magnetic field in the extremely low frequency range—the Schumann resonances—which were observed at Hylaty station (Poland) in the time interval July 2005–May 2006. Power spectrum analysis of the IRS series is carried out for this time interval. The annual and semiannual variations are shown in all of the series together with the following characteristic periodicities: 45 (Madden–Julian oscillation), 17.6, 13.5, and 4.8 days, seen mainly in the series describing the lightning activity of the Maritime Continent. In addition, maps of the dynamical power spectrum are constructed. They present variability both in the values of characteristic periods 26–30, 17–22, 12–14, 9–10, and 5–7 days and in their duration. During the studied time interval, according to these indices, the African center was the most active, whereas the American and Maritime Continent centers showed a similar level of activity. The largest differences among the centers were observed in the summer months in the Northern Hemisphere. [ABSTRACT FROM AUTHOR]

Opaline silica deposits on Mars may be good target sites where organic biosignatures could be preserved. Potential analogues on Earth are provided by ancient cherts containing carbonaceous material (CM) permineralized by silica. In this study, we investigated the ultrastructure and chemical characteristics of CM in the Rhynie chert (c. 410 Ma, UK), Bitter Springs Formation (c. 820 Ma, Australia), and Wumishan Formation (c. 1485 Ma, China). Raman spectroscopy indicates that the CM has experienced advanced diagenesis or low-grade metamorphism at peak metamorphic temperatures of 150-350°C. Raman mapping and micro-Fourier transform infrared (micro-FTIR) spectroscopy were used to document subcellular-scale variation in the CM of fossilized plants, fungi, prokaryotes, and carbonaceous stromatolites. In the Rhynie chert, ultrastructural variation in the CM was found within individual fossils, while in coccoidal and filamentous microfossils of the Bitter Springs and formless CM of the Wumishan stromatolites ultrastructural variation was found between, not within, different microfossils. This heterogeneity cannot be explained by secondary geological processes but supports diverse carbonaceous precursors that experienced differential graphitization. Micro-FTIR analysis found that CM with lower structural order contains more straight carbon chains (has a lower R3/2 branching index) and that the structural order of eukaryotic CM is more heterogeneous than prokaryotic CM. This study demonstrates how Raman spectroscopy combined with micro-FTIR can be used to investigate the origin and preservation of silica-permineralized organics. This approach has good capability for furthering our understanding of CM preserved in Precambrian cherts, and potential biosignatures in siliceous deposits on Mars.

This study focuses on methylamphetamine (MA) seizures made by the Australian Federal Police (AFP) to investigate the use of chemical profiling in an intelligence perspective. Correlation coefficients were used to obtain a similarity degree between a population of linked samples and a population of unlinked samples. Although it was demonstrated that a general framework can be followed for the use of any forensic case data in an intelligence-led perspective, threshold values have to be re-evaluated for each type of illicit drug investigated. Unlike the results obtained in a previous study on 3,4-methylenedioxymethylamphetamine (MDMA) seizures, chemical profiles of MA samples coming from the same seizure showed relative inhomogeneity, limiting their ability to link seizures. Different hypotheses were investigated to obtain a better understanding of this inhomogeneity although no trend was observed. These findings raise an interesting discussion in regards to the homogeneity and representativeness of illicit drug seizures (for intelligence purposes). Further, it also provides some grounds to discuss the initial hypotheses and assumptions that most forensic science studies are based on., (Copyright © 2014 Elsevier Ireland Ltd. All rights reserved.)

In urban areas, spectral mixture analysis (SMA) is a common technique for deriving the fractions of land covers within a pixel and information on the distribution of impervious surfaces. This study examined how the selection of endmembers affected the quantification of impervious surfaces using TM and ASTER imagery. Multiple subsets of endmembers derived using (1) extreme pixels from a minimum noise fraction (MNF) transformation, and (2) a manual approach usinga prioriknowledge of the study area were analysed. Two data sets were used to assess accuracy: (1) simulated image data comprising unmixed and mixed pixels of 10 typical and spectrally different urban land covers, and (2) detailed data derived from high-resolution aerial photography. The dimensionality of the imagery limited the number of endmembers, and as a result, unmixed land covers were modelled using multiple endmembers and some cells had abundance values that summed to more than one or were negative. The land covers of red roofs and concrete were the largest contributors to the error in impervious surfaces. The Sequential Maximum Angle Convex Cone (SMACC) endmember model was also used to unmix the images; however, the larger number of endmembers did not resolve the use of multiple endmembers to model the unmixed land covers and the accuracy was similar to that using SMA. The relationship between the pervious fraction estimated using the vegetation endmember and the ground reference data was stronger than that for the impervious fraction, although the fraction was underestimated. The problems in modelling highly variable impervious surfaces with a limited number of endmembers suggest that in urban environments with substantial vegetation, modelling the vegetation component as the inverse of the impervious fraction may lead to improved results. [ABSTRACT FROM PUBLISHER]

Two consecutive prefractionated fractions of the Australian marine sponge extract, Pipestela candelabra, were identified to be selectively active on the human prostate cancer cells (PC3) compared to the human neonatal foreskin fibroblast non-cancer cells (NFF). Twelve secondary metabolites were isolated in which four compounds are new small peptides. Their structures were characterized by spectroscopic and chemical analysis. These compounds inhibited selectively the growth of prostate cancer cells with IC50 values in the picomolar to sub-micromolar range. Structure-activity relationship of these compounds is discussed.

We report the first short term velocity centroid (VC) periodicity derived from SiO maser emission. L2 Puppis, a semi-regular AGB star, was observed using the Mopra radio telescope of the Australia Telescope National Facility in the SiO v = 1, J = 1-0 and v = 1, J = 2-1 transitions. It exhibits a 139 day period in its SiO maser VC based on a period folding analysis and a Lomb Scargle analysis. L2 Pup's SiO maser emission has an unusually large velocity range and an unusual three-peaked spectrum. To create the change in VC the entire spectrum does not shift in velocity, but changes in the relative emission of the peaks generate the variation. The changes in the VC may be due to differential illumination, an asymmetric circumstellar distribution of material, or a mixture of causes. The unusual velocity structure, similar to that observed in Orion source 1, may be due to revolution of the circumstellar material or asymmetries in the circumstellar environment. [ABSTRACT FROM AUTHOR]

Context. The Large Magellanic Cloud (LMC) is rich in supernova remnants (SNRs), which can be investigated in detail with radio, optical, and X-ray observations. SNR-J0453-6829 is an X-ray and radio-bright remnant in the LMC, within which previous studies revealed the presence of a pulsar wind nebula (PWN), making it one of the most interesting SNRs in the Local Group of galaxies. Aims. We study the emission of SNR-J0453-6829 to improve our understanding of its morphology, spectrum, and thus the emission mechanisms in the shell and the PWN of the remnant. Methods. We obtained new radio data with the Australia Telescope Compact Array and analysed archival XMM-Newton observations of SNR-J0453-6829. We studied the morphology of SNR-J0453-6829 from radio, optical, and X-ray images and investigated the energy spectra in the different parts of the remnant. Results. Our radio results confirm that this LMC SNR hosts a typical PWN. The prominent central core of the PWN exhibits a radio spectral index αCore of −0.04 ± 0.04, while in the rest of the SNR shell the spectral slope is somewhat steeper with αShell = −0.43- ± -0.01. We detect regions with a mean polarisation of P ≅ (12 ± 4)% at 6 cm and (9 ± 2)% at 3 cm. The full remnant is of roughly circular shape with dimensions of (31 ± 1) pc- × (29 ± 1) pc. The spectral analysis of the XMM-Newton EPIC and RGS spectra allowed us to derive physical parameters for the SNR. Somewhat depending on the spectral model, we obtain for the remnant a shock temperature of around 0.2 keV and estimate the dynamical age to 12-000-15-000 years. Using a Sedov model we further derive an electron density in the X-ray emitting material of 1.56-cm-3, typical for LMC remnants, a large swept-up mass of 830 M⊙, and an explosion energy of 7.6 × 1050 erg. These parameters indicate a well evolved SNR with an X-ray spectrum dominated by emission from the swept-up material. [ABSTRACT FROM AUTHOR]

Context. The Large Magellanic Cloud (LMC) is rich in supernova remnants (SNRs), which can be investigated in detail with radio, optical, and X-ray observations. SNRJ0453-6829 is an X-ray and radio-bright remnant in the LMC, within which previous studies revealed the presence of a pulsar wind nebula (PWN), making it one of the most interesting SNRs in the Local Group of galaxies. Aims. We study the emission of SNRJ0453-6829 to improve our understanding of its morphology, spectrum, and thus the emission mechanisms in the shell and the PWN of the remnant. Methods. We obtained new radio data with the Australia Telescope Compact Array and analysed archival XMM-Newton observations of SNRJ0453-6829. We studied the morphology of SNRJ0453-6829 from radio, optical, and X-ray images and investigated the energy spectra in the different parts of the remnant. Results. Our radio results confirm that this LMC SNR hosts a typical PWN. The prominent central core of the PWN exhibits a radio spectral index αCore of -0.04 ± 0.04, while in the rest of the SNR shell the spectral slope is somewhat steeper with αShell = -0.43 ± 0.01. We detect regions with a mean polarisation of P (12 ± 4)% at 6 cm and (9 ± 2)% at 3 cm. The full remnant is of roughly circular shape with dimensions of (31±1) pc × (29±1) pc. The spectral analysis of the XMM-Newton EPIC and RGS spectra allowed us to derive physical parameters for the SNR. Somewhat depending on the spectral model, we obtain for the remnant a shock temperature of around 0.2 keV and estimate the dynamical age to 12 000-15 000 years. Using a Sedov model we further derive an electron density in the X-ray emitting material of 1.56 cm-3, typical for LMC remnants, a large swept-up mass of 830 M☉, and an explosion energy of 7.6 × 1050 erg. These parameters indicate a well evolved SNR with an X-ray spectrum dominated by emission from the swept-up material. [ABSTRACT FROM AUTHOR]

ABSTRACT We have mapped 20 spectral lines in the Central Molecular Zone (CMZ) around the Galactic Centre, emitting from 85.3 to 93.3 GHz. This work used the 22-m Mopra radio telescope in Australia, equipped with the 8-GHz bandwidth University of New South Wales-Mopra Spectrometer (UNSW-MOPS) digital filter bank, obtaining ∼2 km s−1 spectral and ∼40 arcsec spatial resolution. The lines measured include emission from the c-C3H2, CH3CCH, HOCO+, SO, H13CN, H13CO+, SO, H13NC, C2H, HNCO, HCN, HCO+, HNC, HC3N, 13CS and N2H+ molecules. The area covered is Galactic longitude −07 to 18 and latitude −03 to 02, including the bright dust cores around Sgr A, Sgr B2, Sgr C and G1.6−0.025. We present images from this study and conduct a principal component analysis on the integrated emission from the brightest eight lines. This is dominated by the first component, showing that the large-scale distribution of all molecules is very similar. We examine the line ratios and optical depths in selected apertures around the bright dust cores, as well as for the complete mapped region of the CMZ. We highlight the behaviour of the bright HCN, HNC and HCO+ line emission, together with that from the 13C isotopologues of these species, and compare the behaviour with that found in extragalactic sources where the emission is unresolved spatially. We also find that the isotopologue line ratios (e.g. HCO+/H13CO+) rise significantly with increasing redshifted velocity in some locations. Line luminosities are also calculated and compared to that of CO, as well as to line luminosities determined for external galaxies. [ABSTRACT FROM AUTHOR]

Many countries have significant coverage of publicly funded airborne magnetic and gamma-ray spectrometric surveys that are available to explorers as precompetitive information to encourage exploration. However, individual surveys are generally small, and after decades of data acquisition, explorers are faced with the problem of how to effectively combine the individual surveys into coherent regional compilations. The Australian government's response was to fly a baseline survey over the whole of Australia at approximately 75-km flight line spacing. This has enabled all of Australia's public-domain magnetic and gamma-ray spectrometric surveys to be leveled to common datums using new techniques facilitated by the baseline control provided by the new traverses. This adds significant value to these data, as they can now be used for the interpretation of regional-scale features and for direct comparison of geophysical signatures from different parts of the continent. Also, quantitative modeling and analysis of the data can now be carried out over much larger areas. [ABSTRACT FROM AUTHOR]

This paper reports a reconnaissance survey of the concentrations of sterol compounds (as indicators of fecal contamination) in a large water supply system in southeast Australia comprising a network of rivers, channels, and drains. Levels of coprostanol and cholestanol were determined in surface water and bottom sediment using gas chromatography–mass spectrometry analysis across 17 strategic sampling sites and over 12 months. Clear differences in the levels of fecal contamination were observed among sites. Four sites routinely contained high levels of the fecal indicator sterols indicated from surface water and sediment sample analysis. Coprostanol concentrations at each location varied from 0 ng/L at the reference site to 11,327 ng/L in a surface water sample of a drain directly downstream of a knackery. The majority of the sites contained coprostanol in the range of 500 to 800 ng/L. Since no fecal-associated sterol compounds were detected at the external reference sites, these were assumed to be free from fecal contamination. Sewage water discharge and/or substantial water runoff maybe the principal factors contributing to fecal contamination of the supply drains and channels. [ABSTRACT FROM AUTHOR]