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The 'Green economy', a central plank of the sustainable development political and economic international agenda, relies on industrial extraction of water, minerals and other earths to produce 'green energy' to feed capitalist growth. The term Green extractivism describes a global problem that we examine through the case of lithium extraction in the territory of Atacameño-Likanantay (Indigenous) peoples in the Salar de Atacama, Chile. Green extractivism is a multiscalar logic and practice justified in international sustainable development policies, responding to the demands of capital, modifying international and national legal and political instruments, and permeating social, ecological and political realities in the territories of extraction. Green extractivism has many consistencies with the asymmetries of power and economic dependency that characterises the history of extractivism in Chile and Latin America. As such, Green extractivism provides a new logic to sustain consistencies in transnational capitalism. This paper traces national political and legal histories of lithium from the mid-twentieth century, demonstrating the long extractivist relationship between the state and the lithium companies that operate in the Salar de Atacama. We consider, in particular, the dynamics of Atacameño-Likanantay peoples' participation in and refusals of industry and state processes, which trouble extractivist logics. [ABSTRACT FROM AUTHOR]