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Historic charcoal hearth remains provide a unique archive of the long-term interaction between biochar, soil development, and plant growth. Charcoal as raw material was crucial for production of iron in iron works, and hence numerous charcoal hearths can be found in the forests near historic iron works in Europe and in the eastern united States. Charcoal hearths are round to elliptical forms often around 10 m in diameter and consist of several-decimeter-thick layers that contain charcoal fragments, ash, and burnt soil. We studied the soil chemistry of 24 charcoal hearths and compared them with the surrounding "natural" soils in the northern Appalachians of northwestern Connecticut. The thickness of the topsoils on the charcoal hearths and their carbon content are remarkably higher than in the surrounding topsoils. The presence of residual products from charcoal production classifies the soils as Anthropic Udorthents (US Soil Taxonomy) or Spolic Technosols (Humic) according to the World Reference Base for Soil Resources. The widespread occurrence of charcoal hearth remains, and their high spatial density in different ecosystems underlines their importance for further pedological research. [ABSTRACT FROM AUTHOR]