1. Influence of vegetation type and site-to-site variability on soil carbonate clumped isotope records, Andean piedmont of Central Argentina (32–34°S).
- Author
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Ringham, Mallory C., Hoke, Gregory D., Huntington, Katharine W., and Aranibar, Julieta N.
- Subjects
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CARBONATES in soils , *SOIL formation , *GEOTHERMOMETERS - Abstract
The clumped isotope geothermometer estimates the formation temperature ( T ( Δ 47 ) ) of carbonates and has great potential to enhance the extraction of environmental data from pedogenic (soil) carbonate in the geologic record. However, the influence of vegetation type and site-specific conditions on carbonate formation processes and T ( Δ 47 ) records remains poorly understood. This study examines the potential for variability in T ( Δ 47 ) data between nearby, same elevation sites with different C 3 /C 4 biomass. Pedogenic carbonates (undercoatings and nodules) were collected from five modern soil pits in the semi-arid eastern Andean piedmont of Argentina under a summer precipitation regime. Three pits were instrumented with temperature and moisture sensors to 1 m depth, and a fourth was instrumented with additional soil CO 2 and atmospheric (temperature, relative humidity, insolation, and rainfall) sensors. T ( Δ 47 ) values (mean: 30 ± 6 ° C (±1SE)) are invariant with depth and are statistically indistinguishable between the four instrumented sites, though a 10 °C difference between our T ( Δ 47 ) values and those of a nearby Peters et al. (2013, EPSL) study suggests the potential for significant site-to-site variability, likely due to local soil hydrology. The results of this study suggest that deeper (≥40 cm) T ( Δ 47 ) values are consistent with carbonate formation during the early part of soil drying immediately after large mid-summer rainstorms. Carbonate formation ≤ 40 cm depth may be biased to soil drying after small, frequent precipitation events occurring throughout the spring, summer, and fall months, averaging to shallow summer T ( Δ 47 ) values and resulting in a near-isothermal T ( Δ 47 ) profile. [ABSTRACT FROM AUTHOR]
- Published
- 2016
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