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Abstract: Miocene igneous rocks (diorites, andesites, dacites, rhyolites and microgranites) of Chetaibi and Cap de Fer massif, NE Algeria, are high-K calc-alkaline to shoshonitic rocks. Fresh diorites have δ34S and δ18O values ranging between −2.5‰ and +5.9‰, +6.5‰ and +6.7‰ respectively, indicating a mantle origin. The relatively low δ34S values (−5.4‰ to −12.2‰) and high δ18O (+8.3‰ to +9.0‰) of altered diorites indicate the input of a crustal component to the initial magma. The microgranites’ I-type signature is indicated by the geochemical data and the δ34S and δ18O values of −1.2‰ and −3.6‰, and +7.8‰ to +10.4‰ respectively. The andesites show a large variation of δ34S, between −33.2‰ and +25.7‰. Massive andesites with δ34S between +6.8‰ and +7.6‰ preserve a 34S-enriched mantle signature. The δ34S of the lava flows between +25.7‰ and +25.8‰ are attributed to open system magma degassing, whereas the low δ34S of two andesitic dyke samples (−13.7‰ and −33.2‰) strongly suggest a crustal sulphur input. High δ18O (+9.2‰ to +15.7‰) of andesites indicate post-magmatic alteration (mainly silicification); the flyschs with δ18O between of +13.3‰ and +21.7‰ are most likely the contaminant. Quartz veins within the andesites gave a δ18O value of +23.0‰ while silica-filling vesicles yielded a value of +13.8‰. Initial Sr-isotope data are rather high for all the rocks (diorites: 0.707–0.708, andesites: 0.707–0.710, and microgranites and rhyolites: 0.717–0.719), and because geochemical and stable isotope data do not indicate a substantial amount of crustal assimilation, an extensive enrichment of the mantle source by subducted sediments is called for. A metasomatized-mantle source, characterized by high radiogenic Sr and relatively high δ18O, has also been indicated for the genesis of similar Tertiary igneous rocks in the Western Mediterranean basin, e.g. the Volcanic Province of southeasten Spain [Benito, R., Lopez-Ruiz, J., Cebria, J.M., Hertogen, J., Doblas M., Oyarzun, R., Demaiffe, D., 1999. Sr and O isotope constraints on source and crustal contamination in the high-K calc-alkaline and shoshonitic neogene volcanic rocks of SE Spain. Lithos 46, 773–802] and some plutons of northeastern Algeria [Ouabadi, A., 1994. Pétrologie, géochimie et origine des granitoïdes peralumineux à cordiérite (Cap Bougaroun, Béni-Touffout et Filfila), Algérie nord-orientale. Thèse de Doctorat, Université de Rennes I, France, 257p; Fourcade, S., Capdevila, R., Ouabadi, A., Martineau, F., 2001. The origin and geodynamic significance of the Alpine cordierite-bearing granitoids of northern Algeria. A combined petrological, mineralogical, geochemical and isotopic (O, H, Sr, Nd) study. Lithos 57, 187–216]. [Copyright &y& Elsevier]

The petrogenesis of igneous, metamorphic and mineralized rocks in the Edough massif, NE Algeria, indicates an interplay between crustal and magmatic sources, and magmatic and surface fluids, as determined by sulphur and oxygen isotopic analyses. The Tertiary igneous rocks (microgranites and rhyolites) show a tendency towards I-type granitoids with δ34S values of +5.4±2.2‰ (1σ) and δ18O between +5.6‰ and +6.9‰, with the most hydrothermally altered rocks having the lowest δ18O values. This is indicative of seawater being a major component of the hydrothermal fluids. Seawater interaction with the granitoids produced enrichment in 34S of sulphide-sulphur in both the microgranites and associated skarn mineralization. However, in the Beleleita W–Sn–(Au) deposit, magmatic fluids dominated the mineralization, reflected by δ34S values of +1.7‰ and +1.8‰. The basement amphibolites of Kef Lakhal indicate derivation from a basaltic magma with δ18O ranging from +4.9‰ to +8.6‰. Locally altered amphibolite has the lowest δ18O values suggestive of meteoric water interaction, whereas the highest δ18O indicate the incorporation of crustal material during the genesis of the amphibolites. Crustal contamination is also reflected in their δ34S of −18‰ to +2.1‰, with the most contaminated rocks having the lowest δ34S. Host Palaeozoic mica schists with δ18O of +12.7‰ and δ34S of −13.2‰ and associated marbles (δ34S −9.9‰ to −17.4‰) are thought to be the most likely contaminants. At the Ain Barbar Fe–Cu–Pb–Zn deposit, δ34S values range between −9.6‰ and −10.8‰, indicating that the sulphide-sulphur and base-metals were likely leached from the host Cretaceous flysch and/or the underlying mica schists, with local Tertiary magmatic rocks providing the heat for local convection cells. At Boumaiza Fe-deposit, δ34S values of the sulphide-sulphur extend from −1.2‰ to −8.1‰ indicative of magmatic sulphur with the incorporation of substantial amounts of sulphur derived from the host mica schists. [Copyright &y& Elsevier]