1. Water microbial disinfection via supported nAg/Kaolin in a fixed-bed reactor configuration.
- Author
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Ozer, Lütfiye Yıldız, Yusuf, Ahmed, Uratani, Joao M., Cabal, Belén, Díaz, Luis A., Torrecillas, Ramón, Moya, José S., Rodríguez, Jorge, and Palmisano, Giovanni
- Subjects
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KAOLIN , *WATER disinfection , *FIXED bed reactors , *SEWAGE disposal plants , *GLASS beads , *BOROSILICATES - Abstract
In this paper we have investigated and demonstrated the antimicrobial capabilities of nano-silver-4 wt%-kaolin (nAg-4-Kn) composite supported on borosilicate glass beads (BGB). Tests have been conducted in a fixed bed reactor on effluent from the secondary clarifier of a conventional wastewater treatment plant (WWTP) in Abu Dhabi, United Arab Emirates (UAE). The prepared BGB with immobilized nAg-4-Kn (nAg-4-Kn/BGB) were characterized using the RAMAN spectroscopy, TEM equipped with EDX and Focus Ion Beam Scanning Electron Microscope (FIB-SEM) techniques. The rate of disinfection was assessed through Luria-Bertani (LB)-agar plate cell counting technique. The results showed complete disinfection after few hours, which was preserved even after several days in repeated runs. The nAg-4-Kn/BGB was reused, demonstrating that the immobilization of nAg-4-Kn was stably achieved, and the activity and integrity of the composites on the BGB were preserved. First order disinfection kinetic constants were estimated to be 2.76 cm h−1 and 2.56 cm h−1 in two consecutive runs. Analyses of the beads after the experiments showed minor losses of nAg from the kaolin matrix thereby corroborating reusability of these materials. • nAg/Kaolin composites supported on glass have significant antimicrobial properties. • Disinfection of a real effluent follows first order kinetics. • nAg/Kaolin composites are stably supported on glass beads. • nAg/kaolin supported on glass can be reused over a long time. [ABSTRACT FROM AUTHOR]
- Published
- 2020
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