1. Raman probing of competitive laser heating and local recrystallization effect in ZnO nanocrystals.
- Author
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Ye JD, Parkinson P, Ren FF, Gu SL, Tan HH, and Jagadish C
- Subjects
- Hot Temperature, Materials Testing, Nanoparticles ultrastructure, Surface Properties radiation effects, Crystallization methods, Lasers, Nanoparticles chemistry, Nanoparticles radiation effects, Spectrum Analysis, Raman methods, Zinc Oxide chemistry, Zinc Oxide radiation effects
- Abstract
The competitive laser-induced local heating and recrystallization effects in ZnO nanocrystals embedded in a MgO/ZnO stack are reported via resonance Raman spectra. The dependence of the intensity, energy, and resonance effects of the longitudinal optical (LO) phonon on laser excitation condition are discussed in the context of Fröhlich interaction. Redistribution of defects, impurity-diffusion, and grain regrowth caused by thermal and photochemical effects lead to significant changes in coupling strength of electron-phonon interaction, and the resonance behaviors are strongly affected by the interplay of local heating, heat trapping, and local structural modification in such nanostructures.
- Published
- 2012
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