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Metal pollution due to the huge electronic waste (E-waste) accumulation is widespread across the globe. Extraction of copper, zinc and nickel from computer printed circuit boards (c-PCB) with a two-step bleaching process using ferric sulphate generated by Leptospirillum ferriphilum dominated consortium and the factors influencing the process were investigated in the present study. The studied factors with 10 g/L pulp density showed that pH 2.0 was optimum which resulted in 87.50-97.80% Cu-Zn-Ni extraction. Pre-treatment of PCB powder with acidified distilled water and NaCl solution showed 3.80-7.98% increase in metal extraction corresponding to 94.08% Cu, 99.80% Zn and 97.99% Ni extraction. Particle size of 75 μm for Cu and Zn while 1680 μm for Ni showed 2-folds increase in metal extraction, giving 97.35-99.80% Cu-Zn-Ni extraction in 2-6 days of reaction time. Whereas; 2.76-3.12 folds increase in Cu and Zn extraction was observed with the addition of 0.1% chelating agents. When the studies were carried out with high pulp density, ferric iron concentration of 16.57 g/L was found to be optimum for metal extraction from 75 g/L c-PCB and c-PCB addition in multiple installments resulted in 8.81-26.35% increase in metal extraction compared to single addition. The studied factors can be implemented for the scale-up aimed at faster recovery of multimetals from E-waste and thereby providing a secondary source of metal in an eco-friendly manner., (Copyright © 2014 The Society for Biotechnology, Japan. Published by Elsevier B.V. All rights reserved.)

In scale-up biphasic leaching process of polymetallic concentrate, the ferric bioregeneration cycles were performed in 15.0L down flow packed bed reactor; whereas the chemical leaching cycles were done using the biogenerated ferric in an indigenously designed 10.0L stirred tank reactor. The consortium took 25cycles for proper biofilm formation. It showed highest iron oxidation rate (IOR) of 3908.21mg/L/h at 25thcycle under no polymetallic stress. Even under stressed conditions, it was 2650-558mg/L/h. Cu extractions were 86.63-46.51 and Zn extractions were 67.89-14.74% in 1st-4thcycle, respectively. The developed consortium exhibited 17-51times higher IOR compared to original wild type consortium. Extraction isotherm for zinc with 30% Cyanex® 301 indicated that a total of two stages are required for its complete extraction using the phase ratio of 2:1 at equilibrium pH 1.5, leaving behind Fe(II) in the raffinate., (Copyright © 2014 Elsevier Ltd. All rights reserved.)

Recently electronic waste (e-waste) includes the fastest growing waste stream in the world. Nevertheless, it also contains about 40 different elements of the periodic table; hence it is a significant metal source. Generally, e-waste recycling is done by the pyrometallurgy and/or hydrometallurgy method. However, the use of microorganisms in hydrometallurgy called bioleaching is a good alternative for eco-friendly and cost-effective recycling of e-waste and recover metals. Leptospirillum-dominated consortium was used to generate ferric iron lixiviant by oxidizing ferrous iron. The resulting lixiviant was used for bioleaching of metals from waste cell phone printed circuit boards (WPCBs). The pretreatment of pulverized WPCB (p-WPCB) and unpulverized WPCB (up-WPCB) was done using 2 M NaOH to see the effect of pretreatment on metal extraction. Moreover, the effect of maintenance of pH of the system was also checked. The controlling of pH of the system to 2.0 ± 0.1 showed enhancement of Cu, Zn, and Ni solubilization. The highest solubilization of copper was 96.86%, which was achieved with pretreated up-WPCB; zinc was 90.69% with pretreated p-WPCB, whereas nickel was 93.65% with untreated up-WPCB. Ours is the first report for extraction of copper, zinc, and nickel from unpulverized mobile phone WPCBs at high pulp density. The solubilization of metals achieved with 100 g/L pulp density provides a promising indication to scale up the process. [ABSTRACT FROM AUTHOR]

Abstract: Polyphasic optimisation process for ferric iron mediated metal extraction with 50mL system on COD digester showed 60% copper and 56% zinc extractions in only 30 and 90min of contact time respectively. Optimum conditions were 90°C reaction temperature, 10% (w/v) pulp density, pH 1.8 and 1.5% (w/v) Fe3+ concentration. The system was scaled up successfully to 5000mL and as high as 80.81% copper and 54.0% zinc extractions were obtained in 30 and 90min respectively without addition of any catalyst. The bioregeneration of Fe3+ iron from the leachate in shake flask study by developed iron oxidising consortium showed IOR of 396mg/L/h in the presence of as high as 124.8, 21.0, 2.8 and 26.7g/L total dissolved solids, total iron, copper and zinc respectively. The developed biofilm in down-flow packed bed column having UHMWPE plastic material as support matrix showed 3100mg/L/h IOR, which is eight fold higher as compared to the best IOR obtained in shake flask study. [Copyright &y& Elsevier]