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In this research work, a simple spray pyrolysis method was employed to synthesized gadolinium (Gd) doped titanium oxide (TiO2) thin film. The crystal structure and morphology of the sample was characterized by X-ray diffraction (XRD) and scanning electron microscope (SEM). According to XRD measurements, no apparent crystal peak was observed. The thickness of the prepared film was found to be 228 nm from SEM observation. The optical transmittance and bandgap energy of the synthesized thin film was investigated by using UV-Vis spectroscopy. The high transmission of the thin film was found in the visible region. The optical bandgap energy of the prepared film was found to be 2.85 eV. The photocatalytic degradation of malachite green solution was studied. As a result of the photocatalytic experiment, the thin film could be used as an effective photocatalyst for malachite green dye. [ABSTRACT FROM AUTHOR]

Purpose of this study is to investigate effect of gadolinium (Gd) content of GdxFe2O3(100-x), (x = 0, 5, 10, 20) composite system on structural, thermal, optical and radiation protection of poly (vinyl alchool) PVA based nanocomposite film. In this study, Gd doped Fe 2 O 3 nanopowders (with Gd = 0, 5, 10 and 20) were synthesized by spray pyrolysis method. The characterization of these powders have been obtained by using X-ray diffractometer (XRD), scanning electron microscopy (SEM), and Uv–vis spectrometer. After then, GdxFe 2 O 3 (100-x)/PVA (x = 0, 5, 10, 20) polymer composite systems were prepared by solution casting technique. The structural, thermal and optical properties of obtained polymer composites have been examined. The irradiation properties of 6 MeV energized X-ray via cLINAC to obtain radiation shielding performance of these different percentage (0, 5, 10, and 20%) Gd doped Fe 2 O 3 PVA thin films were also investigated. By using obtained results, the Linear Attenuation Coefficient (LAC), Half Value Layer (HVL), Tenth Value Layer (TVL), Mass Attenuation Coefficient (MAC). Also, theoretically Z eff value have been calculated. According to all obtained results, it has been seen that the different percentages (0, 5, 10, and 20%) Gd doped Fe 2 O 3 PVA thin films can be used as radiation shielding material. • Purpose of this study is to investigate effect of gadolinium (Gd) content of GdxFe2O3(100-x), (x=0, 5, 10, 15, 20) composite system on structural, thermal, optical and radiation shielding of poly (vinyl alchool) PVA based nanocomposite film. • The characterization of these powders have been obtained by using X-ray diffractometer (XRD), scanning electron microscopy (SEM), and Uv–vis spectrometer. • The irradiation properties of 6 MeV energized X-ray via cLINAC to obtain radiation shielding performance. • By using obtained results, the Linear Attenuation Coefficient (LAC), Half Value Layer (HVL), Tenth Value Layer(TVL), Mass Attenuation Coefficient(MAC). • Also, theoretically Zeff values have been calculated. [ABSTRACT FROM AUTHOR]

In recent years, the production of alternative materials instead of lead in the environmentally sensitive and non-toxic material research in radiation shielding has been gained importance. In this study, transparent pristine and boron (B) doped zinc oxide (ZnO) thin films were synthesized by spray pyrolysis method. The crystalline structure, morphology and optical properties of the produced films were investigated with X-ray diffractometer (XRD), scanning electron microcopy (SEM) and Uv–vis spectrometer. The wurtzite structure of pure ZnO was deformed by boron doping found from XRD results. The hexagonal rods have been worsened with boron doping observed from SEM analysis. The factors related to radiation shielding; mass and linear attenuation coefficients, half value layer, mean free path and tenth value layer of different percentage (5, 10 and 20%) B doped ZnO thin films were examined. To perform these measurements, PTW® electron detector and irradiation have been utilized with 6 MeV energized electrons by using VARIAN®. The obtained results from these measurements can be useful to understanding of radiation shielding performance of ZnO:B thin films. • Pristine and boron doped zinc oxide thin films were synthesized by pyrolysis methods. • Optical transmittance of the prepared films were enhanced as a function of boron concentration. • The linear attenuation coefficient increased as the percentage of boron in the thin films increased. • ZnO: B thin films can be used as radiation shielding with different materials in radiation treatment centers. [ABSTRACT FROM AUTHOR]