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Your search keyword '"Breeze, Ben G."' showing total 1 results
Start Over Author "Breeze, Ben G." Topic x-ray photoelectron spectroscopy
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1. Cu(III)–bis-thiolato complex forms an unusual mono-thiolato Cu(III)–peroxido adduct.

Author

Donnelly, Jane M., Lermyte, Frederik, Wolny, Juliusz A., Walker, Marc, Breeze, Ben G., Needham, Russell J., Müller, Christina S., O'Connor, Peter B., Schünemann, Volker, Collingwood, Joanna F., and Sadler, Peter J.

Subjects
X-ray photoelectron spectroscopy, CYCLIC voltammetry
Abstract

The stable complex [bis(toluene-3,4-dithiolato)copper(III)][NEt3H] has been synthesised and characterised as a square-planar Cu(III) complex by X-ray photoelectron spectroscopy, cyclic voltammetry and DFT calculations. Intriguingly, when fragmented in FTICR-MS, an unusual [(toluene-3,4-dithiolate)Cu(III)(peroxide)]− complex is formed by reaction with oxygen. Natural 1,2-dithiolenes known to bind molybdenum might stabilise Cu(III) in vivo. [ABSTRACT FROM AUTHOR]

Published
2021
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