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Highlights • The influence of the fluctuation of CO 2 concentration in the lower atmosphere is discussed in the measurement of XCO 2. • A weighting function optimized method is provided considering the actual CO 2 concentration profile and the proportion of the lower weighting function. • The method corrects the bias in the measurement and relaxes the atmosphere sensitivity to pressure. • More appropriate wavelengths have been provided for the further reference of development of an IPDA lidar. Abstract Weighting function can affect the retrieval of the column gas mixing ratio of integrated path differential absorption (IPDA) lidar because it contains the vertical distribution information of the target gas. In order to optimize the wavelengths within the 1.57 um spectral band for IPDA lidar for CO 2 measurement. The temperature, pressure and water vapor (TPH) sensitivity and the proportion of the weight function integration in the lower layer part to the total atmosphere layer (R) of each wavelength are calculated. The measurement errors of each wavelength are simulated with CO 2 fluctuation in the lower layer. The specific wavelength with the R value of 0.6 has been found to be a stable measurement bias which does not change with fluctuations, so the R value of 0.6 is used to optimize the wavelength for measurement CO 2. The simulation results show that the measurement error via wavelength is smaller than 0.05 ppm, when the TPH sensitivity is smaller than 0.95 and when R is about 0.6. This proposed method can be applicable for the further airborne or space-borne lidar development. [ABSTRACT FROM AUTHOR]

Abstract: Chemically reactive atmospheric species play a crucial role in tropospheric processes which affect regional air quality and global climate change. Contrary to long-lived species such as greenhouse gases, interference-free accurate and precise concentration assessments of strongly reactive short-lived species represent a real challenge. In this paper, we report on the recent progress in spectroscopic instrumental developments for monitoring of OH, NO3, HONO and NO2 by using modern photonic sources (Quantum Cascade Laser, distributed feedback diode laser, light emitting diode) in conjunction with high-sensitivity spectroscopic measurement techniques such as multi-pass cell based long optical path length absorption spectroscopy, wavelength-modulation enhanced off-axis integrated cavity output spectroscopy, Faraday rotation spectroscopy, incoherent broadband cavity enhanced absorption spectroscopy. The main techniques available for routine atmospheric measurements of OH, NO3 and HONO are overviewed, in comparison with the emerging modern photonic spectroscopy techniques. [Copyright &y& Elsevier]