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The Total Maximum Daily Load (TMDL) program is an integrated process of watershed assessment and management to address surface water quality impairment. The management of organic contaminants and nutrients is a primary concern in conserving surface water bodies. Watershed-scale pollutant loads simulation can assist stakeholders and watershed planners in making decisions on immediate and long-term land use schemes to improve water quality. However, the behavior of contaminants in a watershed needs to be characterized prior to such model applications. The objectives of this study were to characterize point and nonpoint pollutants runoff at a watershed scale and to develop a Pollutant Load Calculation Model (PLCM), which facilitates the estimation of pollutant delivery to a watershed outlet. The developed model was applied for the six sub-watersheds of the Saemangeum estuarine watershed in Korea, where a large tidal reclamation project has been underway. Two years stream flow and water quality data were used for the model calibration, while 1 year data were utilized for the model validation. The model calibration resulted in the R 2 values of 0.58, 0.53, and 0.35 for BOD, TN, and TP, respectively. Overall performance for the validation period was similar with that for the calibration period although the R 2 values were slightly decreased. The PLCM tends to substantially under or overestimate delivery pollutants loads during the summer rainy seasons when most rainfall events occur. This is probably because once-a-month-measured water quality data, which might not represent appropriately monthly water quality, particularly, for rainy seasons, were used for the loads calculation. Thus, more frequently monitored water quality data should be used for the delivery loads estimation at least for a rainy season in order to improve the PLCM performance. Nevertheless, the developed model took the pollutant reduction process into account, which is not allowed with the conventional unit loading method, and furthermore temporal variations of pollutant loads based on stream flows were also incorporated into the pollutant loads estimation. The developed PLCM can be a useful tool to assess pollutants delivery loads at a watershed scale and thus assist decision makers in developing watershed pollution management schemes.

South Korea is located in the Asian monsoon region, and paddy rice farming is one of the important agricultural activities, which may contribute to the non-point source pollution of inland water bodies along with rainfall runoff. The status of water quality in rural streams located throughout South Korea was examined in this study by water quality monitoring and statistical analysis. Totally six surveys were conducted in 2003 and 2005 to monitor 300 streams located in rural subwatersheds; these streams are affected by agricultural activities and water supply for agricultural practices. The monitoring was performed at the terminal point of each subwatershed. In each study year, the streams were monitored in the three hydrological periods (April, July, and October) to observe differences in the impacts of agricultural activity and rainfall pattern. During the surveys, 15 water quality parameters were measured and interpreted using multivariate statistical methods including factor analysis and cluster analysis. Results show that the water quality of the rural streams monitored in this study appeared to meet the Korean water quality criteria for agricultural use, which are 8.0 and 100 mg/L for biochemical oxygen demand and suspended solids, respectively. In terms of organic contamination and suspended solids, the best stream water quality was observed in October compared to other periods. This can be attributed to the fact that October follows the rice-harvesting period and has low rainfall; thus the streams are probably less affected by agricultural activities and surface runoff. The three hydrological periods did not show much variation in the nitrogen and phosphorus parameters related to stream water nutrient conditions. Factor analysis indicates that the first five factors for April explained about 67% of the total sample variance. In July, the first four factors explained about 60% of the total variance, while the first four factors for October explained about 65%. Cluster analysis reveals that the streams could be divided into four groups in April and October and five groups in July. The box-and-whisker plots of the physicochemical variables indicate that Group A had the best water quality among the groups. This study demonstrates that the rural stream water quality of South Korea in the Asian monsoon region can be greatly affected by agricultural activities such as paddy rice farming and rainfall patterns.

This study was carried out to develop a water quality simulation model for the evaluation of an ungauged watershed. For this purpose, the WASP5 model was selected and modified. The model consists of three sub-models, LOAD-M, DYN-M, and EUT-M. LOAD-M, an empirical model, estimates runoff loadings using point and non-point source data of villages. The Geum River Estuary watershed was selected to calibrate and verify the Modified-WASP5. The LOAD-M model was established using field data of water quality and quantity at the gauging stations of the watershed and was applied to the ungauged watersheds, taking the watershed properties into consideration. The result of water quality simulation using Modified-WASP5 shows that the observed average BOD data from Gongju and Ganggyeong were 2.6 mg/L and 2.8 mg/L, and the simulated data were 2.5 mg/L and 2.4 mg/L, respectively. Generally, simulation results were in good agreement with the observed data. This study focused on formulating an integrated model for evaluating ungauged watersheds. Even though simulation results varied slightly due to limited availability of data, the model developed in this study would be a useful tool for the assessment and management of ungauged watersheds.

We investigated the applicability of a dredged pool formed at the inlet of a reservoir for pollution control. To quantify the effect of a dredged pool on the water quality of a reservoir, we monitored the water quality of the Masan Reservoir, located in the city of Asan, Choongnam Province, Korea, before and after dredging. In addition, a completely mixed box model was applied to simulate the water quality of the dredged pool and reservoir. The model included a water balance equation and chemical mass balance equation, into which several interactions among water quality components, such as phytoplankton, total nitrogen (T-N), total phosphorus (T-P), dissolved oxygen, and chemical oxygen demand (COD), were incorporated. The water quality monitoring and modeling results indicated that reservoir water quality was greatly affected by the dredged pool. The loads of T-N and T-P into the reservoir were reduced by the dredged pool, which may have induced the removal of nutrients by settling. However, the dredged pool may have had a negative effect on the reservoir in terms of COD and chlorophyll-a because of the internal production of organic matter and/or algae with water detention. Therefore, a dredged pool may be used for pollution control in a reservoir, as long as it is combined with measures to reduce concentrations of organic matter and/or algae.

This study was performed to evaluate the need for heating wastewater to enhance treatment efficiency of organic matter (BOD, SS) during cold winter in newly developed Absorbent Biofilter System (ABS) which was established in the Suwon Campus of the Seoul National University. Treatments consisted of non-heating (2000 year) and heating(2001, 2002 year), and sampled data were analyzed during cold winter period as well as post winter period to investigate the influence of heating after winter season. Even the average air temperature showed only difference between two experimental years, the difference in the average effluent temperature during cold winter period between heating and non-heating experiment was approximately . The average effluent concentration of organic matter in non-heating treatment exceeded the Korean standards for water quality of discharged effluent in riparian area (BOD and SS 10 mg/L); however, the standards were met in case of heating treatment during both winter and post winter period. Therefore, the need fur heating wastewater during cold winter season in ABS was justified. On the other hand, there was no improvement of treatment efficiency in T-N and T-p, but we observed the more activated nitrification as increasing the wastewater temperature. Because the average underground temperature was higher than the average air temperature during cold winter period, we recommend that the ABS can be established in the underground rather than on-ground for saving the heating cost.

This study was conducted to identify the characteristics of non-point pollutants discharge in a small agricultural watershed during farming season. for this purpose, the Neoungchon watershed in Goesangun was selected as a typical agricultural area. Runoff and water quality data in the stream, the domestic sewage and the precipitation of the watershed were analyzed periodically from June 1 to November 6 in 2004 and pollutant loads were estimated. As a result the mean concentrations of BOD, SS, TN and TP in the stream were 3.0, 76.7, 8.7, 0.16 mg/L in rainy season and 2.4, 10.0, 3.5, 0.11 mg/L in dry season respectively. Daily discharge of non-point pollutant occurred above of 95% in rainy period. Measured pollutant loads in the watershed were of T-N and of T-P, within the range of other research results. Effluent loads based on guideline of total pollutant to stream management of MOE (Ministry of Environment) were less than delivery loads since the guideline could not reflect the agricultural practices, geomorphic and meteorological characteristics in an agricultural watershed.

A prototype surface flow constructed wetland was built in the upstream area of reclaimed tidal lands to improve the water quality of Lake Sihwa by treating severely polluted stream water. In this study, a tracer test using rhodamine-WT was performed to investigate the flow characteristics and to quantify the observed hydraulic residence time (HRT) for a high-lying cell in the Banwol wetland of the Sihwa constructed wetland. The tracer test indicated that even if flow was mainly observed in the open water area of the Banwol wetland, water flowed continuously in the vegetative area and there was no dead zone. The calculated HRT (51.3 hrs), calculated by dividing the wetland volume by the wetland inflow, exceeded the observed HRT (38.7 hrs), since the short-circuiting of flux resulting from irregular topography and vegetation was not reflected in the calculated HRT. The exit tracer concentration curves were reproduced well by both the plug flow with dispersion and tanks-in-series models, indicating that the performance of the Banwol wetland can be estimated accurately using these models.

NPS pollutant loads from sandy clayey and clayey loam runoff plots were measured. Runoff plots were 210 m in size and 8~10% in slope and paddy area was 4,620 . Soybean, corn, tobacco and control (natural weed) were cultured. Precipitation during the growing season of June to October, 2002 was 869.5 mm. Runoff and water quality were measured more than 10 times during the measurements depending on the growing stage. Pollutants loads were estimated by using respective concentration and runoff volume. Runoff occurred when daily rainfall exceeded about 30 mm. The largest runoff was observed from the paddy but pollutant loads were larger from upland crops than those from paddy. SS loads from paddy and upland were 1.4 ton/ha/yr and 3.1~4.3 ton/ha/yr, respectively. COD loads 30 kg/ha/yr and 66~90 kg/ha/yr, T-N loads 13 kg/ha/yr and 14~23 kg/ha/yr, T-P loads 1 kg/ha/yr와 4 kg/ha/yr, nitrate nitrogen loads 1 kg/ha/yr and 4~8 kg/ha/yr, and phosphate phosphorus loads 0 kg/ha/yr and 4~6 kg/ha/yr, respectively. It was concluded that NPS pollutant loads from upland crop culture have greater impact on the quality of the receiving water body than those from paddy culture.

Reservoirs are the predominant type of lentic ecosystem in Korea, and they account for a considerable proportion (~59%) of the agricultural water uses. There are 18,797 reservoirs in Korea; most (~90%) are small (storage capacity

The objective of this study was to know the qualities of soil and shallow groundwater in plastic film house fields around Central Part of Korea. The study was conducted at 11 sites in Suweon, Hwasung, Pyungtaek, Yongin and Chuncheon through May to August in 1999. Soil textures of plastic films house were mainly sandy loam or loam. Electric conductivity and organic matter content of surface soils mostly exceeded the critical levels for crop production. Average concentration of in the sha]low groundwater was 19.1 mg/L, and it reached almost the limiting level of agricultural groundwater quality (20 mg/L). Moreover about 36% of survey sites exceeded the limiting level of agricultural groundwater quality. Sulfate concentrations also at some sites exceeded agricultural groundwater quality limit level (50 mg/L). Nitrate-N, one of the most important factors in the groundwater quality, had positive correlations with other ions in foundwater.

A pilot study was performed to examine the feasibility of using a constructed wetland system for treatment of sewage in a Korean rural community. The treatment system was a subsurface flow wetland with a loading rate and hydraulic residence time of 6.3 cm/day and 3.5 days, respectively. The wetland system was highly effective in treating the sewage; median removal efficiencies of BOD5 (biological oxygen demand) and TSS (total suspended solids) were about 70.0%, with median effluent concentrations of 24 and 13 mg/L, respectively, for these constituents. However, BOD5 and TSS did often exceed the effluent water quality standards of 20 mg/L. Removal of TN (total nitrogen) and TP (total phosphorus) was relatively less effective and median effluent concentrations were approximately 81 and 8 mg/L, respectively. The treatment system did not experience any clogging or accumulation of organic and inorganic solids during the study, and during winter a substantial amount of removal of BOD5 and TSS continued to occur. Overall, the constructed wetland was judged to be an effective sewage treatment system, but not sufficient by itself to attain regional water quality standards. Therefore, treatment of rural sewage by a wetland system should be followed by another process such as use of the effluent for irrigation of agricultural crops (e.g., rice).

A feasibility study was performed to examine the agronomic application of the treated sewage on paddy rice culture through field experiment. The domestic sewage was treated using a constructed wetland system, a subsurface flow type consisting of sand and macrophyte. The effluent of the wetland system was diluted to maintain the total nitrogen concentration below 25 mg/L and was used as irrigation water. Addition of the treated sewage to the irrigation water showed no adverse effect on the paddy rice culture; in fact some enhancement was noticed in both growth and yield. Irrigation with the treated sewage after the concentration was adjusted accompanied by conventional fertilization showed a better result, with the yield exceeding that of the control where clean water was used, thus suggesting that reuse of the treated sewage as supplemental irrigation water could be a feasible and practical alternative. For a full-scale application, however, further study is recommended on the specific guideline for controlling the major water quality components in the treated sewage.