Search

The effectiveness of UV-based advanced oxidation processes (UV-AOPs) in degrading trace organic contaminants (TrOCs) can be significantly influenced by the ubiquitous presence of nitrate (NO 3 - ) and nitrite (NO 2 - ) in water and wastewater. Indeed, NO 3 - /NO 2 - can play multiple roles of NO 3 - /NO 2 - in UV-AOPs, leading to complexities and conflicting results observed in existing research. They can inhibit the degradation of TrOCs by scavenging reactive species and/or competitively absorbing UV light. Conversely, they can also enhance the elimination of TrOCs by generating additional •OH and reactive nitrogen species (RNS). Furthermore, the presence of NO 3 - /NO 2 - during UV-AOP treatment can affect the transformation pathways of TrOCs, potentially resulting in the nitration/nitrosation of TrOCs. The resulting nitro(so)-products are generally more toxic than the parent TrOCs and may become precursors of nitrogenous disinfection byproducts (N-DBPs) upon chlorination. Particularly, since the impact of NO 3 - /NO 2 - in UV-AOPs is largely due to the generation of RNS from NO 3 - /NO 2 - including NO•, NO 2 •, and peroxynitrite (ONOO - /ONOOH), this review covers the generation, properties, and detection methods of these RNS. From kinetic, mechanistic, and toxicologic perspectives, future research needs are proposed to advance the understanding of how NO 3 - /NO 2 - can be exploited to improve the performance of UV-AOPs treating TrOCs. This critical review provides a comprehensive framework outlining the multifaceted impact of NO 3 - /NO 2 - in UV-AOPs, contributing insights for basic research and practical applications of UV-AOPs containing NO 3 - /NO 2 - ., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Drinking water distribution systems (DWDSs) are important for supplying high-quality water to consumers and disinfectant is widely used to control microbial regrowth in DWDSs. However, the disinfectant's influences on microbial community and antibiotic resistome in DWDS biofilms and the underlying mechanisms driving their dynamics remain elusive. The study investigated the effects of chlorine and chloramine disinfection on the microbiome and antibiotic resistome of biofilms in bench-scale DWDSs using metagenomics assembly. Additionally, the biofilm activity and viability were monitored based on adenosine triphosphate (ATP) and flow cytometer (FCM) staining. The results showed that both chlorine and chloramine disinfectants decreased biofilm ATP, although chloramine at a lower dosage (1 mg/L) could increase it. Chloramine caused a greater decrease in living cells than chlorine. Furthermore, the disinfectants significantly lowered the microbial community diversity and altered microbial community structure. Certain bacterial taxa were enriched, such as Mycobacterium, Sphingomonas, Sphingopyxis, Azospira, and Dechloromonas. Pseudomonas aeruginosa exhibited high resistance towards disinfectants. The disinfectants also decreased the complexity of microbial community networks. Some functional taxa (e.g., Nitrospira, Nitrobacter, Nitrosomonas) were identified as keystones in chloramine-treated DWDS microbial ecological networks. Stochasticity drove biofilm microbial community assembly, and disinfectants increased the contributions of stochastic processes. Chlorine had greater promotion effects on antibiotic resistance genes (ARGs), mobile genetic elements (MGEs) and ARG hosts than chloramine. The disinfectants also selected pathogens, such as Acinetobacter baumannii and Klebsiella pneumonia, and these pathogens also harbored ARGs and MGEs. Overall, this study provides new insights into the effects of disinfectants on biofilm microbiome and antibiotic resistome, highlighting the importance of monitoring and managing disinfection practices in DWDSs., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

Microorganisms play an important role in the degradation of pollutants. However, they also cause problems in drinking water distribution systems, such as pipe corrosion and biofilm growth. The microbial assembly mechanisms and molecular ecological networks associated with different drinking water treatment processes have not yet been clearly analyzed. Therefore, this study investigated the microbiomes of three processes (coal filtration-activated carbon, ozone-activated carbon and UV, and ozone-activated carbon) during different seasons. The results showed that the microbial composition and diversity among the different processes and during different seasons. Water treatment processes had deterministic effects on the microbial assembly process and significantly changed the composition of rare and abundant species, altering the size and modules of molecular ecology networks. Rare species considered as keystone species play important roles in microbial ecology and microbial community construction. Ozone-activated carbon and UV/chlorination decreased the bacterial concentration, increased the deterministic process of microbial assembly, and significantly reduced the size of the network, which is of great significance to microbial control in drinking water. This research broadens our perspectives on the microbial assembly associated with drinking water treatment processes and contributes to ensuring the safe supply of drinking water., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier B.V. All rights reserved.)

The dose-response behavior of pathogens and inactivation mechanisms by UV-LEDs and excimer lamps remains unclear. This study used low-pressure (LP) UV lamps, UV-LEDs with different peak wavelengths, and a 222 nm krypton chlorine (KrCl) excimer lamp to inactivate six microorganisms and to investigate their UV sensitivities and electrical energy efficiencies. The 265 nm UV-LED had the highest inactivation rates (0.47-0.61 cm 2 /mJ) for all tested bacteria. The bacterial sensitivity strongly fitted the absorption curve of nucleic acids at wavelengths of 200-300 nm; however, indirect damage induced by reactive oxygen species (ROS) was the leading cause of bacterial inactivation under 222 nm UV irradiation. In addition, the guanine and cytosine (GC) content and cell wall constituents of bacteria affect inactivation efficiency. The inactivation rate constant of Phi6 (0.13 ± 0.002 cm 2 /mJ) at 222 nm due to lipid envelope damage was significantly higher than other UVC (0.006-0.035 cm 2 /mJ). To achieve 2log reduction, the LP UV lamp had the best electrical energy efficiency (required less energy, average 0.02 kWh/m 3 ) followed by 222 nm KrCl excimer lamp (0.14 kWh/m 3 ) and 285 nm UV-LED (0.49 kWh/m 3 ).

Organic pollutants are toxic and are present in drinking water. The conventional processes of most water plants can basically meet the discharge standard. However, based on the improvement of the objective of organic pollutants control and the constant change of water characteristics, the results may not be ideal. This study evaluates the effectiveness of different treatments such as microfiltration, nanofiltration, reverse osmosis, activated carbon, and ultraviolet irradiation/H 2 O 2 in terms of the removal of organic pollutants. Among the DOM results, nanofiltration, reverse osmosis, and activated carbon showed optimal performance due to the characteristics of processes and the compound properties. However, the risks of low-molecular-weight organic residue and byproduct formation are still present. Thirty-nine species of synthetic organic compounds (SOC) were qualitatively and semiquantitatively analyzed. Different technologies showed varying removal capabilities for SOC based on their properties and many substances coexisted leading to abnormal removal performances. These residual organics showed the characteristics of lower molecular weight, more hydrophilicity, further unknown impacts, and with risk of DBPs. Based on the above insights, possible methods can be rationally chosen for on-demand decontamination of organics in unconfined aquatic environment and long-time impact on water characteristics and human health also should be considered.

Microbial activity and regrowth in drinking water distribution systems is a major concern for water service companies. However, previous studies have focused on the microbial composition and diversity of the drinking water distribution systems (DWDSs), with little discussion on microbial molecular ecological networks (MENs) in different water supply networks. MEN analysis explores the potential microbial interaction and the impact of environmental stress, to explain the characteristics of microbial community structures. In this study, the random matrix theory-based network analysis was employed to investigate the impact of seasonal variation including water source switching on the networks of three DWDSs that used different disinfection methods. The results showed that microbial interaction varied slightly with the seasons but was significantly influenced by different DWDSs. Proteobacteria, identified as key species, play an important role in the network. Combined UV-chlorine disinfection can effectively reduce the size and complexity of the network compared to chlorine disinfection alone, ignoring seasonal variations, which may affect microbial activity or control microbial regrowth in DWDSs. This study provides new insights for analyzing the dynamics of microbial interactions in DWDSs., (Copyright © 2021. Published by Elsevier B.V.)

The use of ceramic membranes and ultraviolet light-emitting diodes (UV-LEDs) has advanced the application of photocatalytic membrane for water treatment. We systematically evaluated the contribution of filtration and photocatalysis to dissolved organic matter (DOM) removal and fouling mechanism during in-situ UV-LED photocatalytic ceramic membrane filtration. The results showed that physical rejection primarily led to removal of 4-15 kDa molecules and photocatalysis further increased the removal of 1-4 kDa molecules, causing small sized microbial humic-like or protein-like materials in the permeate. In-situ UV-LED photocatalysis had an excellent effect on membrane fouling mitigation regardless of DOM sources. The dominant fouling mechanism changed from partial blockage to gel layer formation with increasing Ca 2+ concentration but did not change with UV treatment. Correlation analysis revealed that the removal of 1-4 kDa molecules contributed to the mitigation of both reversible and irreversible fouling resistance, and the small molecules were the major cause of irreversible fouling resistance. Removal of 1-4 kDa terrestrial humic acid-like contributed to the pore blockage mechanism for synthetic water. Removal of 4-15 kDa protein-like materials was closely correlated to the pore blockage mechanism for real water. Trihalomethanes (THMs) and haloacetic acids (HAAs) formation potential (FP) were both significantly reduced after photocatalytic ceramic membrane process, but precursors of nitrogenous disinfection by-products (N-DBPs) with high toxicity were not removed by filtration or by photocatalysis, which deserves attention. Membrane rejection made higher contribution to better DBPFP control than photocatalysis. This study provides novel insights into the impact of UV-LED on DOM removal, DBPFP control and fouling mitigation, promoting the development of photocatalytic ceramic membrane filtration., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022. Published by Elsevier Ltd.)

Antibiotics are emerging contaminants in aquatic environments which pose serious risks to the ecological environment and human health. Advanced oxidation processes (AOPs) based on ultraviolet (UV) light have good application prospects for antibiotic degradation. As new and developing UV-AOPs, UV/chlorine and derived UV/chloramine processes have attracted increasing attention due to the production of highly reactive radicals (e.g., hydroxyl radical, reactive chlorine species, and reactive nitrogen species) and also because they can provide long-lasting disinfection. In this review, the main reaction pathways of radicals formed during the UV/chlor (am)ine process are proposed. The degradation efficiency, influencing factors, generation of disinfection by-products (DBPs), and changes in toxicity that occur during antibiotic degradation by UV/chlor (am)ine are reviewed. Based on the statistics and analysis of published results, the effects caused by energy consumption, defined as electrical energy per order (EE/O), increase in the following order: UV/chlorine < UV/peroxydisulfate (PDS)< UV/H 2 O 2  < UV/persulfate (PS) < 265 nm and 285 nm UV-LED/chlorine (EE/O). Some inherent problems that affect the UV/chlor (am)ine processes and prospects for future research are proposed. The use of UV/chlor (am)ine AOPs is a rich field of research and has promising future applications, and this review provides a theoretical basis for that., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

The degradation efficiency and mechanisms of ciprofloxacin (CIP), a typical antibiotic, by a medium-pressure ultraviolet/chloramine (MPUV/NH 2 Cl) treatment were investigated. The results showed that CIP degradation by MPUV/NH 2 Cl was significantly higher than that by NH 2 Cl oxidation and MPUV photolysis, and that this degradation processes were consistent with pseudo-first-order kinetics. The initial CIP concentration (7.5-30.2 μM) and the presence of HCO 3 - (0.5-10 mM) significantly inhibited CIP degradation with k obs,CIP 0.0090-0.0069 and 0.0078-0.0048 cm 2 /mJ. In contrast, NO 3 - (50-500 μM) and Br - (0.5-10 mM) significantly promoted the degradation with k obs,CIP 0.0078-0.0102 and 0.0078-0.0124 cm 2 /mJ. The effect of Cl - (0.5-10 mM) and natural organic matter (1-5 mg/L) were negligible. The NH 2 Cl dosage (30-60 μM) presented a dual effect, in which its increase within the optimal concentration range (30-40 μM) accelerated CIP degradation due to the formation of reactive radicals, whereas an excessive increase (40-60 μM) quenched the free radicals, ultimately quenching the free radicals and inhibiting the degradation. The optimum pH for CIP degradation under MPUV/NH 2 Cl treatment was 7.0. The contribution of reactive halogen species (i.e., reactive chlorine species and reactive nitrogen species) to CIP degradation was substantially greater than that of hydroxyl radicals under acidic or neutral conditions. We identified the degradation products of CIP and proposed degradation pathways, which included defluorination and cracking of the piperazine ring, with the latter being dominant. Compared to haloacetic acid (HAA) and nitrogenous disinfection byproducts (N-DBPs), MPUV/NH 2 Cl significantly reduced trihalomethane (THM) production and theoretical cytotoxicity by 80.1% and 78.4% respectively, compared to the background experiment in natural water at a UV dose of 300 mJ/cm 2 ., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier B.V. All rights reserved.)

A new focus on biofiltration has emerged that aims to shape microbial communities to improve treatment efficacy. It is therefore necessary to understand the linkages between microbial community structure and biofilter function. However, the assembly and interaction of microbial communities in biological activated carbon (BAC) filters are unknown. In this study, we selected one coal-based granular activated carbon (GAC), GAC-13, with simultaneously developed micropore and micro-level macropore volume used for a bench-scale BAC column experiment, and compared it with other coal-based GACs and wood-based GAC in terms of the dissolved organic carbon (DOC) removal and microbial community characteristics. The results showed that there was no difference between the DOC removal efficiency of BAC-13 and the other two coal-based BAC filters with high iodine value in the period dominated by adsorption, while the DOC removal efficiency of BAC-13 (64.7±0.6%) was significantly higher than that of other BAC filters (36.3±0.8-54.1±0.4%) with a difference of 0.3-0.7 mg/L in DOC during the steady state. The bacterial communities were strongly assembled by deterministic rather than stochastic factors, where the surface polarity of GAC had a greater effect on the microbial communities than its physical properties. The corresponding co-occurrence network revealed that microbes in the BAC filter may be more cooperative than competitive. The keystone bacterium Hyphomicrobium, which had a relatively low abundance, contributed 0.3-1% more to the most abundant functions and produced 5-21 proteins/(g·GAC) more than the dominant bacterium Sphingobium. The metaproteomic-based approach could provide more accurate information regarding the contributions of different species to metabolic functions. The pore size distribution of GAC was found to be an important factor in determining BAC filter performance; the most important pore sizes were micropores and micro-level macropores (0.2-10 μm and >100 μm in diameter), and the latter impacted the abundance of keystone species. Overall, our findings provide new insights into shaping microbial communities by optimizing pore size structure to improve BAC performance, especially the abundance of keystone species., (Copyright © 2022. Published by Elsevier Ltd.)

Monochloramine (NH 2 Cl) oxidant combined with a Ultraviolet (UV)-Light-emitting-diode (LED) light source forms a new advanced oxidation process (AOP), which can achieve high-efficiency degradation of carbamazepine (CBZ). The degradation of CBZ displayed pseudo-first-order reaction kinetics (R 2  > 0.98, k CBZ  = 0.0043 cm 2  mJ -1 at pH 7). The degradation of CBZ was dependent on UV-LED wavelength, with maximum degradation efficiency observed at 265 nm since it was the lowest wavelength studied among UV-LEDs. Variation in pH across the range, which might be expected under normal environmental conditions (pH 6-8), and the presence of Cl - had no significant effect on the degradation efficiency of CBZ, while the presence of HCO 3 - and natural organic matter (NOM) inhibited degradation. Electron paramagnetic resonance (EPR) experiments detected OH in the system. Probe compounds were used to distinguish the contribution of reactive chlorine species (RCS). It was proved that OH and Cl played major roles and OH was responsible for around 50% of the observed degradation of CBZ. Eight transformative products (TPs) in the degradation process of CBZ were identified, with a generally decreasing toxicity. The concentration of disinfection by-products (DBPs) formed during CBZ degradation was all within limits of WHO and China standard for drinking water. Although the concentration of nitrogen-containing DBPs (N-DBPs) was the lowest, N-DBPs were the main contributors to toxicity, and these would require more attention in practical applications. UV-LED/NH 2 Cl AOP was identified as an effective way to degrade pharmaceutically active compounds., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2021 Elsevier B.V. All rights reserved.)

Perfluorinated compounds (PFCs), as emerging persistent pollutants, can exist for a long time in the environment due to their high stability. PFCs have been detected in drinking water, wastewater, and the human body. Studies have shown that PFCs pose a threat to human health and the ecological environment, which is expected to be listed in new drinking water regulations. Traditional processes, including coagulation, biological filtration, chlorination, ozonolysis, and ultraviolet light have ineffective removal efficiency on PFCs; however, advanced oxidation processes (AOP) based on ultraviolet (UV) light have good application prospects for the removal of PFCs. This study provides an overview of the removal of PFCs by UV-based AOPs; systematically introduces the research status of various UV-based AOPs from the perspectives of degradation pathways, degradation efficiency, influencing factors, formation of by-products; and comprehensively compares these different UV-based AOPs. Finally, the limitations of existing research and future research needs are discussed. This review aims to provide an overview for a better understanding of the degradation status and prospects of UV-based AOPs for the degradation of PFCs., (Copyright © 2021 Elsevier Ltd. All rights reserved.)

UV-based advanced oxidation processes (AOPs) via photolysis of precursor chemical oxidants have been of interest to numerous researchers over the past several decades due to their capacity to generate highly active radical species and interesting radical chemistry. However, applications of UV-based AOPs have been commonly optimized case by case, due to the lack of theoretical investigations on process optimization, especially on oxidant doses. In this study, a simple equation for UV/H 2 O 2 (•OH as the sole primary reactive species (PRS)) to obtain the theoretical optimal concentration (C opt-theoretical ) for H 2 O 2 was derived (C opt-theoretical =A b ·S c ε·k). The equation was then validated for its accuracy in the calculation of C opt-theoretical for H 2 O 2 in the UV/H 2 O 2 AOP using a well-established comprehensive kinetic model. A competition kinetics method for the measurement of scavenging capacity (S c , the unknown parameter for the simple equation) was designed, for which nitrobenzene was employed as the probe compound and tert‑butyl alcohol was introduced as the standard compound. Based on this simple equation, we calculated the C opt-theoretical of 77 environmental water samples and introduced the concept of a practical optimal oxidants dose for the UV/H 2 O 2 AOP, while minimizing the operation costs in engineering applications. Moreover, this study mathematically proved that the simple equation obtained from UV/H 2 O 2 could be successfully extended to other UV-based AOPs, including UV/chlorine, UV/NH 2 Cl, UV/S 2 O 8 2- , and UV/peracetic acid. The simple equation of C opt-theoretical derived in this study may not only help to provide instructions for engineering applications, but also point out the ultimate treatment capability of each UV-based AOPs., (Copyright © 2021. Published by Elsevier Ltd.)

Given that fluoroquinolone antibiotics (FQs) are frequently detected in aquatic environments, there is an urgent need for the development of efficient water treatment technologies for their removal. Peracetic acid (PAA)-based advanced oxidation processes (AOPs) have increasingly attracted attention as promising technologies for water decontamination in this regard. In this study, a novel PAA-based AOP (the medium-pressure ultraviolet (MPUV)/PAA process) was employed to degrade norfloxacin (NOR), which is an extensively applied FQ that is widely present in water. Mechanistic and kinetic aspects of the role of pH on this NOR degradation process were investigated. The results obtained showed that the MPUV/PAA process could effectively degrade NOR (pH = 5-9), and the degradation efficiency was significantly enhanced at pH 7 and 9 compared with that at pH 5. This observation could be attributed to the effect of pH on the ionic forms of NOR and the generation of reactive oxygen species (ROS). Further, the rate of PAA photolysis, which resulted in the formation of reactive radicals, increased with pH, as evidenced by the observed increase in the molar absorption coefficient of PAA (ε PAA ). Electron paramagnetic resonance (EPR) tests also indicated that the generation of ROS was significantly enhanced when the pH increased from 5 to 7, and at pH 9, a large amount of •OH were possibly consumed by PAA to form organic radicals, leading to a decrease in the •OH signal. Furthermore, it was observed that •OH is primarily responsible for NOR degradation in the MPUV/PAA process at pH 5, whereas organic radicals were primarily responsible for the degradation at pH 7 and 9. The identification of the transformation products (TPs) led to the observation of different NOR transformation pathways owing to the MPUV/PAA process under different pH conditions. Overall, this study provides a comprehensive understanding of the role of pH on the MPUV/PAA degradation behavior of FQs., (Copyright © 2021 Elsevier Ltd. All rights reserved.)

The microbiological water quality of drinking water distribution systems (DWDSs) is of primary importance for public health. The detachment of biofilm attached on the pipe wall attribution to water source switch and the occurrence of potentially pathogenic chlorine-resistant bacteria (CRB) under chlorine disinfection get lots of attention. Studies examining microbial communities after the water source switch, particularly in low-salinity water, have been scant. The UV‑chlorine combined disinfection applied in one of the investigated drinking water plants provided insight into the control of CRBs. We applied high-throughput sequencing of the 16S rRNA gene to characterize the bacterial communities of the DWDS in northern China over 1 year. A network comprising four different DWDSs was sampled at 48 sites every season (temperate continental monsoon climate), and the impact of key spatial-temporal and physicochemical parameters was investigated. Overall, the entire bacterial community was not significantly different among the four DWDSs (spatial parameter) but varied with seasons (temporal parameter). The switch in water sources might increase the relative abundance of potentially opportunistic pathogens in DWDSs. UV‑chlorine combined disinfection can decrease community diversity and is likely to control the growth of potential opportunistic pathogens in DWDSs., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2021. Published by Elsevier B.V.)

Biologically activated carbon (BAC) filters are widely used in China and worldwide as an essential part of advanced water treatment. However, it is unclear how to properly select the granular activated carbon (GAC) used in BAC filters and to determine when GAC should be replaced. In this study, five BAC filters, each filled with a different coconut- or coal-based GAC with different physicochemical properties, were run continuously for 400 days. The structure and function of the microbial community and the quantity of specific enzymes in the BAC filters were investigated through an integrated metagenomic/metaproteomic analysis. The results indicated that GAC adsorption still played a major role in removing organic matter once the filters reached a steady-state, which was attributed to bioregeneration, and the contribution of adsorption might be relatively greater than that of biodegradation. GAC with strong adsorption capacity and high bioregeneration potential selected bacterial communities more phylogenetically closely-related than others. The iodine value could be used as an indicator of BAC performance in terms of organic matter removal in the initial stage of the filters, which is dominated by adsorption. However, it could not be used to assess performance at a later stage when adsorption and biodegradation occurred simultaneously. Pore-size distribution characteristics could be chosen as a potential better indicator compared with the current adsorption indicators, dually representing the adsorption performance and the microbial activity, and the proportion of important pore-size of GAC that is more suitable for BAC filter is suggested. GAC with strongly polar terminal groups is more conducive to the removal of ammonium-nitrogen., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2021. Published by Elsevier Ltd.)

The UV/NH 2 Cl process is an emerging advanced oxidation process (AOP) that is greatly effective in degrading pharmaceuticals and personal care products (PPCPs). However, detailed information regarding the process is lacking. The degradation of ibuprofen (IBP, an electron-withdrawing PPCP) and naproxen (NPX, an electron-donating PPCP) in UV/NH 2 Cl and UV/NaClO processes was performed to investigate the applicability and security of the UV/NH 2 Cl process and compare with those of UV/NaClO. UV/NH 2 Cl was effective in degrading both IBP and NPX and the degradation followed pseudo-first order kinetics (k IBP  = 0.0037 cm 2 /mJ and k NPX  = 0.0044 cm 2 /mJ). This indicated the broad applicability of UV/NH 2 Cl to different kinds of PPCPs. Ranges of values of UV intensity (0.3-1.0 mW/cm 2 ) and pH (6.0-8.0) showed little effect on the degradation of PPCPs by UV/NH 2 Cl based on UV Dose but HCO 3 - (2-8 mM), natural organic matter (NOM, 2-8 mg/L), and the natural water matrixes were inhibitory. Increasing the dosage of NH 2 Cl from 0.15 mM to 0.75 mM, resulted in an even increase of k IBP ; however, k NPX increased slowly after 0.3 mM NH 2 Cl. Mechanism experiments involving nitrobenzene showed that •OH was the major radical involved in degrading IBP and NPX via UV/NH 2 Cl. The electron spin resonance spectroscopy and kinetic modeling results also indicated the larger amount of •OH and weaker reactive chlorine species (mainly ClO• and ClO 2 •) in UV/NH 2 Cl compared with UV/NaClO. Compared to UV/NaClO in synthetic and natural water, UV/NH 2 Cl was a more stable degrader with little pH- and substrate-dependence, while UV/NaClO preferred degrading the electron-donating PPCP and at low pH. The UV/NH 2 Cl produced less halogenated disinfection byproducts (DBPs) (even nitrogenous DBPs) and was less cytotoxic theoretically than UV/NaClO based on the DBPs included in this study. Thus UV/NH 2 Cl process may be an effective AOP for water treatment., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2020 Elsevier Ltd. All rights reserved.)

Proper granular activated carbon (GAC) selection could improve the performance of biological activated carbon (BAC) filters through a combination of adsorption and biodegradation, while the GACs used in BAC filters are now mainly selected according to adsorption function, ignoring biodegradation. In this study, sand filter effluent obtained from a drinking water treatment plant was fed into continuous-flow bench-scale BAC columns operated in parallel over 245 days to examine the effects of GAC pore-size distribution on BAC filter performance, in terms of the dissolved organic carbon (DOC) and disinfection byproduct (DBP) precursors. A metagenomic analysis indicated that bacterial community structure played an important role in BAC filter performance. A significant correlation was found between metabolism-related proteins and the volume of micro-level macropores based on metaproteomic analysis. It is suggested that the adsorption saturation was dynamic and that adsorption played a role in the performance of the BAC filters throughout the 245-day operating period. Renewed adsorption capacity, or bioregeneration, was driven by bacterial metabolic activity. Such activity largely depended on the organic matter adsorbed by the GAC, in which micro-level macropores, especially those with diameters of 0.2-10 μm, played an important but previously unrecognized role. The results suggest that more attention should be paid to well-developed pores and pore-size distribution in the production and selection of GAC used for full-scale drinking water biofilters., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2020 Elsevier Ltd. All rights reserved.)

Membrane technologies have broad applications in the removal of contaminants from drinking water and wastewater. In recent decades, ceramic membrane has made rapid progress in industrial/municipal wastewater treatment and drinking water treatment owing to their advantageous properties over conventional polymeric membrane. The beneficial characteristics of ceramic membranes include fouling resistance, high permeability, good recoverability, chemical stability, and long life time, which have found applications with the recent innovations in both fabrication methods and nanotechnology. Therefore, ceramic membranes hold great promise for potential applications in water treatment. This paper mainly reviews the progress in the research and development of ceramic membranes, with key focus on porous ceramic membranes and nanomaterial-functionalized ceramic membranes for nanofiltration or catalysis. The current state of the available ceramic membranes in industry and academia, and their potential advantages, limitations and applications are reviewed. The last section of the review focuses on ceramic membrane fouling and the efforts towards ceramic membrane fouling mitigation. The advances in ceramic membrane technologies have rarely been widely reviewed before, therefore, this review could be served as a guide for the new entrants to the field, as well to the established researchers., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2020 Elsevier Ltd. All rights reserved.)

To manage potential microbial risks and meet increasingly strict drinking water health standards, UV treatment has attracted increasing attention for use in drinking water systems in China. However, the effects of UV treatment on microbial control and disinfection by-products (DBPs) formation in real municipal drinking water systems are poorly understood. Here, we collected water samples from three real drinking water systems in Beijing and Tianjin to investigate the impacts of UV treatment on microbial control and DBP formation. We employed heterotrophic plate count (HPC), flow cytometry (FCM), quantitative PCR analysis, and high-throughput sequencing to measure microorganisms in the samples. Different trends were observed between HPC and total cell count (measured by FCM), indicating that a single indicator could not reflect the real degree of biological re-growth in drinking water distribution systems (DWDSs). A significant increase in the 16S rRNA gene concentration was observed when the UV system was stopped. Besides, the bacterial community composition was similar at the phylum level but differed markedly at the genera level among the three DWDSs. Some chlorine-resistant bacteria, including potential pathogens (e.g., Acinetobacter) showed a high relative abundance when the UV system was turned off. It can be concluded that UV treatment can mitigate microbial re-growth to some extent. Finally, UV treatment had a limited influence on the formation of DBPs, including trihalomethanes, haloacetic acids, and nitrogenated DBPs. The findings of this study may help to understand the performance of UV treatment in real drinking water systems., (Copyright © 2019. Published by Elsevier B.V.)

The use of vacuum-ultraviolet (VUV) photolysis in water treatment has been gaining significant interest due to its efficacy in degrading refractory organic contaminants and eliminating oxyanions. In recent years, the reactive species driving pollutant decomposition in VUV-based advanced oxidation and reduction processes (VUV-AOPs and VUV-ARPs) have been identified. This review aims to provide a concise overview of VUV photolysis and its advancements in water treatment. We begin with an introduction to VUV irradiation, followed by a summary of the primary reactive species in both VUV-AOPs and VUV-ARPs. We then explore the factors influencing VUV-photolysis in water treatment, including VUV irradiation dose, catalysts or activators, dissolved gases, water matrix components (e.g., DOM and inorganic anions), and solution pH. In VUV-AOPs, the predominant reactive species are hydroxyl radicals (˙OH), hydrogen peroxide (H 2 O 2), and ozone (O 3). Conversely, in VUV-ARPs, the main reactive species are the hydrated electron (e aq −) and hydrogen atom (˙H). It is worth noting that VUV-based advanced oxidation/reduction processes (VUV-AORPs) can transit between VUV-AOPs and VUV-ARPs based on the externally added chemicals and dissolved gases in the solution. Increase of the VUV irradiation dose and the concentration of catalysts/activators enhances the degradation of contaminants, whereas DOM and inorganic anions inhibit the reaction. The pH influences the redox potential of ˙OH, the speciation of contaminants and activators, and thus the overall performance of the VUV-AOPs. Conversely, an alkaline pH is favored in VUV-ARPs because e aq − predominates at higher pH. [Display omitted] • VUV photolysis includes AOP driven by ˙OH, H 2 O 2 , and O 3 , and ARP driven by e aq − /˙H. • Irradiation dose, catalysts, gas, water matrix, and pH influences VUV efficacy. • VUV-AOP cost is lower than ultrasound, UV, electric AOP, plasma, and photo-Fenton. • Shallow penetration depth of VUV in water leads to full-scale treatment unworkable. • Optimizing the VUV reactor is a good way to overcome its limitations. [ABSTRACT FROM AUTHOR]

Ballast water has been a topic of concern for some time because of its potential to introduce invasive species to new habitats. To comply with the International Convention for the Control and Management of Ships' Ballast Water and Sediments, members of the International Maritime Organization (IMO) must equip their ships with on-board treatment systems to eliminate organism release with ballast water. There are many challenges associated with the implementation of this IMO guideline, one of which is the selection of species for testing the ecological impacts of the treated ballast water. In the United States, ballast water toxicity test methods have been defined by the United States Environmental Protection Agency. However, the test methods had not been finalized in China until the toxicity test methods for ballast water were established in 2008. The Chinese methods have been based on species from three trophic levels: Skeletonema costatum, Neomysis awatschensis, and Ctenogobius gymnauchen. All three species live in broad estuarine and open sea areas of China; they are sensitive to reference toxicants and acclimatize easily to different conditions. In this paper, the biological characteristics, test processes and statistical analysis methods are presented for the three species. Results indicate that the methods for evaluating these three organisms can be included in the ecological toxicity tests for treated ballast water in China. [ABSTRACT FROM AUTHOR]

As a green advanced process for drinking water treatment, the UV/hydrogen peroxide (UV/H2O2) process has been gradually applied in China. To study the effect and mechanism of organic matter removal and the development of microbial communities in the UV/H2O2-biological activated carbon (UV/H2O2-BAC) process, a pilot-scale UV/H2O2-BAC system was built and operated over one year. Low water temperature affects the UV/H2O2 process efficiency, the biofilms in the BAC system were mature and stable after 240 days, and the contribution rate of BAC adsorption to dissolved organic carbon (DOC) removal was approximately 14.2% after one year of operation. The liquid chromatography-organic carbon detection (LC-OCD) analysis shows that UV/H2O2 process can increase the amounts of Low Molecular Weight (LMW) neutrals, and the specific UV absorbance (SUVA254) value is not suitable for predicting Trihalomethanes (THMs) precursor contents in water after UV/H2O2 treatment. High-throughput sequencing results prove that microbial species in the middle section are the most abundant compared to those in the influent and effluent sections, hydrogen peroxide has lower inhibition on the development of microbial community than ozone and the low concentration of hydrogen peroxide (<0.25 mg/L) promotes the development of the microbial communities, hydrogen peroxide can reduce Proteobacteria abundance by inhibiting the growth of anaerobes. Acidobacteria may have a certain contribution to the degradation of soil organic matter (SOM), and the effluent section of BAC with low DOC concentration cannot form the dominant species of Rhodobacter. [ABSTRACT FROM AUTHOR]

• TiO 2 -GO modified ceramic membranes had an extremely high hydrophilicity and negative charge. • Modified membranes had a higher removal of ions and pharmaceuticals and better HAAs-FP control. • A modified Hermia's model was fit well to the data of TA and HA fouling for ceramic membranes. • The fouling mechanism explained pharmaceutical retention of HA-fouled ceramic membranes. • Modified membranes restrained bacterial adhesion but exhibited a minor biofouling inhibition. In this study, modified ceramic membranes functionalized with titanium dioxide (TiO 2) graphene oxide (GO) via the vacuum method were prepared, and the effects of the modification on the surface chemistry, retention property and fouling mechanism were systematically investigated. The characterization of the modified membranes demonstrated an extremely high hydrophilicity and negative charge of membrane surface. A higher removal of humic acid (HA), tannic acid (TA), ions and pharmaceuticals and better haloacetic acids formation potential (HAAs-FP) control was observed for the TiO 2 -GO-modified ceramic membrane compared to the pristine ceramic membrane while maintaining a relatively high permeate flux. The TiO 2 -GO-modified ceramic membrane also exhibited improved antifouling properties against HA and TA fouling. A modified Hermia's model was fit accurately to the experimental data obtained from long-term TA and HA fouling protocols for both pristine and modified membranes. The TA fouling mechanism transformed from a standard blocking to an intermediate blocking mechanism for the TiO 2 -GO-modified membrane, indicating a dramatic decrease in the membrane pore size after modification. The gel layer formation model fit well for the modified ceramic membrane during HA filtration, which explained the decrease in the selected pharmaceutical retention by the HA-fouled membranes, while pore blocking governed the HA fouling for the pristine membranes, causing an increase in the pharmaceutical retention by the fouled membranes. The TiO 2 -GO-modified membrane had a strong effect against bacterial adhesion, but only exhibited a minor inhibition of biofouling after a 24 h protocol in cross-flow filtration. [ABSTRACT FROM AUTHOR]

UV-based advanced oxidation processes (UV-based AOPs) via photolysis of radical precursor chemicals (RPCs) are among the most effective technologies for eliminating trace organic contaminants in water treatment facilities. However, mathematical discussions on the kinetics and energy consumption for the engineering photoreactor set-up of UV-based AOPs, especially the newly proposed UV-based AOPs (e.g., UV/persulfate, UV/chlorine and UV/chloramine), are scarce. In this study, a photoreactor with reflective sleeves was mathematically characterized and validated using clean and complex water matrices, and approaches for measuring effective light absorbance by RPC (I RPC) and the reflectance of the photoreactor wall (η) were proposed. By applying I RPC and η , and employing geosmin as a model compound, energy optimization of the UV-based AOPs was conducted based on an updated kinetic model. A new equation was derived for UV/H 2 O 2 to obtain the most cost-effective RPC dose regarding EE/O (electric energy required for one order of contaminant removal) (C opt-EE/O). This equation was then successfully extended to other UV-based AOPs (including UV/persulfate, UV/chlorine, and UV/chloramine). The balance between the treatment goals and operational costs was also discussed. Overall, the new concepts and approaches proposed in this study may aid in the energy optimization and reduce RPC consumption of various UV-based AOPs for engineering applications. [Display omitted] • A photoreactor with reflective inner surfaces was characterized and validated. • Effective light absorbance by RPC and photoreactor wall reflectance were measured. • An equation to obtain the most cost-effective dose of RPC in UV-based AOP was derived. • The balance between the treatment goals and operational costs was discussed. [ABSTRACT FROM AUTHOR]

The wide occurrence of fluoroquinolones (FQs) in aquatic environments has aroused increasing concern about their potential adverse effects on human health. In this study, an emerging advanced oxidation process, i.e., the Medium-Pressure Ultraviolet/Peracetic Acid (MPUV/PAA) process, was used to degrade FQs (e.g., levofloxacin (LEV), norfloxacin, and ciprofloxacin). Compared with the MPUV process alone and the PAA process alone, the MPUV/PAA process significantly promoted degradation of FQs due to the considerable contribution of reactive radicals. Probe experiments revealed that PAA-specific organic radicals (e.g., CH 3 C(O)O• and CH 3 C(O)OO•) were the major radicals responsible for FQ elimination. Rapid degradation of FQs via the MPUV/PAA process was achieved within a wide range of pH values (5−9) by selecting LEV as the target compound, and higher pH values were more favorable for the reaction. The slight impacts of Cl– and CO 3 2−/HCO 3 – on LEV removal were observed. The transformation products and pathways of LEV were identified, and nearly all of the transformation pathways occurred on the piperazine ring. Based on Quantitative Structure-Activity Relationship (QSAR) analysis, most of the products had lower toxicities than LEV. Overall, these findings improve our understanding and application of the MPUV/PAA process for degrading emerging contaminants in (waste)water treatment. [Display omitted] • FQ degradation via the MPUV/PAA process was systemically explored. • PAA-specific organic radicals were primarily responsible for the FQ degradation. • Rapid LEV degradation was achieved within a wide pH range, as well as in the presence of Cl– and CO 3 2−/HCO 3 –. • The hydroxylation of the piperazine ring via the attack of organic radicals was the major degradation pathway of LEV. • Most of the products have lower toxicities than the parent compound (LEV). [ABSTRACT FROM AUTHOR]