1. Organophosphate esters in the seawater of the Bohai Sea: Environmental occurrence, sources and ecological risks.
- Author
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Xing R, Zhang P, Zheng N, Ji H, Shi R, Ge L, and Ma H
- Subjects
- Environmental Monitoring, Esters analysis, Organophosphates analysis, Seawater, Water analysis, China, Flame Retardants analysis, Water Pollutants, Chemical analysis
- Abstract
Organophosphate esters (OPEs) are widely distributed in surface water systems, but limited information was available on the spatial occurrence and ecological risks of OPEs in the Bohai Sea. In this study, 89 water samples in the Bohai Sea and the five surrounding rivers were investigated for the determination of 15 OPEs. The concentration of ∑
15 OPEs ranged from 373.20 to 2931.27 ng·L-1 in the river water and 137.81 to 2641.30 ng·L-1 in the seawater, with high levels of OPEs in Liaodong Bay. Tris(2-chloroethyl) phosphate (TCEP, 10- 92 %) and triethyl phosphate (TEP, 5- 64 %) were dominant for OPEs. The correlation analysis, principal component analysis and hierarchical cluster analysis suggested the conjunction of municipal wastewater via river input and maritime shipping was the main source of OPEs in the Bohai Sea. The ecological risk assessment indicated that the individual OPEs arise low ecological risks in the Bohai Sea, while medium ecological risks of ∑15 OPEs are in minority river samples., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)- Published
- 2023
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