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In the current research work, the activated carbon synthesized from the plant species Delonix regia is doped with iron oxide nanoparticles and enforced as a nanosorbent for the effective extermination of Tartrazine (TAR) and Methylene blue (MB) dyes. This nanosorbent is prepared from the bark powder of the Delonix regia and subjected to chemical activation; Furthermore, the synthesized biosorbent were characterized using FTIR, SEM, TGA, and XRD to understand their functional properties and structural morphology. The optimum effectiveness adsorption of Tartrazine and Methylene blue has been investigated by using different key parameters. The conclusions have shown the highest removal percentage at a pH of 3 and 6 for Tartrazine and Methylene blue, respectively. For the various initial concentrations, the adsorption percentage reached equilibrium after 60 min and 90 min for TAR and MB. The adsorption equilibrium values were applied to various isotherms models. The adsorbent showed a higher removal capacity of 357.142 mg g -1 and 147.058 mg g -1 and for MB and TAR respectively. The kinetic data were best fits to pseudo second order model. The thermodynamic parameters indicated that this adsorption process was found to be spontaneous, exothermic and feasible at different temperatures. These results have shown that the prepared adsorbent is an environmentally friendly and suitable material for the elimination of TAR and MB from water systems., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier Inc. All rights reserved.)

The objective of the current study was focused on the potential adsorption capability of a biogenic hydroxyapatite/iron nanoparticles-based composite tailored for the elimination of toxic pollutant, Cd(II) ions. Morphological along with physicochemical properties of composites were analyzed by different techniques including Scanning electron microscopy (SEM), Energy-dispersive X-ray spectroscopy (EDAX), X-ray diffraction (XRD), and Fourier Transform Infrared Spectroscopy (FTIR). It has been noticed an increase in cell parameters of prepared composites with an increase in the amount of nanoparticles. The best adsorbent was found to be the one with a 5% amount of nanoparticles (P 400 F e (5%)). The kinetics studies have shown that the pseudo-first-order-models were in good agreement for the removal of Cd(II) ions onto P 400 Fe(5%) at any concentration, suggesting a physisorption mechanism. Besides, isotherms analysis has consistently revealed Freundlich as the model better explained the isotherm data, with a maximum removal capacity of 392.3 mg g -1 , higher compared to many adsorbents. Thermodynamically, the removal adsorption process of Cd(II) ions onto the composite favorable, exothermic, and spontaneous. The regeneration study has been also investigated with reusability used until four cycles. The overall results pointed out the suitability and efficiency of the prepared biogenic composite for the elimination of metal pollutants in wastewater., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2021 Elsevier Ltd. All rights reserved.)

In the current research work, a novel eco-friendly Fe 3 O 4 @SiO 2 nanocomposite immobilized with Pseudomonas fluorescens biomass in calcium alginate beads (MSAB) was used as biosorbent for the elimination of hazardous Rhodamine B dye from aqueous system. The FTIR, XRD and SEM results showed that the MSAB possessed excellent surface properties for the effective sequestration of Rhodamine B. The batch adsorption results concluded that the adsorption of Rhodamine B using MSAB is highly influenced by the parameters such as pH, adsorbent dosage, initial dye concentration and contact time. The equilibrium and kinetics data get best fitted in the Freundlich isotherm and Pseudo first order kinetics for the studied adsorption system. The Langmuir monolayer adsorption capacity was found to be 229.6 mg/g. The thermodynamic studies showed that the adsorption was spontaneous, feasible and exothermic in nature. The adsorption mechanisms are understood using the Intraparticle diffusion and Boyd model. Thus, this Magnetic silica alginate beads (MSAB) containing dead biomass of Pseudomonas fluorescens is considered to be an ideal biosorbent which can be used as an effective tool in treating the industrial dye wastewater treatment., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2020 Elsevier Ltd. All rights reserved.)